"donor-acceptor" oligogermanes: Synthesis, structure, and electronic properties

Kirill V. Zaitsev, Andrey A. Kapranov, Andrei V. Churakov, Oleg Kh Poleshchuk, Yuri F. Oprunenko, Boris N. Tarasevich, Galina S. Zaitseva, Sergey S. Karlov

    Research output: Contribution to journalArticle

    25 Citations (Scopus)

    Abstract

    A series of oligogermanes, (Me3Si)3GeGeCl 3, (C6F5)3GeGePh3, (C6F5)3GeGe(p-Tol)3, and (C 6F5)2Ge[Ge(p-Tol)3]2, containing substituents with different electronic properties at neighboring germanium atoms were synthesized. According to X-ray diffraction studies, UV/visible spectroscopy, and quantum chemical calculations, these "donor-acceptor" oligogermanes are characterized by energies of electronic transitions lower than those for other similar compounds.

    Original languageEnglish
    Pages (from-to)6500-6510
    Number of pages11
    JournalOrganometallics
    Volume32
    Issue number21
    DOIs
    Publication statusPublished - 11 Nov 2013

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    Germanium
    Electronic properties
    Spectroscopy
    X ray diffraction
    Atoms
    synthesis
    electronics
    germanium
    diffraction
    spectroscopy
    atoms
    x rays
    energy

    ASJC Scopus subject areas

    • Organic Chemistry
    • Physical and Theoretical Chemistry
    • Inorganic Chemistry

    Cite this

    Zaitsev, K. V., Kapranov, A. A., Churakov, A. V., Poleshchuk, O. K., Oprunenko, Y. F., Tarasevich, B. N., ... Karlov, S. S. (2013). "donor-acceptor" oligogermanes: Synthesis, structure, and electronic properties. Organometallics, 32(21), 6500-6510. https://doi.org/10.1021/om4008218

    "donor-acceptor" oligogermanes : Synthesis, structure, and electronic properties. / Zaitsev, Kirill V.; Kapranov, Andrey A.; Churakov, Andrei V.; Poleshchuk, Oleg Kh; Oprunenko, Yuri F.; Tarasevich, Boris N.; Zaitseva, Galina S.; Karlov, Sergey S.

    In: Organometallics, Vol. 32, No. 21, 11.11.2013, p. 6500-6510.

    Research output: Contribution to journalArticle

    Zaitsev, KV, Kapranov, AA, Churakov, AV, Poleshchuk, OK, Oprunenko, YF, Tarasevich, BN, Zaitseva, GS & Karlov, SS 2013, '"donor-acceptor" oligogermanes: Synthesis, structure, and electronic properties', Organometallics, vol. 32, no. 21, pp. 6500-6510. https://doi.org/10.1021/om4008218
    Zaitsev KV, Kapranov AA, Churakov AV, Poleshchuk OK, Oprunenko YF, Tarasevich BN et al. "donor-acceptor" oligogermanes: Synthesis, structure, and electronic properties. Organometallics. 2013 Nov 11;32(21):6500-6510. https://doi.org/10.1021/om4008218
    Zaitsev, Kirill V. ; Kapranov, Andrey A. ; Churakov, Andrei V. ; Poleshchuk, Oleg Kh ; Oprunenko, Yuri F. ; Tarasevich, Boris N. ; Zaitseva, Galina S. ; Karlov, Sergey S. / "donor-acceptor" oligogermanes : Synthesis, structure, and electronic properties. In: Organometallics. 2013 ; Vol. 32, No. 21. pp. 6500-6510.
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    abstract = "A series of oligogermanes, (Me3Si)3GeGeCl 3, (C6F5)3GeGePh3, (C6F5)3GeGe(p-Tol)3, and (C 6F5)2Ge[Ge(p-Tol)3]2, containing substituents with different electronic properties at neighboring germanium atoms were synthesized. According to X-ray diffraction studies, UV/visible spectroscopy, and quantum chemical calculations, these {"}donor-acceptor{"} oligogermanes are characterized by energies of electronic transitions lower than those for other similar compounds.",
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