Abstract
Modern NMR-based methods of studying the kinetics and mechanisms of reversible photochemical reactions in solutions are surveyed. Detailed consideration of peculiar features of the experimental techniques based on NMR lineshape analysis and double resonance NMR and used for the determination of the effective rate constants for and quantum yields of photoinduced chemical exchange processes is presented.
| Original language | English |
|---|---|
| Pages (from-to) | 1691-1702 |
| Number of pages | 12 |
| Journal | Russian Chemical Bulletin |
| Volume | 55 |
| Issue number | 10 |
| DOIs | |
| Publication status | Published - Oct 2006 |
| Externally published | Yes |
Keywords
- Biresonance NMR
- Double resonance NMR spectroscopy
- Dynamic NMR spectroscopy
- NMR lineshape
- Nuclear Overhauser effect
- Photochemistry
- Photoinduced chemical exchange
- Photoinduced molecular dynamics
- Photoisomerization
- Quantum yield
- Spin saturation transfer
ASJC Scopus subject areas
- Chemistry(all)
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Cite this
Babailov, S. P. (2006). Dynamic NMR spectroscopy in studies of the kinetics of photoinduced chemical exchange in solutions. Russian Chemical Bulletin, 55(10), 1691-1702. https://doi.org/10.1007/s11172-006-0476-8