Crystal stRucture and properties of [M(NH3)2(M=Ir, Rh, Ru)

P. E. Plyusnin, E. Yu Semitut, I. A. Baidina, L. A. Sheludyakova, S. V. Korenev

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The crystal structures of compounds from the series [M(NH3)2(M=Ir, Rh,Ru) were described. The compounds crystallized in the tetragonal crystal system, space group I4, Z = 2. Crystal data for [Ir(NH3)5Cl](NO3)2<(I): a = 7.6061(1) Å, b = 7.6061(1) Å, c = 10.4039(2) Å, V = 601.894(16) Å3, ρcalc = 2.410 g/cm3, R = 0.0087; [Rh(NH3)5Cl](NO3)2<(II): a = 7.5858(5) Å, b = 7.5858(5) Å, c = 10.41357(7) Å, V = 599.24(7) Å3, ρcalc = 1.926 g/cm3, R = 0.0255; [Ru(NH3)5Cl](NO3)2<(III): a = 7.5811(6) Å, b = 7.5811(6) Å, c = 10.5352(14) Å, V = 605.49(11) Å3, ρcalc = 1.896 g/cm3, R = 0.0266. The compounds were defined by IR spectroscopy and XRPA and thermal analyses.

Original languageEnglish
Pages (from-to)479-484
Number of pages6
JournalJournal of Structural Chemistry
Volume50
Issue number3
DOIs
Publication statusPublished - Jul 2009
Externally publishedYes

Fingerprint

Crystal structure
Crystals
crystal structure
crystals
Infrared spectroscopy
spectroscopy
Hot Temperature

Keywords

  • Chloropentammines
  • Iridium
  • Nitrates
  • Rhodium
  • Ruthenium
  • X-ray analysis
  • X-ray phase analysis

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Plyusnin, P. E., Semitut, E. Y., Baidina, I. A., Sheludyakova, L. A., & Korenev, S. V. (2009). Crystal stRucture and properties of [M(NH3)2(M=Ir, Rh, Ru). Journal of Structural Chemistry, 50(3), 479-484. https://doi.org/10.1007/s10947-009-0072-5

Crystal stRucture and properties of [M(NH3)2(M=Ir, Rh, Ru). / Plyusnin, P. E.; Semitut, E. Yu; Baidina, I. A.; Sheludyakova, L. A.; Korenev, S. V.

In: Journal of Structural Chemistry, Vol. 50, No. 3, 07.2009, p. 479-484.

Research output: Contribution to journalArticle

Plyusnin, PE, Semitut, EY, Baidina, IA, Sheludyakova, LA & Korenev, SV 2009, 'Crystal stRucture and properties of [M(NH3)2(M=Ir, Rh, Ru)', Journal of Structural Chemistry, vol. 50, no. 3, pp. 479-484. https://doi.org/10.1007/s10947-009-0072-5
Plyusnin PE, Semitut EY, Baidina IA, Sheludyakova LA, Korenev SV. Crystal stRucture and properties of [M(NH3)2(M=Ir, Rh, Ru). Journal of Structural Chemistry. 2009 Jul;50(3):479-484. https://doi.org/10.1007/s10947-009-0072-5
Plyusnin, P. E. ; Semitut, E. Yu ; Baidina, I. A. ; Sheludyakova, L. A. ; Korenev, S. V. / Crystal stRucture and properties of [M(NH3)2(M=Ir, Rh, Ru). In: Journal of Structural Chemistry. 2009 ; Vol. 50, No. 3. pp. 479-484.
@article{1fd9bc3661ce45a0b16109a24fa90c84,
title = "Crystal stRucture and properties of [M(NH3)2(M=Ir, Rh, Ru)",
abstract = "The crystal structures of compounds from the series [M(NH3)2(M=Ir, Rh,Ru) were described. The compounds crystallized in the tetragonal crystal system, space group I4, Z = 2. Crystal data for [Ir(NH3)5Cl](NO3)2<(I): a = 7.6061(1) {\AA}, b = 7.6061(1) {\AA}, c = 10.4039(2) {\AA}, V = 601.894(16) {\AA}3, ρcalc = 2.410 g/cm3, R = 0.0087; [Rh(NH3)5Cl](NO3)2<(II): a = 7.5858(5) {\AA}, b = 7.5858(5) {\AA}, c = 10.41357(7) {\AA}, V = 599.24(7) {\AA}3, ρcalc = 1.926 g/cm3, R = 0.0255; [Ru(NH3)5Cl](NO3)2<(III): a = 7.5811(6) {\AA}, b = 7.5811(6) {\AA}, c = 10.5352(14) {\AA}, V = 605.49(11) {\AA}3, ρcalc = 1.896 g/cm3, R = 0.0266. The compounds were defined by IR spectroscopy and XRPA and thermal analyses.",
keywords = "Chloropentammines, Iridium, Nitrates, Rhodium, Ruthenium, X-ray analysis, X-ray phase analysis",
author = "Plyusnin, {P. E.} and Semitut, {E. Yu} and Baidina, {I. A.} and Sheludyakova, {L. A.} and Korenev, {S. V.}",
year = "2009",
month = "7",
doi = "10.1007/s10947-009-0072-5",
language = "English",
volume = "50",
pages = "479--484",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "3",

