Crystal structure of [CuL](NO 3)(ReO 4) and [CuL](ReO 4) 2 (L = 4,6,6-trimethyl-1,9-diamino-3,7- diazanon-3-en)

E. A. Bykova, S. P. Khranenko, E. Yu Semitut, S. A. Gromilov

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

The crystal structures of [CuL](NO 3)(ReO 4) and [CuL](ReO 4) 2 (L is 4,6,6-trimethyl-1,9-diamino-3,7- diazanon-3-en) are studied. The square coordination of the copper atom in [CuL](NO 3)(ReO 4) is completed to a distorted octahedron by two oxygen atoms: Cu⋯O (ReO 4 - ) 2.393 Å and Cu⋯O (NO 3 - ) 2.685 Å, and that in [CuL](ReO 4) 2, by Cu⋯O(ReO 4 - ) 2.468 Å and 2.697 Å. The products of thermolysis of the salts in a hydrogen atmosphere at 800°C are mixtures of nanocrystalline metal powders with coherent scattering regions of ∼45 nm.

Original languageEnglish
Pages (from-to)138-144
Number of pages7
JournalJournal of Structural Chemistry
Volume53
Issue number1
DOIs
Publication statusPublished - Feb 2012
Externally publishedYes

Keywords

  • copper
  • crystal chemistry
  • rhenium
  • single crystal X-ray diffraction
  • thermal studies

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

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