The theory of optically detected ENDOR of radical pairs (RP) recombining in liquid solutions is developed without taking account of the processes of relaxation. The RP spin dynamics is analysed in detail under the conditions of resonant two-frequency pumping of electron and nuclear spins in the particular case of the RP with one and two magnetic equivalent nuclei. Theoretical comparison of the OD ENDOR technique and the OD NMR one shows the advantage of the former method in studying long-lived RP.
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry