Distinctive features of the electronic structure of tetrachloride titanium complexes

G. N. Dolenko, O. Kh Poleshchuk, B. A. Gostewskii, J. N. Latosinska, M. Ostafin

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    Abstract

    The paper reports results of measurements of the C1Kα shifts in the X- ray fluorescence spectra and 35Cl-NQR frequency for a group of tetrachloride titanium complexes. The experimental C1Kα shifts were correlated with the parameters describing donor properties of ligands such as ligand strength (DN), ionisation potential (IP) or parameters of influence (P). Analysis of the correlation dependencies has indicated that changes in the electronic density on the chloride atom of the acceptor, taking place upon complexation, are determined by the polarisation effects. (C) 2000 Elsevier Science B.V.

    Original languageEnglish
    Pages (from-to)201-208
    Number of pages8
    JournalJournal of Molecular Structure
    Volume522
    Issue number1-3
    DOIs
    Publication statusPublished - 11 Apr 2000

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    Keywords

    • Electronic structure
    • TiCl complexes

    ASJC Scopus subject areas

    • Analytical Chemistry
    • Spectroscopy
    • Organic Chemistry
    • Inorganic Chemistry

    Cite this

    Dolenko, G. N., Poleshchuk, O. K., Gostewskii, B. A., Latosinska, J. N., & Ostafin, M. (2000). Distinctive features of the electronic structure of tetrachloride titanium complexes. Journal of Molecular Structure, 522(1-3), 201-208. https://doi.org/10.1016/S0022-2860(99)00361-0