Abstract
A series of oligogermanes, (Me3Si)3GeGeCl 3, (C6F5)3GeGePh3, (C6F5)3GeGe(p-Tol)3, and (C 6F5)2Ge[Ge(p-Tol)3]2, containing substituents with different electronic properties at neighboring germanium atoms were synthesized. According to X-ray diffraction studies, UV/visible spectroscopy, and quantum chemical calculations, these "donor-acceptor" oligogermanes are characterized by energies of electronic transitions lower than those for other similar compounds.
Original language | English |
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Pages (from-to) | 6500-6510 |
Number of pages | 11 |
Journal | Organometallics |
Volume | 32 |
Issue number | 21 |
DOIs | |
Publication status | Published - 11 Nov 2013 |
ASJC Scopus subject areas
- Organic Chemistry
- Physical and Theoretical Chemistry
- Inorganic Chemistry