Abstract
The mechanism of accommodation of the energy liberated in a heterogeneous chemical reaction involving vibrational-vibrational (V-V) exchange between molecules of a product of a reaction and molecules of an adsorption layer is studied. The recombination of hydrogen atoms on a Teflon surface preliminarily filled with D2O, HDO, and H2O molecules results in a nonequilibrium desorption of water molecules due to energy transfer from the vibrationally excited Hv 2-L molecules formed to adsorbed water molecules. The rates of the heterogeneous recombination of hydrogen atoms and of the nonequilibrium desorption of adsorbate molecules periodically change with the duration of treatment of the surface by the H + H2 beam. A kinetic mechanism of V-V relaxation of Hv 2 on the Teflon surface covered with an adsorption layer is discussed.
| Original language | English |
|---|---|
| Pages (from-to) | 777-782 |
| Number of pages | 6 |
| Journal | Russian Journal of Physical Chemistry A |
| Volume | 73 |
| Issue number | 5 |
| Publication status | Published - May 1999 |
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- Physical and Theoretical Chemistry
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Desorption of isotope-substituted molecules from the teflon surface under the action of atomic-molecular hydrogen beams. / Grankin, V. P.; Savinkov, N. A.; Styrov, V. V.; Tyurin, Yu I.
In: Russian Journal of Physical Chemistry A, Vol. 73, No. 5, 05.1999, p. 777-782.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Desorption of isotope-substituted molecules from the teflon surface under the action of atomic-molecular hydrogen beams
AU - Grankin, V. P.
AU - Savinkov, N. A.
AU - Styrov, V. V.
AU - Tyurin, Yu I.
PY - 1999/5
Y1 - 1999/5
N2 - The mechanism of accommodation of the energy liberated in a heterogeneous chemical reaction involving vibrational-vibrational (V-V) exchange between molecules of a product of a reaction and molecules of an adsorption layer is studied. The recombination of hydrogen atoms on a Teflon surface preliminarily filled with D2O, HDO, and H2O molecules results in a nonequilibrium desorption of water molecules due to energy transfer from the vibrationally excited Hv 2-L molecules formed to adsorbed water molecules. The rates of the heterogeneous recombination of hydrogen atoms and of the nonequilibrium desorption of adsorbate molecules periodically change with the duration of treatment of the surface by the H + H2 beam. A kinetic mechanism of V-V relaxation of Hv 2 on the Teflon surface covered with an adsorption layer is discussed.
AB - The mechanism of accommodation of the energy liberated in a heterogeneous chemical reaction involving vibrational-vibrational (V-V) exchange between molecules of a product of a reaction and molecules of an adsorption layer is studied. The recombination of hydrogen atoms on a Teflon surface preliminarily filled with D2O, HDO, and H2O molecules results in a nonequilibrium desorption of water molecules due to energy transfer from the vibrationally excited Hv 2-L molecules formed to adsorbed water molecules. The rates of the heterogeneous recombination of hydrogen atoms and of the nonequilibrium desorption of adsorbate molecules periodically change with the duration of treatment of the surface by the H + H2 beam. A kinetic mechanism of V-V relaxation of Hv 2 on the Teflon surface covered with an adsorption layer is discussed.
UR - http://www.scopus.com/inward/record.url?scp=0033238899&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0033238899&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:33749626294
VL - 73
SP - 777
EP - 782
JO - Russian Journal of Physical Chemistry A
JF - Russian Journal of Physical Chemistry A
SN - 0036-0244
IS - 5
ER -