Dynamic NMR spectroscopy in studies of the kinetics of photoinduced chemical exchange in solutions

S. P. Babailov

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1 Citation (Scopus)

Abstract

Modern NMR-based methods of studying the kinetics and mechanisms of reversible photochemical reactions in solutions are surveyed. Detailed consideration of peculiar features of the experimental techniques based on NMR lineshape analysis and double resonance NMR and used for the determination of the effective rate constants for and quantum yields of photoinduced chemical exchange processes is presented.

Original languageEnglish
Pages (from-to)1691-1702
Number of pages12
JournalRussian Chemical Bulletin
Volume55
Issue number10
DOIs
Publication statusPublished - Oct 2006
Externally publishedYes

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Keywords

  • Biresonance NMR
  • Double resonance NMR spectroscopy
  • Dynamic NMR spectroscopy
  • NMR lineshape
  • Nuclear Overhauser effect
  • Photochemistry
  • Photoinduced chemical exchange
  • Photoinduced molecular dynamics
  • Photoisomerization
  • Quantum yield
  • Spin saturation transfer

ASJC Scopus subject areas

  • Chemistry(all)

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