Determination of 5-nitroindazole using silver solid amalgam electrode

Kateřina Nováková, Vojtěch Hrdlička, Tomáš Navrátil, Vlastimil Vyskočil, Jiří Barek

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Abstract The voltammetric behavior of 5-nitroindazole was investigated at polished (p-AgSAE) and at mercury meniscus-modified (m-AgSAE) silver solid amalgam electrodes (inner diameter 0.5mm) by direct current voltammetry and by differential pulse voltammetry. The results were compared with those obtained using hanging mercury drop electrode. Optimum conditions for differential pulse voltammetry determination of 5-nitroindazole were found in Britton-Robinson buffer of pH 8. The reaction mechanism was investigated using direct current voltammetry and elimination voltammetry with linear scan. Differential pulse voltammetry with optimized parameters was applied for determination of the compound in model and real samples. The limits of detection were calculated as 0.14 × 10-6 mol dm-3 for m-AgSAE and as 0.47 × 10-6 mol dm-3 for p-AgSAE. The proposed method was successfully applied for determination of 5-nitroindazole in real samples of river water.

Original languageEnglish
Article number706
Pages (from-to)761-769
Number of pages9
JournalMonatshefte fur Chemie
Volume146
Issue number5
DOIs
Publication statusPublished - 1 May 2015
Externally publishedYes

Fingerprint

Mercury amalgams
Voltammetry
Silver
Electrodes
Mercury
5-nitroindazole
Buffers
Rivers
Water

Keywords

  • 5-Nitroindazole
  • Hanging mercury drop electrode
  • Nitro compounds
  • Silver sold amalgam electrode

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Determination of 5-nitroindazole using silver solid amalgam electrode. / Nováková, Kateřina; Hrdlička, Vojtěch; Navrátil, Tomáš; Vyskočil, Vlastimil; Barek, Jiří.

In: Monatshefte fur Chemie, Vol. 146, No. 5, 706, 01.05.2015, p. 761-769.

Research output: Contribution to journalArticle

Nováková, K, Hrdlička, V, Navrátil, T, Vyskočil, V & Barek, J 2015, 'Determination of 5-nitroindazole using silver solid amalgam electrode', Monatshefte fur Chemie, vol. 146, no. 5, 706, pp. 761-769. https://doi.org/10.1007/s00706-014-1346-y
Nováková, Kateřina ; Hrdlička, Vojtěch ; Navrátil, Tomáš ; Vyskočil, Vlastimil ; Barek, Jiří. / Determination of 5-nitroindazole using silver solid amalgam electrode. In: Monatshefte fur Chemie. 2015 ; Vol. 146, No. 5. pp. 761-769.
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