Determining the Parameters of Tetrahedral Splittings in the A1- and A2-Type States of Molecules with Spherical Symmetry (Td or Оh)

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Abstract

A method of analytical description of one of the most complex problems in the study of high symmetry quantum-mechanical objects, namely, tetrahedral splittings, is considered. Results are presented that allow tetrahedral splittings of the vibrational states of A1 and A2 symmetries for polyad N ≤ 4 to be determined in an analytical form.

Original languageEnglish
Pages (from-to)1-6
Number of pages6
JournalRussian Physics Journal
Volume60
Issue number10
DOIs
Publication statusAccepted/In press - 8 Feb 2018

Keywords

  • molecules of tetrahedral symmetry
  • rovibrational spectrum
  • spectroscopic parameters
  • symmetrized operators

ASJC Scopus subject areas

  • Physics and Astronomy(all)

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