Determination of rhenium in mineral raw materials by stripping voltammetry

N. A. Kolpakova, L. G. Gol'ts

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The studies on the electropreconcentration of ReO 4- from 1 M HNO3 solutions have shown that, at -0.8 V, ReO 4- is reduced to ReO2 and Re0 at the surface of an impregnated graphite electrode. Two anodic peaks were observed in the voltammogram of the electrooxidation of the deposit obtained. The conditions for the adsorption isolation of ReO 4- on activated carbon from a complex matrix containing Mo(VI), W(VI), Cu(II), Ag(I), and Au(III) were selected. To intensify the adsorption, the solutions are irradiated with UV. A procedure for determining rhenium in mineral ores and naturally occurring samples was proposed.

Original languageEnglish
Pages (from-to)377-381
Number of pages5
JournalJournal of Analytical Chemistry
Volume62
Issue number4
DOIs
Publication statusPublished - Apr 2007

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Rhenium
Voltammetry
Minerals
Raw materials
Adsorption
Graphite electrodes
Electrooxidation
Activated carbon
Ores
Deposits

ASJC Scopus subject areas

  • Analytical Chemistry

Cite this

Determination of rhenium in mineral raw materials by stripping voltammetry. / Kolpakova, N. A.; Gol'ts, L. G.

In: Journal of Analytical Chemistry, Vol. 62, No. 4, 04.2007, p. 377-381.

Research output: Contribution to journalArticle

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