Efficient one-stage procedure of Beckmann ketones rearrangement in the presence of hydroxylamine

Vera Yurievna Kuksenok, Victoria Victorovna Shtrykova, V. D. Filimonov, S. P. Sidel'nikova

The Kizhner Research Center

Research output: Contribution to journal › Article

Abstract

Ketoximes formed from ketones in the presence of hydroxylamine and silica gel in formic acid undergo in situ the Beckmann rearrangement under mild conditions affording in high yields the corresponding amides. Unsymmetrical aromatic ketones, methyl aryl ketones, and methyl cyclohexyl ketone under these conditions form as a rule amides mixtures.

Original language	English
Pages (from-to)	196-199
Number of pages	4
Journal	Russian Journal of Organic Chemistry
Volume	52
Issue number	2
DOIs	https://doi.org/10.1134/S1070428016020056
Publication status	Published - 1 Feb 2016

ASJC Scopus subject areas

Organic Chemistry

Access to Document

10.1134/S1070428016020056

Fingerprint Dive into the research topics of 'Efficient one-stage procedure of Beckmann ketones rearrangement in the presence of hydroxylamine'. Together they form a unique fingerprint.

Cite this

Kuksenok, V. Y., Shtrykova, V. V., Filimonov, V. D., & Sidel'nikova, S. P. (2016). Efficient one-stage procedure of Beckmann ketones rearrangement in the presence of hydroxylamine. Russian Journal of Organic Chemistry, 52(2), 196-199. https://doi.org/10.1134/S1070428016020056

@article{c3b7ca30c3bc40caad0a9c135a5d6cbb,

title = "Efficient one-stage procedure of Beckmann ketones rearrangement in the presence of hydroxylamine",

abstract = "Ketoximes formed from ketones in the presence of hydroxylamine and silica gel in formic acid undergo in situ the Beckmann rearrangement under mild conditions affording in high yields the corresponding amides. Unsymmetrical aromatic ketones, methyl aryl ketones, and methyl cyclohexyl ketone under these conditions form as a rule amides mixtures.",

author = "Kuksenok, {Vera Yurievna} and Shtrykova, {Victoria Victorovna} and Filimonov, {V. D.} and Sidel'nikova, {S. P.}",

year = "2016",

month = feb,

day = "1",

doi = "10.1134/S1070428016020056",

language = "English",

volume = "52",

pages = "196--199",

journal = "Russian Journal of Organic Chemistry",

issn = "1070-4280",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "2",

}

TY - JOUR

T1 - Efficient one-stage procedure of Beckmann ketones rearrangement in the presence of hydroxylamine

AU - Kuksenok, Vera Yurievna

AU - Shtrykova, Victoria Victorovna

AU - Filimonov, V. D.

AU - Sidel'nikova, S. P.

PY - 2016/2/1

Y1 - 2016/2/1

N2 - Ketoximes formed from ketones in the presence of hydroxylamine and silica gel in formic acid undergo in situ the Beckmann rearrangement under mild conditions affording in high yields the corresponding amides. Unsymmetrical aromatic ketones, methyl aryl ketones, and methyl cyclohexyl ketone under these conditions form as a rule amides mixtures.

AB - Ketoximes formed from ketones in the presence of hydroxylamine and silica gel in formic acid undergo in situ the Beckmann rearrangement under mild conditions affording in high yields the corresponding amides. Unsymmetrical aromatic ketones, methyl aryl ketones, and methyl cyclohexyl ketone under these conditions form as a rule amides mixtures.

UR - http://www.scopus.com/inward/record.url?scp=84962376226&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84962376226&partnerID=8YFLogxK

U2 - 10.1134/S1070428016020056

DO - 10.1134/S1070428016020056

M3 - Article

AN - SCOPUS:84962376226

VL - 52

SP - 196

EP - 199

JO - Russian Journal of Organic Chemistry

JF - Russian Journal of Organic Chemistry

SN - 1070-4280

IS - 2

ER -