Abstract
The transformed dipole moment of C//3//v molecules has been worked out up to second order of approximation on the basis of its invariance properties. Its dependence on the total angular momentum components has been made explicit. The dipole moment matrix has been written with a view to calculate vibration-rotation intensities in the case of strongly interacting vibrational polyads. The importance of a coherent phase system for correct intensity calculations has been emphasized.
| Original language | English |
|---|---|
| Pages (from-to) | 1429-1447 |
| Number of pages | 19 |
| Journal | Journal de physique Paris |
| Volume | 45 |
| Issue number | 9 |
| Publication status | Published - Sep 1984 |
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DIPOLE MOMENT MATRIX FOR VIBRATION-ROTATION TRANSITIONS IN C//3//v MOLECULES. / Tarrago, G.; Ulenikov, O. N.; Poussigue, G.
In: Journal de physique Paris, Vol. 45, No. 9, 09.1984, p. 1429-1447.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - DIPOLE MOMENT MATRIX FOR VIBRATION-ROTATION TRANSITIONS IN C//3//v MOLECULES.
AU - Tarrago, G.
AU - Ulenikov, O. N.
AU - Poussigue, G.
PY - 1984/9
Y1 - 1984/9
N2 - The transformed dipole moment of C//3//v molecules has been worked out up to second order of approximation on the basis of its invariance properties. Its dependence on the total angular momentum components has been made explicit. The dipole moment matrix has been written with a view to calculate vibration-rotation intensities in the case of strongly interacting vibrational polyads. The importance of a coherent phase system for correct intensity calculations has been emphasized.
AB - The transformed dipole moment of C//3//v molecules has been worked out up to second order of approximation on the basis of its invariance properties. Its dependence on the total angular momentum components has been made explicit. The dipole moment matrix has been written with a view to calculate vibration-rotation intensities in the case of strongly interacting vibrational polyads. The importance of a coherent phase system for correct intensity calculations has been emphasized.
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UR - http://www.scopus.com/inward/citedby.url?scp=0021494332&partnerID=8YFLogxK
M3 - Article
VL - 45
SP - 1429
EP - 1447
JO - Journal De Physique
JF - Journal De Physique
SN - 0302-0738
IS - 9
ER -