Efficient synthesis of sulfonyl azides from sulfonamides

Jessica Raushel, Suresh M. Pitram, Valery V. Fokin

Research output: Contribution to journal › Article

Abstract

(Equation Presented) Triflyl azide serves as an efficient diazo transfer reagent in this first direct synthesis of sulfonyl azides from readily available and stable sulfonamides. The process is experimentally simple, mild, and high-yielding. Sulfonyl azides participate in various catalytic transformations providing rapid access to diversely functionalized sulfonamide derivatives in good yields.

Original language	English
Pages (from-to)	3385-3388
Number of pages	4
Journal	Organic Letters
Volume	10
Issue number	16
DOIs	https://doi.org/10.1021/ol8011088
Publication status	Published - 2008
Externally published	Yes

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ASJC Scopus subject areas

Organic Chemistry
Physical and Theoretical Chemistry
Biochemistry

Cite this

Raushel, J., Pitram, S. M., & Fokin, V. V. (2008). Efficient synthesis of sulfonyl azides from sulfonamides. Organic Letters, 10(16), 3385-3388. https://doi.org/10.1021/ol8011088

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N2 - (Equation Presented) Triflyl azide serves as an efficient diazo transfer reagent in this first direct synthesis of sulfonyl azides from readily available and stable sulfonamides. The process is experimentally simple, mild, and high-yielding. Sulfonyl azides participate in various catalytic transformations providing rapid access to diversely functionalized sulfonamide derivatives in good yields.

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Access to Document

10.1021/ol8011088