Dynamic NMR spectroscopy in studies of the kinetics of photoinduced chemical exchange in solutions

Abstract

Modern NMR-based methods of studying the kinetics and mechanisms of reversible photochemical reactions in solutions are surveyed. Detailed consideration of peculiar features of the experimental techniques based on NMR lineshape analysis and double resonance NMR and used for the determination of the effective rate constants for and quantum yields of photoinduced chemical exchange processes is presented.

Original language	English
Pages (from-to)	1691-1702
Number of pages	12
Journal	Russian Chemical Bulletin
Volume	55
Issue number	10
DOIs	https://doi.org/10.1007/s11172-006-0476-8
Publication status	Published - Oct 2006
Externally published	Yes

Keywords

Biresonance NMR
Double resonance NMR spectroscopy
Dynamic NMR spectroscopy
NMR lineshape
Nuclear Overhauser effect
Photochemistry
Photoinduced chemical exchange
Photoinduced molecular dynamics
Photoisomerization
Quantum yield
Spin saturation transfer

ASJC Scopus subject areas

Chemistry(all)

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10.1007/s11172-006-0476-8

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title = "Dynamic NMR spectroscopy in studies of the kinetics of photoinduced chemical exchange in solutions",

abstract = "Modern NMR-based methods of studying the kinetics and mechanisms of reversible photochemical reactions in solutions are surveyed. Detailed consideration of peculiar features of the experimental techniques based on NMR lineshape analysis and double resonance NMR and used for the determination of the effective rate constants for and quantum yields of photoinduced chemical exchange processes is presented.",

keywords = "Biresonance NMR, Double resonance NMR spectroscopy, Dynamic NMR spectroscopy, NMR lineshape, Nuclear Overhauser effect, Photochemistry, Photoinduced chemical exchange, Photoinduced molecular dynamics, Photoisomerization, Quantum yield, Spin saturation transfer",

author = "Babailov, {S. P.}",

year = "2006",

month = oct,

doi = "10.1007/s11172-006-0476-8",

language = "English",

volume = "55",

pages = "1691--1702",

journal = "Russian Chemical Bulletin",

issn = "1066-5285",

publisher = "Springer New York",

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T1 - Dynamic NMR spectroscopy in studies of the kinetics of photoinduced chemical exchange in solutions

AU - Babailov, S. P.

PY - 2006/10

Y1 - 2006/10

N2 - Modern NMR-based methods of studying the kinetics and mechanisms of reversible photochemical reactions in solutions are surveyed. Detailed consideration of peculiar features of the experimental techniques based on NMR lineshape analysis and double resonance NMR and used for the determination of the effective rate constants for and quantum yields of photoinduced chemical exchange processes is presented.

AB - Modern NMR-based methods of studying the kinetics and mechanisms of reversible photochemical reactions in solutions are surveyed. Detailed consideration of peculiar features of the experimental techniques based on NMR lineshape analysis and double resonance NMR and used for the determination of the effective rate constants for and quantum yields of photoinduced chemical exchange processes is presented.

KW - Biresonance NMR

KW - Double resonance NMR spectroscopy

KW - Dynamic NMR spectroscopy

KW - NMR lineshape

KW - Nuclear Overhauser effect

KW - Photochemistry

KW - Photoinduced chemical exchange

KW - Photoinduced molecular dynamics

KW - Photoisomerization

KW - Quantum yield

KW - Spin saturation transfer

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U2 - 10.1007/s11172-006-0476-8

DO - 10.1007/s11172-006-0476-8

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EP - 1702

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 10