}

TY - JOUR

T1 - Crystal stRucture and properties of [M(NH3)2(M=Ir, Rh, Ru)

AU - Plyusnin, P. E.

AU - Semitut, E. Yu

AU - Baidina, I. A.

AU - Sheludyakova, L. A.

AU - Korenev, S. V.

PY - 2009/7

Y1 - 2009/7

N2 - The crystal structures of compounds from the series [M(NH3)2(M=Ir, Rh,Ru) were described. The compounds crystallized in the tetragonal crystal system, space group I4, Z = 2. Crystal data for [Ir(NH3)5Cl](NO3)2<(I): a = 7.6061(1) Å, b = 7.6061(1) Å, c = 10.4039(2) Å, V = 601.894(16) Å3, ρcalc = 2.410 g/cm3, R = 0.0087; [Rh(NH3)5Cl](NO3)2<(II): a = 7.5858(5) Å, b = 7.5858(5) Å, c = 10.41357(7) Å, V = 599.24(7) Å3, ρcalc = 1.926 g/cm3, R = 0.0255; [Ru(NH3)5Cl](NO3)2<(III): a = 7.5811(6) Å, b = 7.5811(6) Å, c = 10.5352(14) Å, V = 605.49(11) Å3, ρcalc = 1.896 g/cm3, R = 0.0266. The compounds were defined by IR spectroscopy and XRPA and thermal analyses.

AB - The crystal structures of compounds from the series [M(NH3)2(M=Ir, Rh,Ru) were described. The compounds crystallized in the tetragonal crystal system, space group I4, Z = 2. Crystal data for [Ir(NH3)5Cl](NO3)2<(I): a = 7.6061(1) Å, b = 7.6061(1) Å, c = 10.4039(2) Å, V = 601.894(16) Å3, ρcalc = 2.410 g/cm3, R = 0.0087; [Rh(NH3)5Cl](NO3)2<(II): a = 7.5858(5) Å, b = 7.5858(5) Å, c = 10.41357(7) Å, V = 599.24(7) Å3, ρcalc = 1.926 g/cm3, R = 0.0255; [Ru(NH3)5Cl](NO3)2<(III): a = 7.5811(6) Å, b = 7.5811(6) Å, c = 10.5352(14) Å, V = 605.49(11) Å3, ρcalc = 1.896 g/cm3, R = 0.0266. The compounds were defined by IR spectroscopy and XRPA and thermal analyses.

KW - Chloropentammines

KW - Iridium

KW - Nitrates

KW - Rhodium

KW - Ruthenium

KW - X-ray analysis

KW - X-ray phase analysis

UR - http://www.scopus.com/inward/record.url?scp=70350686808&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=70350686808&partnerID=8YFLogxK

U2 - 10.1007/s10947-009-0072-5

DO - 10.1007/s10947-009-0072-5

M3 - Article

VL - 50

SP - 479

EP - 484

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 3

ER -