Crystal structures of [RhL4Cl2][AuCl4] (L = Py, γ- and β-picolines) complex salts

D. B. Vasilchenko, E. Yu Semitut, E. A. Bykova, S. V. Korenev

    Research output: Contribution to journalArticle

    Abstract

    New double complex salts [RhL4Cl2][AuCl4] (L = Py, γ- and β-picolines) are synthesized. The compounds are characterized by elemental, powder and single crystal X-ray diffraction analyses. The salts crystallize in different space groups. A specific feature of the packing of [AuCl4] complex anions is the chain formation due to additional Au…Cl or Cl…Cl contacts.

    Original languageEnglish
    Pages (from-to)84-89
    Number of pages6
    JournalJournal of Structural Chemistry
    Volume58
    Issue number1
    DOIs
    Publication statusPublished - 1 Jan 2017

    Fingerprint

    Picolines
    Salts
    Crystal structure
    salts
    crystal structure
    Powders
    crystals
    Anions
    Negative ions
    Single crystals
    anions
    X ray diffraction
    single crystals
    diffraction
    x rays

    Keywords

    • gold
    • picoline
    • pyridine
    • rhodium
    • single crystal X-ray diffraction analysis
    • synthesis

    ASJC Scopus subject areas

    • Physical and Theoretical Chemistry
    • Inorganic Chemistry
    • Materials Chemistry

    Cite this

    Crystal structures of [RhL4Cl2][AuCl4] (L = Py, γ- and β-picolines) complex salts. / Vasilchenko, D. B.; Semitut, E. Yu; Bykova, E. A.; Korenev, S. V.

    In: Journal of Structural Chemistry, Vol. 58, No. 1, 01.01.2017, p. 84-89.

    Research output: Contribution to journalArticle

    Vasilchenko, D. B. ; Semitut, E. Yu ; Bykova, E. A. ; Korenev, S. V. / Crystal structures of [RhL4Cl2][AuCl4] (L = Py, γ- and β-picolines) complex salts. In: Journal of Structural Chemistry. 2017 ; Vol. 58, No. 1. pp. 84-89.
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    AU - Korenev, S. V.

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