Effective polarizability operator for X2Y-type molecules. Application to line width and line shift calculations of H2O

V. I. Starikov, A. E. Protasevich

    Research output: Contribution to journalArticle

    13 Citations (Scopus)

    Abstract

    The expressions for the second-order rotational correction terms of the effective polarizability operator of asymmetric rotors have been derived using the method of contact transformation. The correction terms have been calculated for the H2O molecule. The influence of the rotational contributions on the halfwidths and shifts of some selected lines of H2O perturbed by the atoms of inert gases and N2 molecule is investigated.

    Original languageEnglish
    Pages (from-to)81-88
    Number of pages8
    JournalJournal of Molecular Structure
    Volume646
    Issue number1-3
    DOIs
    Publication statusPublished - 19 Feb 2003

    Keywords

    • Effective polarizability
    • Line widths and line shifts of HO

    ASJC Scopus subject areas

    • Structural Biology
    • Organic Chemistry
    • Physical and Theoretical Chemistry
    • Spectroscopy
    • Atomic and Molecular Physics, and Optics

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