Determining the Parameters of the Ground Vibrational State of the 28SiH4 Molecule

Abstract

For high-precision determination of the rotational-vibrational energies of the ground vibrational state of the SiH₄ molecule, high-resolution rotational-vibrational spectrum of this molecule in the range 600–1200 cm^–1 in which bands of the ν₂/ ν₄ dyad are located is analyzed. As a result, rotational and centrifugal distortion parameters of the ground vibrational state with a root-mean-square deviation of 2·10^–4 cm^–1 are obtained.

Original language	English
Pages (from-to)	1-7
Number of pages	7
Journal	Russian Physics Journal
Volume	60
Issue number	5
DOIs	https://doi.org/10.1007/s11182-017-1136-1
Publication status	Accepted/In press - 1 Sep 2017

Keywords

molecules of tetrahedral symmetry
rotational-vibrational spectrum
spectroscopic parameters

ASJC Scopus subject areas

Physics and Astronomy(all)

Access to Document

10.1007/s11182-017-1136-1

Fingerprint Dive into the research topics of 'Determining the Parameters of the Ground Vibrational State of the 28SiH4 Molecule'. Together they form a unique fingerprint.

Cite this

Raspopova, N. I., Gromova, O. V., Bekhtereva, E. S., & Bauerecker, Z. (Accepted/In press). Determining the Parameters of the Ground Vibrational State of the ²⁸SiH₄ Molecule. Russian Physics Journal, 60(5), 1-7. https://doi.org/10.1007/s11182-017-1136-1

@article{818d7f22474a421c902402a4122c08e1,

title = "Determining the Parameters of the Ground Vibrational State of the 28SiH4 Molecule",

abstract = "For high-precision determination of the rotational-vibrational energies of the ground vibrational state of the SiH4 molecule, high-resolution rotational-vibrational spectrum of this molecule in the range 600–1200 cm–1 in which bands of the ν2/ ν4 dyad are located is analyzed. As a result, rotational and centrifugal distortion parameters of the ground vibrational state with a root-mean-square deviation of 2·10–4 cm–1 are obtained.",

keywords = "molecules of tetrahedral symmetry, rotational-vibrational spectrum, spectroscopic parameters",

author = "Raspopova, {N. I.} and Gromova, {O. V.} and Bekhtereva, {E. S.} and Z. Bauerecker",

year = "2017",

month = sep,

day = "1",

doi = "10.1007/s11182-017-1136-1",

language = "English",

volume = "60",

pages = "1--7",

journal = "Russian Physics Journal",

issn = "1064-8887",

publisher = "Consultants Bureau",

number = "5",

}

TY - JOUR

T1 - Determining the Parameters of the Ground Vibrational State of the 28SiH4 Molecule

AU - Raspopova, N. I.

AU - Gromova, O. V.

AU - Bekhtereva, E. S.

AU - Bauerecker, Z.

PY - 2017/9/1

Y1 - 2017/9/1

N2 - For high-precision determination of the rotational-vibrational energies of the ground vibrational state of the SiH4 molecule, high-resolution rotational-vibrational spectrum of this molecule in the range 600–1200 cm–1 in which bands of the ν2/ ν4 dyad are located is analyzed. As a result, rotational and centrifugal distortion parameters of the ground vibrational state with a root-mean-square deviation of 2·10–4 cm–1 are obtained.

AB - For high-precision determination of the rotational-vibrational energies of the ground vibrational state of the SiH4 molecule, high-resolution rotational-vibrational spectrum of this molecule in the range 600–1200 cm–1 in which bands of the ν2/ ν4 dyad are located is analyzed. As a result, rotational and centrifugal distortion parameters of the ground vibrational state with a root-mean-square deviation of 2·10–4 cm–1 are obtained.

KW - molecules of tetrahedral symmetry

KW - rotational-vibrational spectrum

KW - spectroscopic parameters

UR - http://www.scopus.com/inward/record.url?scp=85028761970&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85028761970&partnerID=8YFLogxK

U2 - 10.1007/s11182-017-1136-1

DO - 10.1007/s11182-017-1136-1

M3 - Article

AN - SCOPUS:85028761970

VL - 60

SP - 1

EP - 7

JO - Russian Physics Journal

JF - Russian Physics Journal

SN - 1064-8887

IS - 5

ER -