Crystal structures of [RhL4Cl2][AuCl4] (L = Py, γ- and β-picolines) complex salts

D. B. Vasilchenko, E. Yu Semitut, E. A. Bykova, S. V. Korenev

    Research output: Contribution to journalArticle

    Abstract

    New double complex salts [RhL4Cl2][AuCl4] (L = Py, γ- and β-picolines) are synthesized. The compounds are characterized by elemental, powder and single crystal X-ray diffraction analyses. The salts crystallize in different space groups. A specific feature of the packing of [AuCl4] complex anions is the chain formation due to additional Au…Cl or Cl…Cl contacts.

    Original languageEnglish
    Pages (from-to)84-89
    Number of pages6
    JournalJournal of Structural Chemistry
    Volume58
    Issue number1
    DOIs
    Publication statusPublished - 1 Jan 2017

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    Keywords

    • gold
    • picoline
    • pyridine
    • rhodium
    • single crystal X-ray diffraction analysis
    • synthesis

    ASJC Scopus subject areas

    • Physical and Theoretical Chemistry
    • Inorganic Chemistry
    • Materials Chemistry

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