Direct iodination of 3- and 4-nitropyrazoles with a reagent based on iodine monochloride and silver sulfate

V. K. Chaikovskii, T. S. Kharlova, E. V. Tretyakov, S. F. Vasilevsky, V. D. Filimonov

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The reagent obtained from iodine monochloride and silver sulfate in sulfuric acid easily iodinates 1-methyl-3-nitropyrazole under mild conditions to give 4-iodo or 4,5-diiodo derivatives. 1-Methyl-4-nitropyrazole was also directly iodinated with this reagent for the first time.

Original languageEnglish
Pages (from-to)1475-1477
Number of pages3
JournalRussian Chemical Bulletin
Volume49
Issue number8
DOIs
Publication statusPublished - 1 Jan 2000

Fingerprint

Silver
Sulfates
Derivatives
iodine monochloride
3-nitropyrazole
sulfuric acid

Keywords

  • Iodination
  • Iodine monochloride
  • Iodomethylnitro-pyrazoles
  • Methylnitropyrazoles

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Direct iodination of 3- and 4-nitropyrazoles with a reagent based on iodine monochloride and silver sulfate. / Chaikovskii, V. K.; Kharlova, T. S.; Tretyakov, E. V.; Vasilevsky, S. F.; Filimonov, V. D.

In: Russian Chemical Bulletin, Vol. 49, No. 8, 01.01.2000, p. 1475-1477.

Research output: Contribution to journalArticle

Chaikovskii, V. K. ; Kharlova, T. S. ; Tretyakov, E. V. ; Vasilevsky, S. F. ; Filimonov, V. D. / Direct iodination of 3- and 4-nitropyrazoles with a reagent based on iodine monochloride and silver sulfate. In: Russian Chemical Bulletin. 2000 ; Vol. 49, No. 8. pp. 1475-1477.
@article{a387dcc627da47acb20f50f2f35c9d00,
title = "Direct iodination of 3- and 4-nitropyrazoles with a reagent based on iodine monochloride and silver sulfate",
abstract = "The reagent obtained from iodine monochloride and silver sulfate in sulfuric acid easily iodinates 1-methyl-3-nitropyrazole under mild conditions to give 4-iodo or 4,5-diiodo derivatives. 1-Methyl-4-nitropyrazole was also directly iodinated with this reagent for the first time.",
keywords = "Iodination, Iodine monochloride, Iodomethylnitro-pyrazoles, Methylnitropyrazoles",
author = "Chaikovskii, {V. K.} and Kharlova, {T. S.} and Tretyakov, {E. V.} and Vasilevsky, {S. F.} and Filimonov, {V. D.}",
year = "2000",
month = "1",
day = "1",
doi = "10.1007/BF02495102",
language = "English",
volume = "49",
pages = "1475--1477",
journal = "Russian Chemical Bulletin",
issn = "0568-5230",
publisher = "Consultants Bureau",
number = "8",

}

TY - JOUR

T1 - Direct iodination of 3- and 4-nitropyrazoles with a reagent based on iodine monochloride and silver sulfate

AU - Chaikovskii, V. K.

AU - Kharlova, T. S.

AU - Tretyakov, E. V.

AU - Vasilevsky, S. F.

AU - Filimonov, V. D.

PY - 2000/1/1

Y1 - 2000/1/1

N2 - The reagent obtained from iodine monochloride and silver sulfate in sulfuric acid easily iodinates 1-methyl-3-nitropyrazole under mild conditions to give 4-iodo or 4,5-diiodo derivatives. 1-Methyl-4-nitropyrazole was also directly iodinated with this reagent for the first time.

AB - The reagent obtained from iodine monochloride and silver sulfate in sulfuric acid easily iodinates 1-methyl-3-nitropyrazole under mild conditions to give 4-iodo or 4,5-diiodo derivatives. 1-Methyl-4-nitropyrazole was also directly iodinated with this reagent for the first time.

KW - Iodination

KW - Iodine monochloride

KW - Iodomethylnitro-pyrazoles

KW - Methylnitropyrazoles

UR - http://www.scopus.com/inward/record.url?scp=0034342728&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0034342728&partnerID=8YFLogxK

U2 - 10.1007/BF02495102

DO - 10.1007/BF02495102

M3 - Article

AN - SCOPUS:0034342728

VL - 49

SP - 1475

EP - 1477

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 0568-5230

IS - 8

ER -