"donor-acceptor" oligogermanes: Synthesis, structure, and electronic properties

Kirill V. Zaitsev, Andrey A. Kapranov, Andrei V. Churakov, Oleg Kh Poleshchuk, Yuri F. Oprunenko, Boris N. Tarasevich, Galina S. Zaitseva, Sergey S. Karlov

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26 Citations (Scopus)

Abstract

A series of oligogermanes, (Me₃Si)₃GeGeCl ₃, (C₆F₅)₃GeGePh₃, (C₆F₅)₃GeGe(p-Tol)₃, and (C ₆F₅)₂Ge[Ge(p-Tol)₃]₂, containing substituents with different electronic properties at neighboring germanium atoms were synthesized. According to X-ray diffraction studies, UV/visible spectroscopy, and quantum chemical calculations, these "donor-acceptor" oligogermanes are characterized by energies of electronic transitions lower than those for other similar compounds.

Original language	English
Pages (from-to)	6500-6510
Number of pages	11
Journal	Organometallics
Volume	32
Issue number	21
DOIs	https://doi.org/10.1021/om4008218
Publication status	Published - 11 Nov 2013

ASJC Scopus subject areas

Organic Chemistry
Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/om4008218

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Zaitsev, K. V., Kapranov, A. A., Churakov, A. V., Poleshchuk, O. K., Oprunenko, Y. F., Tarasevich, B. N., Zaitseva, G. S., & Karlov, S. S. (2013). "donor-acceptor" oligogermanes: Synthesis, structure, and electronic properties. Organometallics, 32(21), 6500-6510. https://doi.org/10.1021/om4008218

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title = "{"}donor-acceptor{"} oligogermanes: Synthesis, structure, and electronic properties",

abstract = "A series of oligogermanes, (Me3Si)3GeGeCl 3, (C6F5)3GeGePh3, (C6F5)3GeGe(p-Tol)3, and (C 6F5)2Ge[Ge(p-Tol)3]2, containing substituents with different electronic properties at neighboring germanium atoms were synthesized. According to X-ray diffraction studies, UV/visible spectroscopy, and quantum chemical calculations, these {"}donor-acceptor{"} oligogermanes are characterized by energies of electronic transitions lower than those for other similar compounds.",

author = "Zaitsev, {Kirill V.} and Kapranov, {Andrey A.} and Churakov, {Andrei V.} and Poleshchuk, {Oleg Kh} and Oprunenko, {Yuri F.} and Tarasevich, {Boris N.} and Zaitseva, {Galina S.} and Karlov, {Sergey S.}",

year = "2013",

month = nov,

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doi = "10.1021/om4008218",

language = "English",

volume = "32",

pages = "6500--6510",

journal = "Organometallics",

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T2 - Synthesis, structure, and electronic properties

AU - Zaitsev, Kirill V.

AU - Kapranov, Andrey A.

AU - Churakov, Andrei V.

AU - Poleshchuk, Oleg Kh

AU - Oprunenko, Yuri F.

AU - Tarasevich, Boris N.

AU - Zaitseva, Galina S.

AU - Karlov, Sergey S.

PY - 2013/11/11

Y1 - 2013/11/11

N2 - A series of oligogermanes, (Me3Si)3GeGeCl 3, (C6F5)3GeGePh3, (C6F5)3GeGe(p-Tol)3, and (C 6F5)2Ge[Ge(p-Tol)3]2, containing substituents with different electronic properties at neighboring germanium atoms were synthesized. According to X-ray diffraction studies, UV/visible spectroscopy, and quantum chemical calculations, these "donor-acceptor" oligogermanes are characterized by energies of electronic transitions lower than those for other similar compounds.

AB - A series of oligogermanes, (Me3Si)3GeGeCl 3, (C6F5)3GeGePh3, (C6F5)3GeGe(p-Tol)3, and (C 6F5)2Ge[Ge(p-Tol)3]2, containing substituents with different electronic properties at neighboring germanium atoms were synthesized. According to X-ray diffraction studies, UV/visible spectroscopy, and quantum chemical calculations, these "donor-acceptor" oligogermanes are characterized by energies of electronic transitions lower than those for other similar compounds.

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