Estimation of the composition of electrolytically prepared intermetallic bismuth-platinum deposits

Natalya Shekhovtsova, Tatyana Svyatoslavovna Glyzina, Sergey Romanenko, Nina Kolpakova

Research output: Contribution to journal › Article

Abstract

The method of partial anodic peak resolution is applied to complex voltammograms. The estimation of the composition of the intermetallic Bi-Pt compounds electrolytically deposited is carried out by a resolution of the components of the voltammograms. It is shown that nonequilibrium conditions take place in electrolytic Bi-Pt deposit when three intermetallic compounds such as: Pt ₂Bi ₃, PtBi ₂, PtBi, and phase of pure Bi exist simultaneously on the electrode.

Original language	English
Pages (from-to)	2419-2423
Number of pages	5
Journal	Journal of Solid State Electrochemistry
Volume	16
Issue number	7
DOIs	https://doi.org/10.1007/s10008-012-1730-7
Publication status	Published - Jul 2012

Fingerprint

Keywords

Binary alloy
Bismuth
Intermetallic compound
Platinum
Stripping voltammetry

ASJC Scopus subject areas

Electrochemistry
Electrical and Electronic Engineering
Condensed Matter Physics
Materials Science(all)

Cite this

Shekhovtsova, N., Glyzina, T. S., Romanenko, S., & Kolpakova, N. (2012). Estimation of the composition of electrolytically prepared intermetallic bismuth-platinum deposits. Journal of Solid State Electrochemistry, 16(7), 2419-2423. https://doi.org/10.1007/s10008-012-1730-7

@article{381421a027e04a89b5d9385fb2e8b5ad,

title = "Estimation of the composition of electrolytically prepared intermetallic bismuth-platinum deposits",

abstract = "The method of partial anodic peak resolution is applied to complex voltammograms. The estimation of the composition of the intermetallic Bi-Pt compounds electrolytically deposited is carried out by a resolution of the components of the voltammograms. It is shown that nonequilibrium conditions take place in electrolytic Bi-Pt deposit when three intermetallic compounds such as: Pt 2Bi 3, PtBi 2, PtBi, and phase of pure Bi exist simultaneously on the electrode.",

keywords = "Binary alloy, Bismuth, Intermetallic compound, Platinum, Stripping voltammetry",

author = "Natalya Shekhovtsova and Glyzina, {Tatyana Svyatoslavovna} and Sergey Romanenko and Nina Kolpakova",

year = "2012",

month = jul,

doi = "10.1007/s10008-012-1730-7",

language = "English",

volume = "16",

pages = "2419--2423",

journal = "Journal of Solid State Electrochemistry",

issn = "1432-8488",

publisher = "Springer Verlag",

number = "7",

}

TY - JOUR

T1 - Estimation of the composition of electrolytically prepared intermetallic bismuth-platinum deposits

AU - Shekhovtsova, Natalya

AU - Glyzina, Tatyana Svyatoslavovna

AU - Romanenko, Sergey

AU - Kolpakova, Nina

PY - 2012/7

Y1 - 2012/7

N2 - The method of partial anodic peak resolution is applied to complex voltammograms. The estimation of the composition of the intermetallic Bi-Pt compounds electrolytically deposited is carried out by a resolution of the components of the voltammograms. It is shown that nonequilibrium conditions take place in electrolytic Bi-Pt deposit when three intermetallic compounds such as: Pt 2Bi 3, PtBi 2, PtBi, and phase of pure Bi exist simultaneously on the electrode.

AB - The method of partial anodic peak resolution is applied to complex voltammograms. The estimation of the composition of the intermetallic Bi-Pt compounds electrolytically deposited is carried out by a resolution of the components of the voltammograms. It is shown that nonequilibrium conditions take place in electrolytic Bi-Pt deposit when three intermetallic compounds such as: Pt 2Bi 3, PtBi 2, PtBi, and phase of pure Bi exist simultaneously on the electrode.

KW - Binary alloy

KW - Bismuth

KW - Intermetallic compound

KW - Platinum

KW - Stripping voltammetry

UR - http://www.scopus.com/inward/record.url?scp=84865495258&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84865495258&partnerID=8YFLogxK

U2 - 10.1007/s10008-012-1730-7

DO - 10.1007/s10008-012-1730-7

M3 - Article

AN - SCOPUS:84865495258

VL - 16

SP - 2419

EP - 2423

JO - Journal of Solid State Electrochemistry

JF - Journal of Solid State Electrochemistry

SN - 1432-8488

IS - 7

ER -

Access to Document

10.1007/s10008-012-1730-7