Distinctive features of the electronic structure of tetrachloride titanium complexes

Abstract

The paper reports results of measurements of the C1Kα shifts in the X- ray fluorescence spectra and ³⁵Cl-NQR frequency for a group of tetrachloride titanium complexes. The experimental C1Kα shifts were correlated with the parameters describing donor properties of ligands such as ligand strength (DN), ionisation potential (IP) or parameters of influence (P). Analysis of the correlation dependencies has indicated that changes in the electronic density on the chloride atom of the acceptor, taking place upon complexation, are determined by the polarisation effects. (C) 2000 Elsevier Science B.V.

Original language	English
Pages (from-to)	201-208
Number of pages	8
Journal	Journal of Molecular Structure
Volume	522
Issue number	1-3
DOIs	https://doi.org/10.1016/S0022-2860(99)00361-0
Publication status	Published - 11 Apr 2000

Keywords

Electronic structure
TiCl complexes

ASJC Scopus subject areas

Analytical Chemistry
Spectroscopy
Organic Chemistry
Inorganic Chemistry

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10.1016/S0022-2860(99)00361-0

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title = "Distinctive features of the electronic structure of tetrachloride titanium complexes",

abstract = "The paper reports results of measurements of the C1Kα shifts in the X- ray fluorescence spectra and 35Cl-NQR frequency for a group of tetrachloride titanium complexes. The experimental C1Kα shifts were correlated with the parameters describing donor properties of ligands such as ligand strength (DN), ionisation potential (IP) or parameters of influence (P). Analysis of the correlation dependencies has indicated that changes in the electronic density on the chloride atom of the acceptor, taking place upon complexation, are determined by the polarisation effects. (C) 2000 Elsevier Science B.V.",

keywords = "Electronic structure, TiCl complexes",

author = "Dolenko, {G. N.} and Poleshchuk, {O. Kh} and Gostewskii, {B. A.} and Latosinska, {J. N.} and M. Ostafin",

year = "2000",

month = apr,

day = "11",

doi = "10.1016/S0022-2860(99)00361-0",

language = "English",

volume = "522",

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journal = "Journal of Molecular Structure",

issn = "0022-2860",

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number = "1-3",

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T1 - Distinctive features of the electronic structure of tetrachloride titanium complexes

AU - Dolenko, G. N.

AU - Poleshchuk, O. Kh

AU - Gostewskii, B. A.

AU - Latosinska, J. N.

AU - Ostafin, M.

PY - 2000/4/11

Y1 - 2000/4/11

N2 - The paper reports results of measurements of the C1Kα shifts in the X- ray fluorescence spectra and 35Cl-NQR frequency for a group of tetrachloride titanium complexes. The experimental C1Kα shifts were correlated with the parameters describing donor properties of ligands such as ligand strength (DN), ionisation potential (IP) or parameters of influence (P). Analysis of the correlation dependencies has indicated that changes in the electronic density on the chloride atom of the acceptor, taking place upon complexation, are determined by the polarisation effects. (C) 2000 Elsevier Science B.V.

AB - The paper reports results of measurements of the C1Kα shifts in the X- ray fluorescence spectra and 35Cl-NQR frequency for a group of tetrachloride titanium complexes. The experimental C1Kα shifts were correlated with the parameters describing donor properties of ligands such as ligand strength (DN), ionisation potential (IP) or parameters of influence (P). Analysis of the correlation dependencies has indicated that changes in the electronic density on the chloride atom of the acceptor, taking place upon complexation, are determined by the polarisation effects. (C) 2000 Elsevier Science B.V.

KW - Electronic structure

KW - TiCl complexes

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JF - Journal of Molecular Structure

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