Electrochemical, quantum-chemical and antioxidant properties of antipyrine and its derivatives

N. V. Bashkatova, E. I. Korotkova, Yu A. Karbainov, A. Yu Yagovkin, A. A. Bakibaev

Research output: Contribution to journalArticle

35 Citations (Scopus)

Abstract

Electrochemical, quantum-chemical and antioxidant properties of antipyrine and its derivatives have been investigated in this work. New quantum-chemical parameter such as difference of formation heats of a molecule and its cation radical (ΔΔHcat) has been used in order to describe properties of the investigated substances. Electrochemical properties (oxidation, reduction potentials) have been investigated. Correlation between the calculated ΔΔHcat and the experimentally obtained oxidation potentials for antipyrine and its derivatives has been found.

Original languageEnglish
Pages (from-to)1143-1147
Number of pages5
JournalJournal of Pharmaceutical and Biomedical Analysis
Volume37
Issue number5
DOIs
Publication statusPublished - 29 Apr 2005

Fingerprint

Antipyrine
Antioxidants
Derivatives
Electrochemical properties
Oxidation-Reduction
Cations
Hot Temperature
Oxidation
Molecules

Keywords

  • Antioxidant
  • Antipyrine
  • Antipyrine derivatives
  • Quantum-chemical parameters
  • Voltammetry

ASJC Scopus subject areas

  • Analytical Chemistry
  • Pharmaceutical Science

Cite this

Electrochemical, quantum-chemical and antioxidant properties of antipyrine and its derivatives. / Bashkatova, N. V.; Korotkova, E. I.; Karbainov, Yu A.; Yagovkin, A. Yu; Bakibaev, A. A.

In: Journal of Pharmaceutical and Biomedical Analysis, Vol. 37, No. 5, 29.04.2005, p. 1143-1147.

Research output: Contribution to journalArticle

Bashkatova, N. V. ; Korotkova, E. I. ; Karbainov, Yu A. ; Yagovkin, A. Yu ; Bakibaev, A. A. / Electrochemical, quantum-chemical and antioxidant properties of antipyrine and its derivatives. In: Journal of Pharmaceutical and Biomedical Analysis. 2005 ; Vol. 37, No. 5. pp. 1143-1147.
@article{f187b4a89c9e44559e0626a8230e953a,
title = "Electrochemical, quantum-chemical and antioxidant properties of antipyrine and its derivatives",
abstract = "Electrochemical, quantum-chemical and antioxidant properties of antipyrine and its derivatives have been investigated in this work. New quantum-chemical parameter such as difference of formation heats of a molecule and its cation radical (ΔΔHcat) has been used in order to describe properties of the investigated substances. Electrochemical properties (oxidation, reduction potentials) have been investigated. Correlation between the calculated ΔΔHcat and the experimentally obtained oxidation potentials for antipyrine and its derivatives has been found.",
keywords = "Antioxidant, Antipyrine, Antipyrine derivatives, Quantum-chemical parameters, Voltammetry",
author = "Bashkatova, {N. V.} and Korotkova, {E. I.} and Karbainov, {Yu A.} and Yagovkin, {A. Yu} and Bakibaev, {A. A.}",
year = "2005",
month = "4",
day = "29",
doi = "10.1016/j.jpba.2004.11.046",
language = "English",
volume = "37",
pages = "1143--1147",
journal = "Journal of Pharmaceutical and Biomedical Analysis",
issn = "0731-7085",
publisher = "Elsevier",
number = "5",

}

TY - JOUR

T1 - Electrochemical, quantum-chemical and antioxidant properties of antipyrine and its derivatives

AU - Bashkatova, N. V.

AU - Korotkova, E. I.

AU - Karbainov, Yu A.

AU - Yagovkin, A. Yu

AU - Bakibaev, A. A.

PY - 2005/4/29

Y1 - 2005/4/29

N2 - Electrochemical, quantum-chemical and antioxidant properties of antipyrine and its derivatives have been investigated in this work. New quantum-chemical parameter such as difference of formation heats of a molecule and its cation radical (ΔΔHcat) has been used in order to describe properties of the investigated substances. Electrochemical properties (oxidation, reduction potentials) have been investigated. Correlation between the calculated ΔΔHcat and the experimentally obtained oxidation potentials for antipyrine and its derivatives has been found.

AB - Electrochemical, quantum-chemical and antioxidant properties of antipyrine and its derivatives have been investigated in this work. New quantum-chemical parameter such as difference of formation heats of a molecule and its cation radical (ΔΔHcat) has been used in order to describe properties of the investigated substances. Electrochemical properties (oxidation, reduction potentials) have been investigated. Correlation between the calculated ΔΔHcat and the experimentally obtained oxidation potentials for antipyrine and its derivatives has been found.

KW - Antioxidant

KW - Antipyrine

KW - Antipyrine derivatives

KW - Quantum-chemical parameters

KW - Voltammetry

UR - http://www.scopus.com/inward/record.url?scp=18144420005&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=18144420005&partnerID=8YFLogxK

U2 - 10.1016/j.jpba.2004.11.046

DO - 10.1016/j.jpba.2004.11.046

M3 - Article

VL - 37

SP - 1143

EP - 1147

JO - Journal of Pharmaceutical and Biomedical Analysis

JF - Journal of Pharmaceutical and Biomedical Analysis

SN - 0731-7085

IS - 5

ER -