Electronic stricture and reactivity of phenyl and pentafluorophenylsubstituted N,N-dichloroamides and -amines

G. N. Dolenko, A. V. Zibarev, S. A. Krupoder, L. N. Mazalov, O. Ch Poleshchuk, G. G. Furin, G. F. Khudorozhko, G. G. Yakobson

    Research output: Contribution to journalArticle

    8 Citations (Scopus)

    Abstract

    The charge distribution in the polyfluoroaromatic N,N-dichloroamides and -amines and their hydrocarbon analogues has been established from the X-ray fluorescent ClKα- and SKα-spectra and X-ray photoelectron spectra of chlorine, sulphur and nitrogen in comparoson with data obtained from NQR 35Cl frequencies and semiempirical calculations by CNDO/2. The action of sulphur and selenium on the N,N-dichloroamides of pentafluorobenzenesulphonic acid and pentafluorobenzoic acid leads to the corresponding S,S-dichlorosulphimines and Se,Se-dichloroselenoimines respectively. The polyfluoroaromatic N,N-dichloroamimes have been found to form polyfluorinated trans-azobenzenes under the same conditions. The mechanism of these reactions has been discussed.

    Original languageEnglish
    Pages (from-to)1-14
    Number of pages14
    JournalJournal of Fluorine Chemistry
    Volume17
    Issue number1
    DOIs
    Publication statusPublished - 1981

    ASJC Scopus subject areas

    • Inorganic Chemistry
    • Organic Chemistry
    • Materials Chemistry
    • Polymers and Plastics

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