Crystal structure of [CuL](NO 3)(ReO 4) and [CuL](ReO 4) 2 (L = 4,6,6-trimethyl-1,9-diamino-3,7- diazanon-3-en)

E. A. Bykova, S. P. Khranenko, E. Yu Semitut, S. A. Gromilov

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The crystal structures of [CuL](NO 3)(ReO 4) and [CuL](ReO 4) 2 (L is 4,6,6-trimethyl-1,9-diamino-3,7- diazanon-3-en) are studied. The square coordination of the copper atom in [CuL](NO 3)(ReO 4) is completed to a distorted octahedron by two oxygen atoms: Cu⋯O (ReO 4 - ) 2.393 Å and Cu⋯O (NO 3 - ) 2.685 Å, and that in [CuL](ReO 4) 2, by Cu⋯O(ReO 4 - ) 2.468 Å and 2.697 Å. The products of thermolysis of the salts in a hydrogen atmosphere at 800°C are mixtures of nanocrystalline metal powders with coherent scattering regions of ∼45 nm.

Original languageEnglish
Pages (from-to)138-144
Number of pages7
JournalJournal of Structural Chemistry
Volume53
Issue number1
DOIs
Publication statusPublished - Feb 2012
Externally publishedYes

Fingerprint

metal powder
coherent scattering
oxygen atoms
Crystal structure
Coherent scattering
salts
atmospheres
copper
Atoms
Thermolysis
crystal structure
Powder metals
hydrogen
products
atoms
Copper
Hydrogen
Salts
Oxygen

Keywords

  • copper
  • crystal chemistry
  • rhenium
  • single crystal X-ray diffraction
  • thermal studies

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Crystal structure of [CuL](NO 3)(ReO 4) and [CuL](ReO 4) 2 (L = 4,6,6-trimethyl-1,9-diamino-3,7- diazanon-3-en). / Bykova, E. A.; Khranenko, S. P.; Semitut, E. Yu; Gromilov, S. A.

In: Journal of Structural Chemistry, Vol. 53, No. 1, 02.2012, p. 138-144.

Research output: Contribution to journalArticle

Bykova, E. A. ; Khranenko, S. P. ; Semitut, E. Yu ; Gromilov, S. A. / Crystal structure of [CuL](NO 3)(ReO 4) and [CuL](ReO 4) 2 (L = 4,6,6-trimethyl-1,9-diamino-3,7- diazanon-3-en). In: Journal of Structural Chemistry. 2012 ; Vol. 53, No. 1. pp. 138-144.
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abstract = "The crystal structures of [CuL](NO 3)(ReO 4) and [CuL](ReO 4) 2 (L is 4,6,6-trimethyl-1,9-diamino-3,7- diazanon-3-en) are studied. The square coordination of the copper atom in [CuL](NO 3)(ReO 4) is completed to a distorted octahedron by two oxygen atoms: Cu⋯O (ReO 4 - ) 2.393 {\AA} and Cu⋯O (NO 3 - ) 2.685 {\AA}, and that in [CuL](ReO 4) 2, by Cu⋯O(ReO 4 - ) 2.468 {\AA} and 2.697 {\AA}. The products of thermolysis of the salts in a hydrogen atmosphere at 800°C are mixtures of nanocrystalline metal powders with coherent scattering regions of ∼45 nm.",
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AU - Bykova, E. A.

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N2 - The crystal structures of [CuL](NO 3)(ReO 4) and [CuL](ReO 4) 2 (L is 4,6,6-trimethyl-1,9-diamino-3,7- diazanon-3-en) are studied. The square coordination of the copper atom in [CuL](NO 3)(ReO 4) is completed to a distorted octahedron by two oxygen atoms: Cu⋯O (ReO 4 - ) 2.393 Å and Cu⋯O (NO 3 - ) 2.685 Å, and that in [CuL](ReO 4) 2, by Cu⋯O(ReO 4 - ) 2.468 Å and 2.697 Å. The products of thermolysis of the salts in a hydrogen atmosphere at 800°C are mixtures of nanocrystalline metal powders with coherent scattering regions of ∼45 nm.

AB - The crystal structures of [CuL](NO 3)(ReO 4) and [CuL](ReO 4) 2 (L is 4,6,6-trimethyl-1,9-diamino-3,7- diazanon-3-en) are studied. The square coordination of the copper atom in [CuL](NO 3)(ReO 4) is completed to a distorted octahedron by two oxygen atoms: Cu⋯O (ReO 4 - ) 2.393 Å and Cu⋯O (NO 3 - ) 2.685 Å, and that in [CuL](ReO 4) 2, by Cu⋯O(ReO 4 - ) 2.468 Å and 2.697 Å. The products of thermolysis of the salts in a hydrogen atmosphere at 800°C are mixtures of nanocrystalline metal powders with coherent scattering regions of ∼45 nm.

KW - copper

KW - crystal chemistry

KW - rhenium

KW - single crystal X-ray diffraction

KW - thermal studies

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