Electronic structure of bridging halogen atoms in metal halide dimers studied by the AMI method and NQR spectroscopy

O. Kh Poleshchuk, B. Nogaj, J. N. Latosińska, J. Koput

    Research output: Contribution to journalArticle

    Abstract

    A nuclear quadrupole resonance (NQR) study of the electronic structure of bridging halogen atoms in dimers of transition and non-transition metal halides has been performed. An explanation of the differences in the NQR frequencies for transition and non-transition metal halides is proposed. The population of the bridging halogen atom orbitals and the metal-halogen bond lengths have been estimated by the AMI method. The aim of this paper was to obtain a relationship describing the lengths of the metal-halogen bonds.

    Original languageEnglish
    Pages (from-to)267-274
    Number of pages8
    JournalSolid State Nuclear Magnetic Resonance
    Volume6
    Issue number3
    DOIs
    Publication statusPublished - Jun 1996

    Fingerprint

    Nuclear quadrupole resonance
    Metal halides
    Halogens
    metal halides
    nuclear quadrupole resonance
    Dimers
    halogens
    Electronic structure
    dimers
    Spectroscopy
    electronic structure
    Atoms
    Bond length
    Metals
    spectroscopy
    atoms
    transition metals
    metals
    orbitals

    Keywords

    • AMI
    • Bridging halogen atom
    • Electronic structure
    • Nuclear quadrupole resonance (NQR)

    ASJC Scopus subject areas

    • Physical and Theoretical Chemistry
    • Spectroscopy
    • Electronic, Optical and Magnetic Materials

    Cite this

    Electronic structure of bridging halogen atoms in metal halide dimers studied by the AMI method and NQR spectroscopy. / Poleshchuk, O. Kh; Nogaj, B.; Latosińska, J. N.; Koput, J.

    In: Solid State Nuclear Magnetic Resonance, Vol. 6, No. 3, 06.1996, p. 267-274.

    Research output: Contribution to journalArticle

    Poleshchuk, O. Kh ; Nogaj, B. ; Latosińska, J. N. ; Koput, J. / Electronic structure of bridging halogen atoms in metal halide dimers studied by the AMI method and NQR spectroscopy. In: Solid State Nuclear Magnetic Resonance. 1996 ; Vol. 6, No. 3. pp. 267-274.
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