Abstract
Electrochemical, quantum-chemical and antioxidant properties of antipyrine and its derivatives have been investigated in this work. New quantum-chemical parameter such as difference of formation heats of a molecule and its cation radical (ΔΔHcat) has been used in order to describe properties of the investigated substances. Electrochemical properties (oxidation, reduction potentials) have been investigated. Correlation between the calculated ΔΔHcat and the experimentally obtained oxidation potentials for antipyrine and its derivatives has been found.
| Original language | English |
|---|---|
| Pages (from-to) | 1143-1147 |
| Number of pages | 5 |
| Journal | Journal of Pharmaceutical and Biomedical Analysis |
| Volume | 37 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - 29 Apr 2005 |
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Keywords
- Antioxidant
- Antipyrine
- Antipyrine derivatives
- Quantum-chemical parameters
- Voltammetry
ASJC Scopus subject areas
- Analytical Chemistry
- Pharmaceutical Science
Cite this
Electrochemical, quantum-chemical and antioxidant properties of antipyrine and its derivatives. / Bashkatova, N. V.; Korotkova, E. I.; Karbainov, Yu A.; Yagovkin, A. Yu; Bakibaev, A. A.
In: Journal of Pharmaceutical and Biomedical Analysis, Vol. 37, No. 5, 29.04.2005, p. 1143-1147.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Electrochemical, quantum-chemical and antioxidant properties of antipyrine and its derivatives
AU - Bashkatova, N. V.
AU - Korotkova, E. I.
AU - Karbainov, Yu A.
AU - Yagovkin, A. Yu
AU - Bakibaev, A. A.
PY - 2005/4/29
Y1 - 2005/4/29
N2 - Electrochemical, quantum-chemical and antioxidant properties of antipyrine and its derivatives have been investigated in this work. New quantum-chemical parameter such as difference of formation heats of a molecule and its cation radical (ΔΔHcat) has been used in order to describe properties of the investigated substances. Electrochemical properties (oxidation, reduction potentials) have been investigated. Correlation between the calculated ΔΔHcat and the experimentally obtained oxidation potentials for antipyrine and its derivatives has been found.
AB - Electrochemical, quantum-chemical and antioxidant properties of antipyrine and its derivatives have been investigated in this work. New quantum-chemical parameter such as difference of formation heats of a molecule and its cation radical (ΔΔHcat) has been used in order to describe properties of the investigated substances. Electrochemical properties (oxidation, reduction potentials) have been investigated. Correlation between the calculated ΔΔHcat and the experimentally obtained oxidation potentials for antipyrine and its derivatives has been found.
KW - Antioxidant
KW - Antipyrine
KW - Antipyrine derivatives
KW - Quantum-chemical parameters
KW - Voltammetry
UR - http://www.scopus.com/inward/record.url?scp=18144420005&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=18144420005&partnerID=8YFLogxK
U2 - 10.1016/j.jpba.2004.11.046
DO - 10.1016/j.jpba.2004.11.046
M3 - Article
VL - 37
SP - 1143
EP - 1147
JO - Journal of Pharmaceutical and Biomedical Analysis
JF - Journal of Pharmaceutical and Biomedical Analysis
SN - 0731-7085
IS - 5
ER -