Electronic effects of CF<sub>3</sub> group in polyfluorinated toluenes: Infrared, raman, and ultraviolet spectra

Abstract

Relying on analysis of experimental infrared, Raman, and ultraviolet spectra and on calculation of frequencies and forms of normal vibrations of polyfluorinated toluenes these compounds were established to be prone to quinoid structure, and the interaction of the CF₃ group with the polyfluorinated benzene ring was found to occur predominantly through the π-system.

Original language	English
Pages (from-to)	1603-1607
Number of pages	5
Journal	Russian Journal of Organic Chemistry
Volume	39
Issue number	11
DOIs	https://doi.org/10.1023/B:RUJO.0000013134.09771.c7
Publication status	Published - Nov 2003

ASJC Scopus subject areas

Organic Chemistry

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10.1023/B:RUJO.0000013134.09771.c7

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Poleshchuk, O. K., Korobeinicheva, I. K., Fugaeva, O. M., & Furin, G. G. (2003). Electronic effects of CF₃ group in polyfluorinated toluenes: Infrared, raman, and ultraviolet spectra. Russian Journal of Organic Chemistry, 39(11), 1603-1607. https://doi.org/10.1023/B:RUJO.0000013134.09771.c7

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abstract = "Relying on analysis of experimental infrared, Raman, and ultraviolet spectra and on calculation of frequencies and forms of normal vibrations of polyfluorinated toluenes these compounds were established to be prone to quinoid structure, and the interaction of the CF3 group with the polyfluorinated benzene ring was found to occur predominantly through the π-system.",

author = "Poleshchuk, {O. Kh} and Korobeinicheva, {I. K.} and Fugaeva, {O. M.} and Furin, {G. G.}",

year = "2003",

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language = "English",

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T2 - Infrared, raman, and ultraviolet spectra

AU - Poleshchuk, O. Kh

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AU - Fugaeva, O. M.

AU - Furin, G. G.

PY - 2003/11

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N2 - Relying on analysis of experimental infrared, Raman, and ultraviolet spectra and on calculation of frequencies and forms of normal vibrations of polyfluorinated toluenes these compounds were established to be prone to quinoid structure, and the interaction of the CF3 group with the polyfluorinated benzene ring was found to occur predominantly through the π-system.

AB - Relying on analysis of experimental infrared, Raman, and ultraviolet spectra and on calculation of frequencies and forms of normal vibrations of polyfluorinated toluenes these compounds were established to be prone to quinoid structure, and the interaction of the CF3 group with the polyfluorinated benzene ring was found to occur predominantly through the π-system.

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