Determination of optimal temperature of catalytic dewaxing process for diesel fuel production

Nataliya S. Belinskaya, Evgeniya V. Frantsina, Emiliya D. Ivanchina, Natalya V. Popova, Natalya E. Belozertseva

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The improvement of catalytic dewaxing reactor model for the production of diesel fuel was arranged. The formalized scheme of the reactions proceeding in the reactor was advanced by applying the results of thermodynamic calculations in the Gaussian software package. The occurrence of such important reactions as paraffin cracking and olefin cyclization was defined. The improved reaction network allowed developing the kinetic model of the reactor with a heat balance for predicting reactor outlet temperature depending on the feedstock composition. The results of forecasting calculations showed that optimal temperatures for production of diesel fuel with the pour point temperature of -35°C and cloud point temperature of -26°C range within 357-369°C depending on the feed composition. In this case, it is likely to obtain the yield of product equal to 95-98 %. Model predictions of reactor temperature drop, low-temperature properties and volume of diesel fraction obtained match closely the plant data.

Original languageEnglish
Pages (from-to)695-699
Number of pages5
JournalPetroleum and Coal
Volume58
Issue number7
Publication statusPublished - 2016

Fingerprint

Dewaxing
Diesel fuels
Temperature
Low temperature properties
Cyclization
Chemical analysis
Software packages
Paraffins
Feedstocks
Olefins
Thermodynamics
Kinetics

Keywords

  • Catalytic dewaxing
  • Diesel fuel
  • Low-temperature characteristics
  • Mathematical model

ASJC Scopus subject areas

  • Energy(all)

Cite this

Determination of optimal temperature of catalytic dewaxing process for diesel fuel production. / Belinskaya, Nataliya S.; Frantsina, Evgeniya V.; Ivanchina, Emiliya D.; Popova, Natalya V.; Belozertseva, Natalya E.

In: Petroleum and Coal, Vol. 58, No. 7, 2016, p. 695-699.

Research output: Contribution to journalArticle

@article{b19a66af349d44d6a3d147767d37e769,
title = "Determination of optimal temperature of catalytic dewaxing process for diesel fuel production",
abstract = "The improvement of catalytic dewaxing reactor model for the production of diesel fuel was arranged. The formalized scheme of the reactions proceeding in the reactor was advanced by applying the results of thermodynamic calculations in the Gaussian software package. The occurrence of such important reactions as paraffin cracking and olefin cyclization was defined. The improved reaction network allowed developing the kinetic model of the reactor with a heat balance for predicting reactor outlet temperature depending on the feedstock composition. The results of forecasting calculations showed that optimal temperatures for production of diesel fuel with the pour point temperature of -35°C and cloud point temperature of -26°C range within 357-369°C depending on the feed composition. In this case, it is likely to obtain the yield of product equal to 95-98 {\%}. Model predictions of reactor temperature drop, low-temperature properties and volume of diesel fraction obtained match closely the plant data.",
keywords = "Catalytic dewaxing, Diesel fuel, Low-temperature characteristics, Mathematical model",
author = "Belinskaya, {Nataliya S.} and Frantsina, {Evgeniya V.} and Ivanchina, {Emiliya D.} and Popova, {Natalya V.} and Belozertseva, {Natalya E.}",
year = "2016",
language = "English",
volume = "58",
pages = "695--699",
journal = "Petroleum and Coal",
issn = "1337-7027",
publisher = "Vyskumny ustav pre ropu a uhlovodikove plyny (VURUP)",
number = "7",

}

TY - JOUR

T1 - Determination of optimal temperature of catalytic dewaxing process for diesel fuel production

AU - Belinskaya, Nataliya S.

AU - Frantsina, Evgeniya V.

AU - Ivanchina, Emiliya D.

AU - Popova, Natalya V.

AU - Belozertseva, Natalya E.

PY - 2016

Y1 - 2016

N2 - The improvement of catalytic dewaxing reactor model for the production of diesel fuel was arranged. The formalized scheme of the reactions proceeding in the reactor was advanced by applying the results of thermodynamic calculations in the Gaussian software package. The occurrence of such important reactions as paraffin cracking and olefin cyclization was defined. The improved reaction network allowed developing the kinetic model of the reactor with a heat balance for predicting reactor outlet temperature depending on the feedstock composition. The results of forecasting calculations showed that optimal temperatures for production of diesel fuel with the pour point temperature of -35°C and cloud point temperature of -26°C range within 357-369°C depending on the feed composition. In this case, it is likely to obtain the yield of product equal to 95-98 %. Model predictions of reactor temperature drop, low-temperature properties and volume of diesel fraction obtained match closely the plant data.

AB - The improvement of catalytic dewaxing reactor model for the production of diesel fuel was arranged. The formalized scheme of the reactions proceeding in the reactor was advanced by applying the results of thermodynamic calculations in the Gaussian software package. The occurrence of such important reactions as paraffin cracking and olefin cyclization was defined. The improved reaction network allowed developing the kinetic model of the reactor with a heat balance for predicting reactor outlet temperature depending on the feedstock composition. The results of forecasting calculations showed that optimal temperatures for production of diesel fuel with the pour point temperature of -35°C and cloud point temperature of -26°C range within 357-369°C depending on the feed composition. In this case, it is likely to obtain the yield of product equal to 95-98 %. Model predictions of reactor temperature drop, low-temperature properties and volume of diesel fraction obtained match closely the plant data.

KW - Catalytic dewaxing

KW - Diesel fuel

KW - Low-temperature characteristics

KW - Mathematical model

UR - http://www.scopus.com/inward/record.url?scp=85011928515&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85011928515&partnerID=8YFLogxK

M3 - Article

VL - 58

SP - 695

EP - 699

JO - Petroleum and Coal

JF - Petroleum and Coal

SN - 1337-7027

IS - 7

ER -