Abstract
For high-precision determination of the rotational-vibrational energies of the ground vibrational state of the SiH4 molecule, high-resolution rotational-vibrational spectrum of this molecule in the range 600–1200 cm–1 in which bands of the ν2/ ν4 dyad are located is analyzed. As a result, rotational and centrifugal distortion parameters of the ground vibrational state with a root-mean-square deviation of 2·10–4 cm–1 are obtained.
| Original language | English |
|---|---|
| Pages (from-to) | 1-7 |
| Number of pages | 7 |
| Journal | Russian Physics Journal |
| Volume | 60 |
| Issue number | 5 |
| DOIs | |
| Publication status | Accepted/In press - 1 Sep 2017 |
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Keywords
- molecules of tetrahedral symmetry
- rotational-vibrational spectrum
- spectroscopic parameters
ASJC Scopus subject areas
- Physics and Astronomy(all)
Cite this
Determining the Parameters of the Ground Vibrational State of the 28SiH4 Molecule. / Raspopova, N. I.; Gromova, O. V.; Bekhtereva, E. S.; Bauerecker, Z.
In: Russian Physics Journal, Vol. 60, No. 5, 01.09.2017, p. 1-7.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Determining the Parameters of the Ground Vibrational State of the 28SiH4 Molecule
AU - Raspopova, N. I.
AU - Gromova, O. V.
AU - Bekhtereva, E. S.
AU - Bauerecker, Z.
PY - 2017/9/1
Y1 - 2017/9/1
N2 - For high-precision determination of the rotational-vibrational energies of the ground vibrational state of the SiH4 molecule, high-resolution rotational-vibrational spectrum of this molecule in the range 600–1200 cm–1 in which bands of the ν2/ ν4 dyad are located is analyzed. As a result, rotational and centrifugal distortion parameters of the ground vibrational state with a root-mean-square deviation of 2·10–4 cm–1 are obtained.
AB - For high-precision determination of the rotational-vibrational energies of the ground vibrational state of the SiH4 molecule, high-resolution rotational-vibrational spectrum of this molecule in the range 600–1200 cm–1 in which bands of the ν2/ ν4 dyad are located is analyzed. As a result, rotational and centrifugal distortion parameters of the ground vibrational state with a root-mean-square deviation of 2·10–4 cm–1 are obtained.
KW - molecules of tetrahedral symmetry
KW - rotational-vibrational spectrum
KW - spectroscopic parameters
UR - http://www.scopus.com/inward/record.url?scp=85028761970&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85028761970&partnerID=8YFLogxK
U2 - 10.1007/s11182-017-1136-1
DO - 10.1007/s11182-017-1136-1
M3 - Article
VL - 60
SP - 1
EP - 7
JO - Russian Physics Journal
JF - Russian Physics Journal
SN - 1064-8887
IS - 5
ER -