Di-methyl carbonate transesterification with EtOH over MOFs: Basicity and synergic effect of basic and acid active sites

Abstract

The catalytic activity of metal-organic frameworks (MOFs) towards the transesterification of dimethyl carbonate with ethanol has been unprecedented assessed. The relation between the catalytic activity and the amount of base active sites has been proved as well as the inability of the Lewis acid sites alone to catalyze this transesterification. The synergic effect of both acid and base sites cannot be completely excluded and a plausible reaction mechanism has been proposed. MOF-808 resulted to be more efficient than every heterogeneous commercial catalyst. MOF-808 can be recycled up to 4 times with exceptional retention of both catalytic activity and crystal structure.

Original language	English
Pages (from-to)	82-85
Number of pages	4
Journal	Catalysis Communications
Volume	104
DOIs	https://doi.org/10.1016/j.catcom.2017.10.022
Publication status	Published - 10 Jan 2018

Keywords

Acid/base active sites
Diethyl carbonate
Dimethyl carbonate
Ethyl methyl carbonate
MOFs

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Process Chemistry and Technology

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10.1016/j.catcom.2017.10.022

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title = "Di-methyl carbonate transesterification with EtOH over MOFs: Basicity and synergic effect of basic and acid active sites",

abstract = "The catalytic activity of metal-organic frameworks (MOFs) towards the transesterification of dimethyl carbonate with ethanol has been unprecedented assessed. The relation between the catalytic activity and the amount of base active sites has been proved as well as the inability of the Lewis acid sites alone to catalyze this transesterification. The synergic effect of both acid and base sites cannot be completely excluded and a plausible reaction mechanism has been proposed. MOF-808 resulted to be more efficient than every heterogeneous commercial catalyst. MOF-808 can be recycled up to 4 times with exceptional retention of both catalytic activity and crystal structure.",

keywords = "Acid/base active sites, Diethyl carbonate, Dimethyl carbonate, Ethyl methyl carbonate, MOFs",

author = "Luca Desidery and Somboon Chaemcheun and Mekhman Yusubov and Francis Verpoort",

year = "2018",

month = jan,

day = "10",

doi = "10.1016/j.catcom.2017.10.022",

language = "English",

volume = "104",

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journal = "Catalysis Communications",

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T1 - Di-methyl carbonate transesterification with EtOH over MOFs

T2 - Basicity and synergic effect of basic and acid active sites

AU - Desidery, Luca

AU - Chaemcheun, Somboon

AU - Yusubov, Mekhman

AU - Verpoort, Francis

PY - 2018/1/10

Y1 - 2018/1/10

N2 - The catalytic activity of metal-organic frameworks (MOFs) towards the transesterification of dimethyl carbonate with ethanol has been unprecedented assessed. The relation between the catalytic activity and the amount of base active sites has been proved as well as the inability of the Lewis acid sites alone to catalyze this transesterification. The synergic effect of both acid and base sites cannot be completely excluded and a plausible reaction mechanism has been proposed. MOF-808 resulted to be more efficient than every heterogeneous commercial catalyst. MOF-808 can be recycled up to 4 times with exceptional retention of both catalytic activity and crystal structure.

AB - The catalytic activity of metal-organic frameworks (MOFs) towards the transesterification of dimethyl carbonate with ethanol has been unprecedented assessed. The relation between the catalytic activity and the amount of base active sites has been proved as well as the inability of the Lewis acid sites alone to catalyze this transesterification. The synergic effect of both acid and base sites cannot be completely excluded and a plausible reaction mechanism has been proposed. MOF-808 resulted to be more efficient than every heterogeneous commercial catalyst. MOF-808 can be recycled up to 4 times with exceptional retention of both catalytic activity and crystal structure.

KW - Acid/base active sites

KW - Diethyl carbonate

KW - Dimethyl carbonate

KW - Ethyl methyl carbonate

KW - MOFs

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