Abstract
Modern NMR-based methods of studying the kinetics and mechanisms of reversible photochemical reactions in solutions are surveyed. Detailed consideration of peculiar features of the experimental techniques based on NMR lineshape analysis and double resonance NMR and used for the determination of the effective rate constants for and quantum yields of photoinduced chemical exchange processes is presented.
| Original language | English |
|---|---|
| Pages (from-to) | 1691-1702 |
| Number of pages | 12 |
| Journal | Russian Chemical Bulletin |
| Volume | 55 |
| Issue number | 10 |
| DOIs | |
| Publication status | Published - Oct 2006 |
| Externally published | Yes |
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Keywords
- Biresonance NMR
- Double resonance NMR spectroscopy
- Dynamic NMR spectroscopy
- NMR lineshape
- Nuclear Overhauser effect
- Photochemistry
- Photoinduced chemical exchange
- Photoinduced molecular dynamics
- Photoisomerization
- Quantum yield
- Spin saturation transfer
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Dynamic NMR spectroscopy in studies of the kinetics of photoinduced chemical exchange in solutions. / Babailov, S. P.
In: Russian Chemical Bulletin, Vol. 55, No. 10, 10.2006, p. 1691-1702.Research output: Contribution to journal › Review article
}
TY - JOUR
T1 - Dynamic NMR spectroscopy in studies of the kinetics of photoinduced chemical exchange in solutions
AU - Babailov, S. P.
PY - 2006/10
Y1 - 2006/10
N2 - Modern NMR-based methods of studying the kinetics and mechanisms of reversible photochemical reactions in solutions are surveyed. Detailed consideration of peculiar features of the experimental techniques based on NMR lineshape analysis and double resonance NMR and used for the determination of the effective rate constants for and quantum yields of photoinduced chemical exchange processes is presented.
AB - Modern NMR-based methods of studying the kinetics and mechanisms of reversible photochemical reactions in solutions are surveyed. Detailed consideration of peculiar features of the experimental techniques based on NMR lineshape analysis and double resonance NMR and used for the determination of the effective rate constants for and quantum yields of photoinduced chemical exchange processes is presented.
KW - Biresonance NMR
KW - Double resonance NMR spectroscopy
KW - Dynamic NMR spectroscopy
KW - NMR lineshape
KW - Nuclear Overhauser effect
KW - Photochemistry
KW - Photoinduced chemical exchange
KW - Photoinduced molecular dynamics
KW - Photoisomerization
KW - Quantum yield
KW - Spin saturation transfer
UR - http://www.scopus.com/inward/record.url?scp=33947150466&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33947150466&partnerID=8YFLogxK
U2 - 10.1007/s11172-006-0476-8
DO - 10.1007/s11172-006-0476-8
M3 - Review article
AN - SCOPUS:33947150466
VL - 55
SP - 1691
EP - 1702
JO - Russian Chemical Bulletin
JF - Russian Chemical Bulletin
SN - 1066-5285
IS - 10
ER -