Equilibrium CH acidity of arylacetylenes in dimethyl sulfoxide

M. I. Terekhova, E. S. Petrov, S. F. Vasilevskii, V. F. Ivanov, M. S. Shvartsberg

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Abstract

1. We measured the equilibrium CH acidity in DMSO of a series of para-substituted phenylacetylenes, 1- and 2-ethynylnaphthalene, 3- and 4-ethynylpyridines, and 2-ethynylpyrimidine. 2. A linear correlation between the pK and the Hammett σ constants of the substituents is fulfilled in the series of para-substituted phenylacetylenes and ethynylazines.

Original languageEnglish
Pages (from-to)850-852
Number of pages3
JournalBulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume33
Issue number4
DOIs
Publication statusPublished - 1 Apr 1984
Externally publishedYes

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ASJC Scopus subject areas

  • Chemistry(all)

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