Determination of Unsaturation Level, Halogen Content, and Main Forms of Isoprene Units in Halogenated Butyl Rubbers by 1H NMR Spectroscopy

I. I. Smolentseva, V. I. Mashukov, E. I. Korotkova

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

We have used1H NMR spectroscopy to study commercial samples of chloro-substituted and bromo-substituted butyl rubbers. We propose calculation formulas for quantitative determination of the main forms in halobutyl rubber (1,4-isoprene, exo form) and its characteristics: unsaturation level, halogen content in the isoprene units. We show that it is possible to determine the main structural characteristics of bromobutyl rubber in the presence of filler.

Original languageEnglish
Pages (from-to)465-469
Number of pages5
JournalJournal of Applied Spectroscopy
Volume82
Issue number3
DOIs
Publication statusPublished - 1 Jul 2015

Fingerprint

Halogens
Rubber
rubber
halogens
Nuclear magnetic resonance spectroscopy
nuclear magnetic resonance
spectroscopy
Fillers
fillers
isoprene
butyl rubber

Keywords

  • filler
  • halogen content
  • halogenated butyl rubber
  • NMR spectroscopy
  • structural characteristics
  • unsaturation level

ASJC Scopus subject areas

  • Spectroscopy
  • Condensed Matter Physics

Cite this

Determination of Unsaturation Level, Halogen Content, and Main Forms of Isoprene Units in Halogenated Butyl Rubbers by 1H NMR Spectroscopy. / Smolentseva, I. I.; Mashukov, V. I.; Korotkova, E. I.

In: Journal of Applied Spectroscopy, Vol. 82, No. 3, 01.07.2015, p. 465-469.

Research output: Contribution to journalArticle

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