Abstract
The charge distribution in the polyfluoroaromatic N,N-dichloroamides and -amines and their hydrocarbon analogues has been established from the X-ray fluorescent ClKα- and SKα-spectra and X-ray photoelectron spectra of chlorine, sulphur and nitrogen in comparoson with data obtained from NQR 35Cl frequencies and semiempirical calculations by CNDO/2. The action of sulphur and selenium on the N,N-dichloroamides of pentafluorobenzenesulphonic acid and pentafluorobenzoic acid leads to the corresponding S,S-dichlorosulphimines and Se,Se-dichloroselenoimines respectively. The polyfluoroaromatic N,N-dichloroamimes have been found to form polyfluorinated trans-azobenzenes under the same conditions. The mechanism of these reactions has been discussed.
| Original language | English |
|---|---|
| Pages (from-to) | 1-14 |
| Number of pages | 14 |
| Journal | Journal of Fluorine Chemistry |
| Volume | 17 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 1981 |
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ASJC Scopus subject areas
- Inorganic Chemistry
- Organic Chemistry
- Materials Chemistry
- Polymers and Plastics
Cite this
Electronic stricture and reactivity of phenyl and pentafluorophenylsubstituted N,N-dichloroamides and -amines. / Dolenko, G. N.; Zibarev, A. V.; Krupoder, S. A.; Mazalov, L. N.; Poleshchuk, O. Ch; Furin, G. G.; Khudorozhko, G. F.; Yakobson, G. G.
In: Journal of Fluorine Chemistry, Vol. 17, No. 1, 1981, p. 1-14.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Electronic stricture and reactivity of phenyl and pentafluorophenylsubstituted N,N-dichloroamides and -amines
AU - Dolenko, G. N.
AU - Zibarev, A. V.
AU - Krupoder, S. A.
AU - Mazalov, L. N.
AU - Poleshchuk, O. Ch
AU - Furin, G. G.
AU - Khudorozhko, G. F.
AU - Yakobson, G. G.
PY - 1981
Y1 - 1981
N2 - The charge distribution in the polyfluoroaromatic N,N-dichloroamides and -amines and their hydrocarbon analogues has been established from the X-ray fluorescent ClKα- and SKα-spectra and X-ray photoelectron spectra of chlorine, sulphur and nitrogen in comparoson with data obtained from NQR 35Cl frequencies and semiempirical calculations by CNDO/2. The action of sulphur and selenium on the N,N-dichloroamides of pentafluorobenzenesulphonic acid and pentafluorobenzoic acid leads to the corresponding S,S-dichlorosulphimines and Se,Se-dichloroselenoimines respectively. The polyfluoroaromatic N,N-dichloroamimes have been found to form polyfluorinated trans-azobenzenes under the same conditions. The mechanism of these reactions has been discussed.
AB - The charge distribution in the polyfluoroaromatic N,N-dichloroamides and -amines and their hydrocarbon analogues has been established from the X-ray fluorescent ClKα- and SKα-spectra and X-ray photoelectron spectra of chlorine, sulphur and nitrogen in comparoson with data obtained from NQR 35Cl frequencies and semiempirical calculations by CNDO/2. The action of sulphur and selenium on the N,N-dichloroamides of pentafluorobenzenesulphonic acid and pentafluorobenzoic acid leads to the corresponding S,S-dichlorosulphimines and Se,Se-dichloroselenoimines respectively. The polyfluoroaromatic N,N-dichloroamimes have been found to form polyfluorinated trans-azobenzenes under the same conditions. The mechanism of these reactions has been discussed.
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UR - http://www.scopus.com/inward/citedby.url?scp=27344460767&partnerID=8YFLogxK
U2 - 10.1016/S0022-1139(00)85246-X
DO - 10.1016/S0022-1139(00)85246-X
M3 - Article
VL - 17
SP - 1
EP - 14
JO - Journal of Fluorine Chemistry
JF - Journal of Fluorine Chemistry
SN - 0022-1139
IS - 1
ER -