Abstract
The spectrum of the ν7 + ν8 band of the ethylene-1-13C (13C12СH4) molecule is recorded with a Bruker IFS 125 HR Fourier spectrometer in the range from 1500 to 2100 cm–1 with a resolution of 0.0025 cm–1. As a result of analysis of the experimental spectrum, more than 1000 transitions belonging to the ν7 + ν8 band are assigned. Parameters of the Hamiltonian obtained as a result of solving the inverse spectroscopic problem reproduce 400 initial experimental energies with error close to the experimental one.
Original language | English |
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Pages (from-to) | 299-303 |
Number of pages | 5 |
Journal | Russian Physics Journal |
Volume | 61 |
Issue number | 2 |
DOIs | |
Publication status | Published - 1 Jun 2018 |
Keywords
- effective Hamiltonian
- ethylene
- molecular spectroscopy
- rotational operators
- rovibrational spectra
ASJC Scopus subject areas
- Physics and Astronomy(all)