Estimation of the composition of electrolytically prepared intermetallic bismuth-platinum deposits

Abstract

The method of partial anodic peak resolution is applied to complex voltammograms. The estimation of the composition of the intermetallic Bi-Pt compounds electrolytically deposited is carried out by a resolution of the components of the voltammograms. It is shown that nonequilibrium conditions take place in electrolytic Bi-Pt deposit when three intermetallic compounds such as: Pt ₂Bi ₃, PtBi ₂, PtBi, and phase of pure Bi exist simultaneously on the electrode.

Original language	English
Pages (from-to)	2419-2423
Number of pages	5
Journal	Journal of Solid State Electrochemistry
Volume	16
Issue number	7
DOIs	https://doi.org/10.1007/s10008-012-1730-7
Publication status	Published - Jul 2012

Keywords

Binary alloy
Bismuth
Intermetallic compound
Platinum
Stripping voltammetry

ASJC Scopus subject areas

Electrochemistry
Electrical and Electronic Engineering
Condensed Matter Physics
Materials Science(all)

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10.1007/s10008-012-1730-7

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title = "Estimation of the composition of electrolytically prepared intermetallic bismuth-platinum deposits",

abstract = "The method of partial anodic peak resolution is applied to complex voltammograms. The estimation of the composition of the intermetallic Bi-Pt compounds electrolytically deposited is carried out by a resolution of the components of the voltammograms. It is shown that nonequilibrium conditions take place in electrolytic Bi-Pt deposit when three intermetallic compounds such as: Pt 2Bi 3, PtBi 2, PtBi, and phase of pure Bi exist simultaneously on the electrode.",

keywords = "Binary alloy, Bismuth, Intermetallic compound, Platinum, Stripping voltammetry",

author = "Natalya Shekhovtsova and Glyzina, {Tatyana Svyatoslavovna} and Sergey Romanenko and Nina Kolpakova",

year = "2012",

month = jul,

doi = "10.1007/s10008-012-1730-7",

language = "English",

volume = "16",

pages = "2419--2423",

journal = "Journal of Solid State Electrochemistry",

issn = "1432-8488",

publisher = "Springer Verlag",

number = "7",

}

TY - JOUR

T1 - Estimation of the composition of electrolytically prepared intermetallic bismuth-platinum deposits

AU - Shekhovtsova, Natalya

AU - Glyzina, Tatyana Svyatoslavovna

AU - Romanenko, Sergey

AU - Kolpakova, Nina

PY - 2012/7

Y1 - 2012/7

N2 - The method of partial anodic peak resolution is applied to complex voltammograms. The estimation of the composition of the intermetallic Bi-Pt compounds electrolytically deposited is carried out by a resolution of the components of the voltammograms. It is shown that nonequilibrium conditions take place in electrolytic Bi-Pt deposit when three intermetallic compounds such as: Pt 2Bi 3, PtBi 2, PtBi, and phase of pure Bi exist simultaneously on the electrode.

AB - The method of partial anodic peak resolution is applied to complex voltammograms. The estimation of the composition of the intermetallic Bi-Pt compounds electrolytically deposited is carried out by a resolution of the components of the voltammograms. It is shown that nonequilibrium conditions take place in electrolytic Bi-Pt deposit when three intermetallic compounds such as: Pt 2Bi 3, PtBi 2, PtBi, and phase of pure Bi exist simultaneously on the electrode.

KW - Binary alloy

KW - Bismuth

KW - Intermetallic compound

KW - Platinum

KW - Stripping voltammetry

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U2 - 10.1007/s10008-012-1730-7

DO - 10.1007/s10008-012-1730-7

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VL - 16

SP - 2419

EP - 2423

JO - Journal of Solid State Electrochemistry

JF - Journal of Solid State Electrochemistry

SN - 1432-8488

IS - 7

ER -