Abstract
The expressions for the second-order rotational correction terms of the effective polarizability operator of asymmetric rotors have been derived using the method of contact transformation. The correction terms have been calculated for the H2O molecule. The influence of the rotational contributions on the halfwidths and shifts of some selected lines of H2O perturbed by the atoms of inert gases and N2 molecule is investigated.
Original language | English |
---|---|
Pages (from-to) | 81-88 |
Number of pages | 8 |
Journal | Journal of Molecular Structure |
Volume | 646 |
Issue number | 1-3 |
DOIs | |
Publication status | Published - 19 Feb 2003 |
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Keywords
- Effective polarizability
- Line widths and line shifts of HO
ASJC Scopus subject areas
- Structural Biology
- Organic Chemistry
- Physical and Theoretical Chemistry
- Spectroscopy
- Atomic and Molecular Physics, and Optics
Cite this
Effective polarizability operator for X2Y-type molecules. Application to line width and line shift calculations of H2O. / Starikov, V. I.; Protasevich, A. E.
In: Journal of Molecular Structure, Vol. 646, No. 1-3, 19.02.2003, p. 81-88.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Effective polarizability operator for X2Y-type molecules. Application to line width and line shift calculations of H2O
AU - Starikov, V. I.
AU - Protasevich, A. E.
PY - 2003/2/19
Y1 - 2003/2/19
N2 - The expressions for the second-order rotational correction terms of the effective polarizability operator of asymmetric rotors have been derived using the method of contact transformation. The correction terms have been calculated for the H2O molecule. The influence of the rotational contributions on the halfwidths and shifts of some selected lines of H2O perturbed by the atoms of inert gases and N2 molecule is investigated.
AB - The expressions for the second-order rotational correction terms of the effective polarizability operator of asymmetric rotors have been derived using the method of contact transformation. The correction terms have been calculated for the H2O molecule. The influence of the rotational contributions on the halfwidths and shifts of some selected lines of H2O perturbed by the atoms of inert gases and N2 molecule is investigated.
KW - Effective polarizability
KW - Line widths and line shifts of HO
UR - http://www.scopus.com/inward/record.url?scp=0037453985&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0037453985&partnerID=8YFLogxK
U2 - 10.1016/S0022-2860(02)00613-0
DO - 10.1016/S0022-2860(02)00613-0
M3 - Article
AN - SCOPUS:0037453985
VL - 646
SP - 81
EP - 88
JO - Journal of Molecular Structure
JF - Journal of Molecular Structure
SN - 0022-2860
IS - 1-3
ER -