Efficient one-stage procedure of Beckmann ketones rearrangement in the presence of hydroxylamine

Vera Yurievna Kuksenok, Victoria Victorovna Shtrykova, V. D. Filimonov, S. P. Sidel'nikova

The Kizhner Research Center

Research output: Contribution to journal › Article › peer-review

Abstract

Ketoximes formed from ketones in the presence of hydroxylamine and silica gel in formic acid undergo in situ the Beckmann rearrangement under mild conditions affording in high yields the corresponding amides. Unsymmetrical aromatic ketones, methyl aryl ketones, and methyl cyclohexyl ketone under these conditions form as a rule amides mixtures.

Original language	English
Pages (from-to)	196-199
Number of pages	4
Journal	Russian Journal of Organic Chemistry
Volume	52
Issue number	2
DOIs	https://doi.org/10.1134/S1070428016020056
Publication status	Published - 1 Feb 2016

ASJC Scopus subject areas

Organic Chemistry

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title = "Efficient one-stage procedure of Beckmann ketones rearrangement in the presence of hydroxylamine",

abstract = "Ketoximes formed from ketones in the presence of hydroxylamine and silica gel in formic acid undergo in situ the Beckmann rearrangement under mild conditions affording in high yields the corresponding amides. Unsymmetrical aromatic ketones, methyl aryl ketones, and methyl cyclohexyl ketone under these conditions form as a rule amides mixtures.",

author = "Kuksenok, {Vera Yurievna} and Shtrykova, {Victoria Victorovna} and Filimonov, {V. D.} and Sidel'nikova, {S. P.}",

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AU - Shtrykova, Victoria Victorovna

AU - Filimonov, V. D.

AU - Sidel'nikova, S. P.

PY - 2016/2/1

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AB - Ketoximes formed from ketones in the presence of hydroxylamine and silica gel in formic acid undergo in situ the Beckmann rearrangement under mild conditions affording in high yields the corresponding amides. Unsymmetrical aromatic ketones, methyl aryl ketones, and methyl cyclohexyl ketone under these conditions form as a rule amides mixtures.

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