Dipyridine Salts of closo-Borate Anions B6H6 2- and B12H12 2-

Abstract

Dipyridine salts [HBipy]₂B₁₂H₁₂ and [HBipy]B₆H₇ were synthesized and studied by IR spectroscopy. An X-ray diffraction study of [HBipy]₂B₁₂H₁₂ was carried out. The crystals are triclinic, space group p 1̄, a = 8.689(3) Å, b = 8.838(2) Å, c = 9.397(3) Å, α = 93.66(2)°, β = 112.04(3)°, γ= 109.19(2)°, V= 617.1(4) Å³, Z = 1. The IR spectral data show that the hydrogen atom of the NH group of the dipyridine cation forms local multicenter bonds with the boron atoms of the closo-dodecahydroborate anion. The spectral data imply that the 7 hexaborate dipyridine salt synthesized contains the closo-B₆7^- anion; this is in accordance with the data of the elemental analysis.

Original language	English
Pages (from-to)	1525-1530
Number of pages	6
Journal	Russian Journal of Inorganic Chemistry
Volume	41
Issue number	10
Publication status	Published - 1996
Externally published	Yes

ASJC Scopus subject areas

Materials Science (miscellaneous)
Physical and Theoretical Chemistry
Inorganic Chemistry

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Dipyridine Salts of closo-Borate Anions B₆H₆ ^2- and B₁₂H₁₂ ^2-. / Orlova, A. M.; Mustyatsa, V. N.; Goeva, L. V.; Kaiser, S. B.; Lagun, V. L.; Solntsev, K. A.; Kuznetsov, N. T.

In: Russian Journal of Inorganic Chemistry, Vol. 41, No. 10, 1996, p. 1525-1530.

Research output: Contribution to journal › Article › peer-review

@article{dddbc3b7f7c44852ac341a54021e0a8b,

title = "Dipyridine Salts of closo-Borate Anions B6H6 2- and B12H12 2-",

abstract = "Dipyridine salts [HBipy]2B12H12 and [HBipy]B6H7 were synthesized and studied by IR spectroscopy. An X-ray diffraction study of [HBipy]2B12H12 was carried out. The crystals are triclinic, space group p {\=1}, a = 8.689(3) {\AA}, b = 8.838(2) {\AA}, c = 9.397(3) {\AA}, α = 93.66(2)°, β = 112.04(3)°, γ= 109.19(2)°, V= 617.1(4) {\AA}3, Z = 1. The IR spectral data show that the hydrogen atom of the NH group of the dipyridine cation forms local multicenter bonds with the boron atoms of the closo-dodecahydroborate anion. The spectral data imply that the 7 hexaborate dipyridine salt synthesized contains the closo-B67- anion; this is in accordance with the data of the elemental analysis.",

author = "Orlova, {A. M.} and Mustyatsa, {V. N.} and Goeva, {L. V.} and Kaiser, {S. B.} and Lagun, {V. L.} and Solntsev, {K. A.} and Kuznetsov, {N. T.}",

year = "1996",

language = "English",

volume = "41",

pages = "1525--1530",

journal = "Russian Journal of Inorganic Chemistry",

issn = "0036-0236",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "10",

}

TY - JOUR

T1 - Dipyridine Salts of closo-Borate Anions B6H6 2- and B12H12 2-

AU - Orlova, A. M.

AU - Mustyatsa, V. N.

AU - Goeva, L. V.

AU - Kaiser, S. B.

AU - Lagun, V. L.

AU - Solntsev, K. A.

AU - Kuznetsov, N. T.

PY - 1996

Y1 - 1996

N2 - Dipyridine salts [HBipy]2B12H12 and [HBipy]B6H7 were synthesized and studied by IR spectroscopy. An X-ray diffraction study of [HBipy]2B12H12 was carried out. The crystals are triclinic, space group p 1̄, a = 8.689(3) Å, b = 8.838(2) Å, c = 9.397(3) Å, α = 93.66(2)°, β = 112.04(3)°, γ= 109.19(2)°, V= 617.1(4) Å3, Z = 1. The IR spectral data show that the hydrogen atom of the NH group of the dipyridine cation forms local multicenter bonds with the boron atoms of the closo-dodecahydroborate anion. The spectral data imply that the 7 hexaborate dipyridine salt synthesized contains the closo-B67- anion; this is in accordance with the data of the elemental analysis.

AB - Dipyridine salts [HBipy]2B12H12 and [HBipy]B6H7 were synthesized and studied by IR spectroscopy. An X-ray diffraction study of [HBipy]2B12H12 was carried out. The crystals are triclinic, space group p 1̄, a = 8.689(3) Å, b = 8.838(2) Å, c = 9.397(3) Å, α = 93.66(2)°, β = 112.04(3)°, γ= 109.19(2)°, V= 617.1(4) Å3, Z = 1. The IR spectral data show that the hydrogen atom of the NH group of the dipyridine cation forms local multicenter bonds with the boron atoms of the closo-dodecahydroborate anion. The spectral data imply that the 7 hexaborate dipyridine salt synthesized contains the closo-B67- anion; this is in accordance with the data of the elemental analysis.

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JO - Russian Journal of Inorganic Chemistry

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