Abstract
Interaction of external electric field with free and bound charges in the salt solution volume in polar dielectric fluid was considered and the equation describing ion oscillations relative to solvent molecules was obtained. Fundamental frequencies of the solvation shell relative to the ion in different approximations describing the system: ion - solvation shell were evaluated. The results of comparison with the experiment pointed out that the model, in which the solvated ion is considered as a spherical rotator formed by the solvent molecules layer bordering with the external solvation shell, is the most appropriate. It provides an opportunity of development of new technologies for extraction of rare earth elements.
| Original language | English |
|---|---|
| Article number | 00012 |
| Journal | MATEC Web of Conferences |
| Volume | 96 |
| DOIs | |
| Publication status | Published - 19 Jan 2017 |
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ASJC Scopus subject areas
- Chemistry(all)
- Engineering(all)
- Materials Science(all)
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Excitation Frequencies of the Effects of Selective Drift of Solvated Cations in Moving Salts Solution. / Shamanin, Igor; Kazaryan, Mishik A.; Gofman, Valeriy; Timchenko, Sergey; Poberezhnikov, Andrei; Tuksov, Ilya.
In: MATEC Web of Conferences, Vol. 96, 00012, 19.01.2017.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Excitation Frequencies of the Effects of Selective Drift of Solvated Cations in Moving Salts Solution
AU - Shamanin, Igor
AU - Kazaryan, Mishik A.
AU - Gofman, Valeriy
AU - Timchenko, Sergey
AU - Poberezhnikov, Andrei
AU - Tuksov, Ilya
PY - 2017/1/19
Y1 - 2017/1/19
N2 - Interaction of external electric field with free and bound charges in the salt solution volume in polar dielectric fluid was considered and the equation describing ion oscillations relative to solvent molecules was obtained. Fundamental frequencies of the solvation shell relative to the ion in different approximations describing the system: ion - solvation shell were evaluated. The results of comparison with the experiment pointed out that the model, in which the solvated ion is considered as a spherical rotator formed by the solvent molecules layer bordering with the external solvation shell, is the most appropriate. It provides an opportunity of development of new technologies for extraction of rare earth elements.
AB - Interaction of external electric field with free and bound charges in the salt solution volume in polar dielectric fluid was considered and the equation describing ion oscillations relative to solvent molecules was obtained. Fundamental frequencies of the solvation shell relative to the ion in different approximations describing the system: ion - solvation shell were evaluated. The results of comparison with the experiment pointed out that the model, in which the solvated ion is considered as a spherical rotator formed by the solvent molecules layer bordering with the external solvation shell, is the most appropriate. It provides an opportunity of development of new technologies for extraction of rare earth elements.
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UR - http://www.scopus.com/inward/citedby.url?scp=85013129724&partnerID=8YFLogxK
U2 - 10.1051/matecconf/20179600012
DO - 10.1051/matecconf/20179600012
M3 - Article
VL - 96
JO - MATEC Web of Conferences
JF - MATEC Web of Conferences
M1 - 00012
ER -