Ethylene glycol oxidation over Ag-containing catalysts: A theoretical study

M. A. Salaev, O. Kh Poleshchuk, O. V. Vodyankina

    Research output: Contribution to journalArticle

    4 Citations (Scopus)

    Abstract

    A theoretical interpretation of the mechanism of ethylene glycol oxidation to glyoxal over Ag-containingcatalysts is considered. A model system, reflecting the interaction of Ag cluster with process adsorbates and/or intermediates, is proposed. Both partial oxidation of ethylene glycol to glyoxal and CO2 formationroutes are reconstructed, and the corresponding reaction profiles are represented. The roles played by themost important reaction intermediates participating in the process under consideration are discussed.

    Original languageEnglish
    Pages (from-to)61-67
    Number of pages7
    JournalJournal of Molecular Catalysis A: Chemical
    Volume396
    DOIs
    Publication statusPublished - 2015

    Keywords

    • Cluster model
    • DFT
    • Ethylene glycol
    • Oxidation
    • Silver

    ASJC Scopus subject areas

    • Catalysis
    • Physical and Theoretical Chemistry
    • Process Chemistry and Technology

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