"donor-acceptor" oligogermanes: Synthesis, structure, and electronic properties

Kirill V. Zaitsev, Andrey A. Kapranov, Andrei V. Churakov, Oleg Kh Poleshchuk, Yuri F. Oprunenko, Boris N. Tarasevich, Galina S. Zaitseva, Sergey S. Karlov

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26 Citations (Scopus)

Abstract

A series of oligogermanes, (Me₃Si)₃GeGeCl ₃, (C₆F₅)₃GeGePh₃, (C₆F₅)₃GeGe(p-Tol)₃, and (C ₆F₅)₂Ge[Ge(p-Tol)₃]₂, containing substituents with different electronic properties at neighboring germanium atoms were synthesized. According to X-ray diffraction studies, UV/visible spectroscopy, and quantum chemical calculations, these "donor-acceptor" oligogermanes are characterized by energies of electronic transitions lower than those for other similar compounds.

Original language	English
Pages (from-to)	6500-6510
Number of pages	11
Journal	Organometallics
Volume	32
Issue number	21
DOIs	https://doi.org/10.1021/om4008218
Publication status	Published - 11 Nov 2013

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ASJC Scopus subject areas

Organic Chemistry
Physical and Theoretical Chemistry
Inorganic Chemistry

Cite this

Zaitsev, K. V., Kapranov, A. A., Churakov, A. V., Poleshchuk, O. K., Oprunenko, Y. F., Tarasevich, B. N., Zaitseva, G. S., & Karlov, S. S. (2013). "donor-acceptor" oligogermanes: Synthesis, structure, and electronic properties. Organometallics, 32(21), 6500-6510. https://doi.org/10.1021/om4008218

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title = "{"}donor-acceptor{"} oligogermanes: Synthesis, structure, and electronic properties",

abstract = "A series of oligogermanes, (Me3Si)3GeGeCl 3, (C6F5)3GeGePh3, (C6F5)3GeGe(p-Tol)3, and (C 6F5)2Ge[Ge(p-Tol)3]2, containing substituents with different electronic properties at neighboring germanium atoms were synthesized. According to X-ray diffraction studies, UV/visible spectroscopy, and quantum chemical calculations, these {"}donor-acceptor{"} oligogermanes are characterized by energies of electronic transitions lower than those for other similar compounds.",

author = "Zaitsev, {Kirill V.} and Kapranov, {Andrey A.} and Churakov, {Andrei V.} and Poleshchuk, {Oleg Kh} and Oprunenko, {Yuri F.} and Tarasevich, {Boris N.} and Zaitseva, {Galina S.} and Karlov, {Sergey S.}",

year = "2013",

month = nov

day = "11",

doi = "10.1021/om4008218",

language = "English",

volume = "32",

pages = "6500--6510",

journal = "Organometallics",

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publisher = "American Chemical Society",

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TY - JOUR

T1 - "donor-acceptor" oligogermanes

T2 - Synthesis, structure, and electronic properties

AU - Zaitsev, Kirill V.

AU - Kapranov, Andrey A.

AU - Churakov, Andrei V.

AU - Poleshchuk, Oleg Kh

AU - Oprunenko, Yuri F.

AU - Tarasevich, Boris N.

AU - Zaitseva, Galina S.

AU - Karlov, Sergey S.

PY - 2013/11/11

Y1 - 2013/11/11

N2 - A series of oligogermanes, (Me3Si)3GeGeCl 3, (C6F5)3GeGePh3, (C6F5)3GeGe(p-Tol)3, and (C 6F5)2Ge[Ge(p-Tol)3]2, containing substituents with different electronic properties at neighboring germanium atoms were synthesized. According to X-ray diffraction studies, UV/visible spectroscopy, and quantum chemical calculations, these "donor-acceptor" oligogermanes are characterized by energies of electronic transitions lower than those for other similar compounds.

AB - A series of oligogermanes, (Me3Si)3GeGeCl 3, (C6F5)3GeGePh3, (C6F5)3GeGe(p-Tol)3, and (C 6F5)2Ge[Ge(p-Tol)3]2, containing substituents with different electronic properties at neighboring germanium atoms were synthesized. According to X-ray diffraction studies, UV/visible spectroscopy, and quantum chemical calculations, these "donor-acceptor" oligogermanes are characterized by energies of electronic transitions lower than those for other similar compounds.

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Access to Document

10.1021/om4008218