Abstract
Differential pulse voltammetry, direct current voltammetry, adsorptive Stripping voltammetry and HPLC with electrochemical detection were used for the determination of 5-amino-6-nitroquinoline at a carbon paste electrode. The methods are based either on anodic oxidation or cathodic reduction of this substance, whose electrochemical behavior at carbon paste electrode was further studied by cyclic voltammetry. Practical applicability of these methods was demonstrated on the determination of 5-amino-6-nitroquinoline in model samples of drinking and river water. The detection limit was 2.0 × 10-6 mol 1-1 for anodic differential pulse voltammetry in a mixture of Britton-Robinson buffer (pH 11)-methanol 1:1 (v/v) and 1.6 × 10 -7 mol 1-1 for HPLC with electrochemical detection (E = +1.2 V) in a mobile phase Britton-Robinson buffer (pH 7)-methanol 1:9 (v/v).
| Original language | English |
|---|---|
| Pages (from-to) | 1477-1488 |
| Number of pages | 12 |
| Journal | Collection of Czechoslovak Chemical Communications |
| Volume | 74 |
| Issue number | 10 |
| DOIs | |
| Publication status | Published - 1 Oct 2009 |
| Externally published | Yes |
Fingerprint
Keywords
- 5-amino-6-nitroquinoline
- Carbon paste electrode
- Cyclic voltammetry
- Differential pulse voltammetry
- Electrochemical detection
- HPLC
- Spectrophotometry detection
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Determination of 5-amino-6-nitroquinoline at a carbon paste electrode. / Němcová, Lenka; Zima, Jiří; Barek, Jiří.
In: Collection of Czechoslovak Chemical Communications, Vol. 74, No. 10, 01.10.2009, p. 1477-1488.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Determination of 5-amino-6-nitroquinoline at a carbon paste electrode
AU - Němcová, Lenka
AU - Zima, Jiří
AU - Barek, Jiří
PY - 2009/10/1
Y1 - 2009/10/1
N2 - Differential pulse voltammetry, direct current voltammetry, adsorptive Stripping voltammetry and HPLC with electrochemical detection were used for the determination of 5-amino-6-nitroquinoline at a carbon paste electrode. The methods are based either on anodic oxidation or cathodic reduction of this substance, whose electrochemical behavior at carbon paste electrode was further studied by cyclic voltammetry. Practical applicability of these methods was demonstrated on the determination of 5-amino-6-nitroquinoline in model samples of drinking and river water. The detection limit was 2.0 × 10-6 mol 1-1 for anodic differential pulse voltammetry in a mixture of Britton-Robinson buffer (pH 11)-methanol 1:1 (v/v) and 1.6 × 10 -7 mol 1-1 for HPLC with electrochemical detection (E = +1.2 V) in a mobile phase Britton-Robinson buffer (pH 7)-methanol 1:9 (v/v).
AB - Differential pulse voltammetry, direct current voltammetry, adsorptive Stripping voltammetry and HPLC with electrochemical detection were used for the determination of 5-amino-6-nitroquinoline at a carbon paste electrode. The methods are based either on anodic oxidation or cathodic reduction of this substance, whose electrochemical behavior at carbon paste electrode was further studied by cyclic voltammetry. Practical applicability of these methods was demonstrated on the determination of 5-amino-6-nitroquinoline in model samples of drinking and river water. The detection limit was 2.0 × 10-6 mol 1-1 for anodic differential pulse voltammetry in a mixture of Britton-Robinson buffer (pH 11)-methanol 1:1 (v/v) and 1.6 × 10 -7 mol 1-1 for HPLC with electrochemical detection (E = +1.2 V) in a mobile phase Britton-Robinson buffer (pH 7)-methanol 1:9 (v/v).
KW - 5-amino-6-nitroquinoline
KW - Carbon paste electrode
KW - Cyclic voltammetry
KW - Differential pulse voltammetry
KW - Electrochemical detection
KW - HPLC
KW - Spectrophotometry detection
UR - http://www.scopus.com/inward/record.url?scp=77149179350&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=77149179350&partnerID=8YFLogxK
U2 - 10.1135/cccc2009065
DO - 10.1135/cccc2009065
M3 - Article
VL - 74
SP - 1477
EP - 1488
JO - Collection of Czechoslovak Chemical Communications
JF - Collection of Czechoslovak Chemical Communications
SN - 0010-0765
IS - 10
ER -