Efficient synthesis of sulfonyl azides from sulfonamides

Abstract

(Equation Presented) Triflyl azide serves as an efficient diazo transfer reagent in this first direct synthesis of sulfonyl azides from readily available and stable sulfonamides. The process is experimentally simple, mild, and high-yielding. Sulfonyl azides participate in various catalytic transformations providing rapid access to diversely functionalized sulfonamide derivatives in good yields.

Original language	English
Pages (from-to)	3385-3388
Number of pages	4
Journal	Organic Letters
Volume	10
Issue number	16
DOIs	https://doi.org/10.1021/ol8011088
Publication status	Published - 2008
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry
Physical and Theoretical Chemistry
Biochemistry

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10.1021/ol8011088

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Raushel, J., Pitram, S. M., & Fokin, V. V. (2008). Efficient synthesis of sulfonyl azides from sulfonamides. Organic Letters, 10(16), 3385-3388. https://doi.org/10.1021/ol8011088

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title = "Efficient synthesis of sulfonyl azides from sulfonamides",

abstract = "(Equation Presented) Triflyl azide serves as an efficient diazo transfer reagent in this first direct synthesis of sulfonyl azides from readily available and stable sulfonamides. The process is experimentally simple, mild, and high-yielding. Sulfonyl azides participate in various catalytic transformations providing rapid access to diversely functionalized sulfonamide derivatives in good yields.",

author = "Jessica Raushel and Pitram, {Suresh M.} and Fokin, {Valery V.}",

year = "2008",

doi = "10.1021/ol8011088",

language = "English",

volume = "10",

pages = "3385--3388",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "16",

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AU - Pitram, Suresh M.

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Y1 - 2008

N2 - (Equation Presented) Triflyl azide serves as an efficient diazo transfer reagent in this first direct synthesis of sulfonyl azides from readily available and stable sulfonamides. The process is experimentally simple, mild, and high-yielding. Sulfonyl azides participate in various catalytic transformations providing rapid access to diversely functionalized sulfonamide derivatives in good yields.

AB - (Equation Presented) Triflyl azide serves as an efficient diazo transfer reagent in this first direct synthesis of sulfonyl azides from readily available and stable sulfonamides. The process is experimentally simple, mild, and high-yielding. Sulfonyl azides participate in various catalytic transformations providing rapid access to diversely functionalized sulfonamide derivatives in good yields.

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