Effective polarizability operator for X2Y-type molecules. Application to line width and line shift calculations of H2O

V. I. Starikov, A. E. Protasevich

    Research output: Contribution to journal › Article

    12 Citations (Scopus)

    Abstract

    The expressions for the second-order rotational correction terms of the effective polarizability operator of asymmetric rotors have been derived using the method of contact transformation. The correction terms have been calculated for the H2O molecule. The influence of the rotational contributions on the halfwidths and shifts of some selected lines of H2O perturbed by the atoms of inert gases and N2 molecule is investigated.

    Original languageEnglish
    Pages (from-to)81-88
    Number of pages8
    JournalJournal of Molecular Structure
    Volume646
    Issue number1-3
    DOIs
    Publication statusPublished - 19 Feb 2003

    Fingerprint

    Noble Gases
    Linewidth
    operators
    Molecules
    shift
    rotors
    molecules
    rare gases
    Rotors
    Atoms
    atoms

    Keywords

    • Effective polarizability
    • Line widths and line shifts of HO

    ASJC Scopus subject areas

    • Structural Biology
    • Organic Chemistry
    • Physical and Theoretical Chemistry
    • Spectroscopy
    • Atomic and Molecular Physics, and Optics

    Cite this

    Effective polarizability operator for X2Y-type molecules. Application to line width and line shift calculations of H2O. / Starikov, V. I.; Protasevich, A. E.

    In: Journal of Molecular Structure, Vol. 646, No. 1-3, 19.02.2003, p. 81-88.

    Research output: Contribution to journal › Article

    Starikov, VI & Protasevich, AE 2003, 'Effective polarizability operator for X2Y-type molecules. Application to line width and line shift calculations of H2O', Journal of Molecular Structure, vol. 646, no. 1-3, pp. 81-88. https://doi.org/10.1016/S0022-2860(02)00613-0
    Starikov VI, Protasevich AE. Effective polarizability operator for X2Y-type molecules. Application to line width and line shift calculations of H2O. Journal of Molecular Structure. 2003 Feb 19;646(1-3):81-88. https://doi.org/10.1016/S0022-2860(02)00613-0
    Starikov, V. I. ; Protasevich, A. E. / Effective polarizability operator for X2Y-type molecules. Application to line width and line shift calculations of H2O. In: Journal of Molecular Structure. 2003 ; Vol. 646, No. 1-3. pp. 81-88.
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