Effects of hyperfine splitting of levels in the pressure broadening of the methyl chloride rotational transitions

Abstract

Features of the methyl chloride isotopes ¹²CH₃ ³⁵Cl, ¹²CH₃ ³⁷Cl rotational transitions broadening, associated with the hyperfine splitting of levels due to the nuclear quadrupole interaction, are considered in the framework of impact approximation. The relaxation parameters are calculated and the values of the broadening coefficients are compared with experimental data. The character of the doublet transition contour shape transformation by pressure is investigated.

Original language	English
Pages (from-to)	22-29
Number of pages	8
Journal	Atmospheric and Oceanic Optics
Volume	24
Issue number	1
DOIs	https://doi.org/10.1134/S1024856011010052
Publication status	Published - 1 Feb 2011

ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics
Atmospheric Science
Earth-Surface Processes
Oceanography

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title = "Effects of hyperfine splitting of levels in the pressure broadening of the methyl chloride rotational transitions",

abstract = "Features of the methyl chloride isotopes 12CH3 35Cl, 12CH3 37Cl rotational transitions broadening, associated with the hyperfine splitting of levels due to the nuclear quadrupole interaction, are considered in the framework of impact approximation. The relaxation parameters are calculated and the values of the broadening coefficients are compared with experimental data. The character of the doublet transition contour shape transformation by pressure is investigated.",

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AB - Features of the methyl chloride isotopes 12CH3 35Cl, 12CH3 37Cl rotational transitions broadening, associated with the hyperfine splitting of levels due to the nuclear quadrupole interaction, are considered in the framework of impact approximation. The relaxation parameters are calculated and the values of the broadening coefficients are compared with experimental data. The character of the doublet transition contour shape transformation by pressure is investigated.

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Effects of hyperfine splitting of levels in the pressure broadening of the methyl chloride rotational transitions

Abstract

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