DIPOLE MOMENT MATRIX FOR VIBRATION-ROTATION TRANSITIONS IN C//3//v MOLECULES.

G. Tarrago, O. N. Ulenikov, G. Poussigue

Research output: Contribution to journalArticle

46 Citations (Scopus)

Abstract

The transformed dipole moment of C//3//v molecules has been worked out up to second order of approximation on the basis of its invariance properties. Its dependence on the total angular momentum components has been made explicit. The dipole moment matrix has been written with a view to calculate vibration-rotation intensities in the case of strongly interacting vibrational polyads. The importance of a coherent phase system for correct intensity calculations has been emphasized.

Original languageEnglish
Pages (from-to)1429-1447
Number of pages19
JournalJournal de physique Paris
Volume45
Issue number9
Publication statusPublished - Sep 1984

ASJC Scopus subject areas

  • Engineering(all)

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