Dynamic NMR spectroscopy in studies of the kinetics of photoinduced chemical exchange in solutions

S. P. Babailov

Research output: Contribution to journal › Review article

Abstract

Modern NMR-based methods of studying the kinetics and mechanisms of reversible photochemical reactions in solutions are surveyed. Detailed consideration of peculiar features of the experimental techniques based on NMR lineshape analysis and double resonance NMR and used for the determination of the effective rate constants for and quantum yields of photoinduced chemical exchange processes is presented.

Original language	English
Pages (from-to)	1691-1702
Number of pages	12
Journal	Russian Chemical Bulletin
Volume	55
Issue number	10
DOIs	https://doi.org/10.1007/s11172-006-0476-8
Publication status	Published - Oct 2006
Externally published	Yes

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Keywords

Biresonance NMR
Double resonance NMR spectroscopy
Dynamic NMR spectroscopy
NMR lineshape
Nuclear Overhauser effect
Photochemistry
Photoinduced chemical exchange
Photoinduced molecular dynamics
Photoisomerization
Quantum yield
Spin saturation transfer

ASJC Scopus subject areas

Chemistry(all)

Cite this

Babailov, S. P. (2006). Dynamic NMR spectroscopy in studies of the kinetics of photoinduced chemical exchange in solutions. Russian Chemical Bulletin, 55(10), 1691-1702. https://doi.org/10.1007/s11172-006-0476-8

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Access to Document

10.1007/s11172-006-0476-8