Dynamic NMR spectroscopy in studies of the kinetics of photoinduced chemical exchange in solutions

S. P. Babailov

Research output: Contribution to journalReview article

1 Citation (Scopus)

Abstract

Modern NMR-based methods of studying the kinetics and mechanisms of reversible photochemical reactions in solutions are surveyed. Detailed consideration of peculiar features of the experimental techniques based on NMR lineshape analysis and double resonance NMR and used for the determination of the effective rate constants for and quantum yields of photoinduced chemical exchange processes is presented.

Original languageEnglish
Pages (from-to)1691-1702
Number of pages12
JournalRussian Chemical Bulletin
Volume55
Issue number10
DOIs
Publication statusPublished - Oct 2006
Externally publishedYes

Fingerprint

Nuclear magnetic resonance spectroscopy
Ion exchange
Nuclear magnetic resonance
Kinetics
Photochemical reactions
Quantum yield
Rate constants

Keywords

  • Biresonance NMR
  • Double resonance NMR spectroscopy
  • Dynamic NMR spectroscopy
  • NMR lineshape
  • Nuclear Overhauser effect
  • Photochemistry
  • Photoinduced chemical exchange
  • Photoinduced molecular dynamics
  • Photoisomerization
  • Quantum yield
  • Spin saturation transfer

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Dynamic NMR spectroscopy in studies of the kinetics of photoinduced chemical exchange in solutions. / Babailov, S. P.

In: Russian Chemical Bulletin, Vol. 55, No. 10, 10.2006, p. 1691-1702.

Research output: Contribution to journalReview article

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