Efficient one-stage procedure of Beckmann ketones rearrangement in the presence of hydroxylamine

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Abstract

Ketoximes formed from ketones in the presence of hydroxylamine and silica gel in formic acid undergo in situ the Beckmann rearrangement under mild conditions affording in high yields the corresponding amides. Unsymmetrical aromatic ketones, methyl aryl ketones, and methyl cyclohexyl ketone under these conditions form as a rule amides mixtures.

Original languageEnglish
Pages (from-to)196-199
Number of pages4
JournalRussian Journal of Organic Chemistry
Volume52
Issue number2
DOIs
Publication statusPublished - 1 Feb 2016

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Hydroxylamine
Ketones
formic acid
Amides
Oximes
Silica Gel

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

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title = "Efficient one-stage procedure of Beckmann ketones rearrangement in the presence of hydroxylamine",
abstract = "Ketoximes formed from ketones in the presence of hydroxylamine and silica gel in formic acid undergo in situ the Beckmann rearrangement under mild conditions affording in high yields the corresponding amides. Unsymmetrical aromatic ketones, methyl aryl ketones, and methyl cyclohexyl ketone under these conditions form as a rule amides mixtures.",
author = "Kuksenok, {Vera Yurievna} and Shtrykova, {Victoria Victorovna} and Filimonov, {V. D.} and Sidel'nikova, {S. P.}",
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AU - Filimonov, V. D.

AU - Sidel'nikova, S. P.

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