Cyclodextrin modified carbon paste based electrodes as sensors for the determination of carcinogenic polycyclic aromatic amines

Adriana Ferancová, Elena Korgová, Ján Labudaa, Jirĩ́ Zima, Jirĩ́ Barek

Research output: Contribution to journalArticle

46 Citations (Scopus)

Abstract

Voltammetric properties and possibility of the determination of carcinogenic aminoderivatives of polycyclic aromatic hydrocarbons, namely 1- and 2-aminonaphthalene and 2-aminobiphenyl, have been investigated. Carbon paste electrodes (CPE) modified with monomeric α-, β- or γ-cyclodextrin and carbon-based screen-printed electrodes (SPE) surface-modified with a thin film of β-cyclodextrin (β-CDP) or carboxymethylated β-cyclodextrin (β-CDPA) condensation polymer were used for that purpose as simple electrochemical biosensors. Analytical procedure for the DPV determination of tested amines using these biosensors was proposed. Linear calibration plots within the concentration range of 2 × 10-8 -2 × 10-7 mol dm-3 and 2 × 10-7 -1 × 10-6 mol dm-3 with limits of quantification of the order of 10-9 mol dm-3 were obtained for the modified CPE and modified SPE.

Original languageEnglish
Pages (from-to)1668-1673
Number of pages6
JournalElectroanalysis
Volume14
Issue number23
DOIs
Publication statusPublished - 1 Dec 2002
Externally publishedYes

Fingerprint

Cyclodextrins
Ointments
Amines
Carbon
Electrodes
Sensors
Biosensors
1-Naphthylamine
2-Naphthylamine
Cytidine Diphosphate
Polycyclic Aromatic Hydrocarbons
Polycyclic aromatic hydrocarbons
Condensation
Polymers
Calibration
Thin films

Keywords

  • 1-Aminonaphthalene
  • 2-Aminobiphenyl
  • 2-Aminonaphthalene
  • Carbon paste electrodes
  • Chemically modified electrode
  • Cyclodextrin
  • Screen -printed electrodes

ASJC Scopus subject areas

  • Analytical Chemistry
  • Electrochemistry

Cite this

Cyclodextrin modified carbon paste based electrodes as sensors for the determination of carcinogenic polycyclic aromatic amines. / Ferancová, Adriana; Korgová, Elena; Labudaa, Ján; Zima, Jirĩ́; Barek, Jirĩ́.

In: Electroanalysis, Vol. 14, No. 23, 01.12.2002, p. 1668-1673.

Research output: Contribution to journalArticle

Ferancová, Adriana ; Korgová, Elena ; Labudaa, Ján ; Zima, Jirĩ́ ; Barek, Jirĩ́. / Cyclodextrin modified carbon paste based electrodes as sensors for the determination of carcinogenic polycyclic aromatic amines. In: Electroanalysis. 2002 ; Vol. 14, No. 23. pp. 1668-1673.
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AU - Barek, Jirĩ́

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