Determining the Parameters of Tetrahedral Splittings in the A1- and A2-Type States of Molecules with Spherical Symmetry (Td or Оh)

Abstract

A method of analytical description of one of the most complex problems in the study of high symmetry quantum-mechanical objects, namely, tetrahedral splittings, is considered. Results are presented that allow tetrahedral splittings of the vibrational states of A₁ and A₂ symmetries for polyad N ≤ 4 to be determined in an analytical form.

Original language	English
Pages (from-to)	1-6
Number of pages	6
Journal	Russian Physics Journal
Volume	60
Issue number	10
DOIs	https://doi.org/10.1007/s11182-018-1269-x
Publication status	Accepted/In press - 8 Feb 2018

Keywords

molecules of tetrahedral symmetry
rovibrational spectrum
spectroscopic parameters
symmetrized operators

ASJC Scopus subject areas

Physics and Astronomy(all)

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10.1007/s11182-018-1269-x

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abstract = "A method of analytical description of one of the most complex problems in the study of high symmetry quantum-mechanical objects, namely, tetrahedral splittings, is considered. Results are presented that allow tetrahedral splittings of the vibrational states of A1 and A2 symmetries for polyad N ≤ 4 to be determined in an analytical form.",

keywords = "molecules of tetrahedral symmetry, rovibrational spectrum, spectroscopic parameters, symmetrized operators",

author = "Raspopova, {N. I.} and Sklyarova, {E. A.} and Aslapovskaya, {Y. S.} and Kuznetsov, {S. I.} and K. Maul",

year = "2018",

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journal = "Russian Physics Journal",

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T1 - Determining the Parameters of Tetrahedral Splittings in the A1- and A2-Type States of Molecules with Spherical Symmetry (Td or Оh)

AU - Raspopova, N. I.

AU - Sklyarova, E. A.

AU - Aslapovskaya, Y. S.

AU - Kuznetsov, S. I.

AU - Maul, K.

PY - 2018/2/8

Y1 - 2018/2/8

N2 - A method of analytical description of one of the most complex problems in the study of high symmetry quantum-mechanical objects, namely, tetrahedral splittings, is considered. Results are presented that allow tetrahedral splittings of the vibrational states of A1 and A2 symmetries for polyad N ≤ 4 to be determined in an analytical form.

AB - A method of analytical description of one of the most complex problems in the study of high symmetry quantum-mechanical objects, namely, tetrahedral splittings, is considered. Results are presented that allow tetrahedral splittings of the vibrational states of A1 and A2 symmetries for polyad N ≤ 4 to be determined in an analytical form.

KW - molecules of tetrahedral symmetry

KW - rovibrational spectrum

KW - spectroscopic parameters

KW - symmetrized operators

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DO - 10.1007/s11182-018-1269-x

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VL - 60

SP - 1

EP - 6

JO - Russian Physics Journal

JF - Russian Physics Journal

SN - 1064-8887

IS - 10

ER -

Determining the Parameters of Tetrahedral Splittings in the A₁- and A₂-Type States of Molecules with Spherical Symmetry (T_d or О_h)

Abstract

Keywords

ASJC Scopus subject areas

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