TY - JOUR
T1 - Efficient one-stage procedure of Beckmann ketones rearrangement in the presence of hydroxylamine
AU - Kuksenok, Vera Yurievna
AU - Shtrykova, Victoria Victorovna
AU - Filimonov, V. D.
AU - Sidel'nikova, S. P.
PY - 2016/2/1
Y1 - 2016/2/1
N2 - Ketoximes formed from ketones in the presence of hydroxylamine and silica gel in formic acid undergo in situ the Beckmann rearrangement under mild conditions affording in high yields the corresponding amides. Unsymmetrical aromatic ketones, methyl aryl ketones, and methyl cyclohexyl ketone under these conditions form as a rule amides mixtures.
AB - Ketoximes formed from ketones in the presence of hydroxylamine and silica gel in formic acid undergo in situ the Beckmann rearrangement under mild conditions affording in high yields the corresponding amides. Unsymmetrical aromatic ketones, methyl aryl ketones, and methyl cyclohexyl ketone under these conditions form as a rule amides mixtures.
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U2 - 10.1134/S1070428016020056
DO - 10.1134/S1070428016020056
M3 - Article
AN - SCOPUS:84962376226
VL - 52
SP - 196
EP - 199
JO - Russian Journal of Organic Chemistry
JF - Russian Journal of Organic Chemistry
SN - 1070-4280
IS - 2
ER -