Abstract
Ketoximes formed from ketones in the presence of hydroxylamine and silica gel in formic acid undergo in situ the Beckmann rearrangement under mild conditions affording in high yields the corresponding amides. Unsymmetrical aromatic ketones, methyl aryl ketones, and methyl cyclohexyl ketone under these conditions form as a rule amides mixtures.
| Original language | English |
|---|---|
| Pages (from-to) | 196-199 |
| Number of pages | 4 |
| Journal | Russian Journal of Organic Chemistry |
| Volume | 52 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - 1 Feb 2016 |
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ASJC Scopus subject areas
- Organic Chemistry
Cite this
Efficient one-stage procedure of Beckmann ketones rearrangement in the presence of hydroxylamine. / Kuksenok, Vera Yurievna; Shtrykova, Victoria Victorovna; Filimonov, V. D.; Sidel'nikova, S. P.
In: Russian Journal of Organic Chemistry, Vol. 52, No. 2, 01.02.2016, p. 196-199.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Efficient one-stage procedure of Beckmann ketones rearrangement in the presence of hydroxylamine
AU - Kuksenok, Vera Yurievna
AU - Shtrykova, Victoria Victorovna
AU - Filimonov, V. D.
AU - Sidel'nikova, S. P.
PY - 2016/2/1
Y1 - 2016/2/1
N2 - Ketoximes formed from ketones in the presence of hydroxylamine and silica gel in formic acid undergo in situ the Beckmann rearrangement under mild conditions affording in high yields the corresponding amides. Unsymmetrical aromatic ketones, methyl aryl ketones, and methyl cyclohexyl ketone under these conditions form as a rule amides mixtures.
AB - Ketoximes formed from ketones in the presence of hydroxylamine and silica gel in formic acid undergo in situ the Beckmann rearrangement under mild conditions affording in high yields the corresponding amides. Unsymmetrical aromatic ketones, methyl aryl ketones, and methyl cyclohexyl ketone under these conditions form as a rule amides mixtures.
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UR - http://www.scopus.com/inward/citedby.url?scp=84962376226&partnerID=8YFLogxK
U2 - 10.1134/S1070428016020056
DO - 10.1134/S1070428016020056
M3 - Article
VL - 52
SP - 196
EP - 199
JO - Russian Journal of Organic Chemistry
JF - Russian Journal of Organic Chemistry
SN - 1070-4280
IS - 2
ER -