Electronic structure of bridging halogen atoms in metal halide dimers studied by the AMI method and NQR spectroscopy

O. Kh Poleshchuk, B. Nogaj, J. N. Latosińska, J. Koput

    Research output: Contribution to journalArticle

    Abstract

    A nuclear quadrupole resonance (NQR) study of the electronic structure of bridging halogen atoms in dimers of transition and non-transition metal halides has been performed. An explanation of the differences in the NQR frequencies for transition and non-transition metal halides is proposed. The population of the bridging halogen atom orbitals and the metal-halogen bond lengths have been estimated by the AMI method. The aim of this paper was to obtain a relationship describing the lengths of the metal-halogen bonds.

    Original languageEnglish
    Pages (from-to)267-274
    Number of pages8
    JournalSolid State Nuclear Magnetic Resonance
    Volume6
    Issue number3
    DOIs
    Publication statusPublished - Jun 1996

    Keywords

    • AMI
    • Bridging halogen atom
    • Electronic structure
    • Nuclear quadrupole resonance (NQR)

    ASJC Scopus subject areas

    • Physical and Theoretical Chemistry
    • Spectroscopy
    • Electronic, Optical and Magnetic Materials

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