Copper(II) thenoyltrifluoroacetonate as acceptor matrix in design of heterospin complexes

Ilia Yeltsov, Victor Ovcharenko, Vladimir Ikorskii, Galina Romanenko, Sergei Vasilevsky

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

Coordination compounds of Cu(II) thenoyltrifluoroacetonate with stable 2-imidazoline nitroxides were synthesized; their structure and magnetic properties were investigated. The complex with a pyrazole nitroxide was isolated as two polymorphous modifications. For both polymorphs, the structure is comprised of Cu(tta)2(NITPz1.3Me) molecules shaped as nearly regular pyramids with four O atoms of the two tta ligands lying at the base. The solid polymorphs are constructed from formal binuclear fragments appearing when the pyramid bases of two neighboring molecules approach each other forming rather short contacts Cu - S (3.848 and 3.596 Å), due to which the polymorphs differ considerably in magnetic properties. In the modification with longer Cu - S distances, there are no exchange interactions between the paramagnetic centers of the neighboring Cu(tta)2(NITPz1.3Me) molecules whereas in the polymorph with shorter Cu - S distances the interactions are significant and analogous to those in real dimer molecules based on the Cu(AcO)2 matrix with a nitroxide.

Original languageEnglish
Pages (from-to)1215-1222
Number of pages8
JournalPolyhedron
Volume20
Issue number11-14
DOIs
Publication statusPublished - 30 May 2001
Externally publishedYes

Fingerprint

Polymorphism
Copper
copper
Molecules
matrices
pyramids
molecules
Magnetic properties
magnetic properties
Exchange interactions
Dimers
Ligands
dimers
fragments
interactions
Atoms
ligands
atoms

Keywords

  • Copper(II)
  • Dimers
  • Nitroxide
  • Polymorphous modifications

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Copper(II) thenoyltrifluoroacetonate as acceptor matrix in design of heterospin complexes. / Yeltsov, Ilia; Ovcharenko, Victor; Ikorskii, Vladimir; Romanenko, Galina; Vasilevsky, Sergei.

In: Polyhedron, Vol. 20, No. 11-14, 30.05.2001, p. 1215-1222.

Research output: Contribution to journalArticle

Yeltsov, Ilia ; Ovcharenko, Victor ; Ikorskii, Vladimir ; Romanenko, Galina ; Vasilevsky, Sergei. / Copper(II) thenoyltrifluoroacetonate as acceptor matrix in design of heterospin complexes. In: Polyhedron. 2001 ; Vol. 20, No. 11-14. pp. 1215-1222.
@article{193edb26bd36440ab1d223998fc38f8c,
title = "Copper(II) thenoyltrifluoroacetonate as acceptor matrix in design of heterospin complexes",
abstract = "Coordination compounds of Cu(II) thenoyltrifluoroacetonate with stable 2-imidazoline nitroxides were synthesized; their structure and magnetic properties were investigated. The complex with a pyrazole nitroxide was isolated as two polymorphous modifications. For both polymorphs, the structure is comprised of Cu(tta)2(NITPz1.3Me) molecules shaped as nearly regular pyramids with four O atoms of the two tta ligands lying at the base. The solid polymorphs are constructed from formal binuclear fragments appearing when the pyramid bases of two neighboring molecules approach each other forming rather short contacts Cu - S (3.848 and 3.596 {\AA}), due to which the polymorphs differ considerably in magnetic properties. In the modification with longer Cu - S distances, there are no exchange interactions between the paramagnetic centers of the neighboring Cu(tta)2(NITPz1.3Me) molecules whereas in the polymorph with shorter Cu - S distances the interactions are significant and analogous to those in real dimer molecules based on the Cu(AcO)2 matrix with a nitroxide.",
keywords = "Copper(II), Dimers, Nitroxide, Polymorphous modifications",
author = "Ilia Yeltsov and Victor Ovcharenko and Vladimir Ikorskii and Galina Romanenko and Sergei Vasilevsky",
year = "2001",
month = "5",
day = "30",
doi = "10.1016/S0277-5387(01)00596-4",
language = "English",
volume = "20",
pages = "1215--1222",
journal = "Polyhedron",
issn = "0277-5387",
publisher = "Elsevier Limited",
number = "11-14",

}

TY - JOUR

T1 - Copper(II) thenoyltrifluoroacetonate as acceptor matrix in design of heterospin complexes

AU - Yeltsov, Ilia

AU - Ovcharenko, Victor

AU - Ikorskii, Vladimir

AU - Romanenko, Galina

AU - Vasilevsky, Sergei

PY - 2001/5/30

Y1 - 2001/5/30

N2 - Coordination compounds of Cu(II) thenoyltrifluoroacetonate with stable 2-imidazoline nitroxides were synthesized; their structure and magnetic properties were investigated. The complex with a pyrazole nitroxide was isolated as two polymorphous modifications. For both polymorphs, the structure is comprised of Cu(tta)2(NITPz1.3Me) molecules shaped as nearly regular pyramids with four O atoms of the two tta ligands lying at the base. The solid polymorphs are constructed from formal binuclear fragments appearing when the pyramid bases of two neighboring molecules approach each other forming rather short contacts Cu - S (3.848 and 3.596 Å), due to which the polymorphs differ considerably in magnetic properties. In the modification with longer Cu - S distances, there are no exchange interactions between the paramagnetic centers of the neighboring Cu(tta)2(NITPz1.3Me) molecules whereas in the polymorph with shorter Cu - S distances the interactions are significant and analogous to those in real dimer molecules based on the Cu(AcO)2 matrix with a nitroxide.

AB - Coordination compounds of Cu(II) thenoyltrifluoroacetonate with stable 2-imidazoline nitroxides were synthesized; their structure and magnetic properties were investigated. The complex with a pyrazole nitroxide was isolated as two polymorphous modifications. For both polymorphs, the structure is comprised of Cu(tta)2(NITPz1.3Me) molecules shaped as nearly regular pyramids with four O atoms of the two tta ligands lying at the base. The solid polymorphs are constructed from formal binuclear fragments appearing when the pyramid bases of two neighboring molecules approach each other forming rather short contacts Cu - S (3.848 and 3.596 Å), due to which the polymorphs differ considerably in magnetic properties. In the modification with longer Cu - S distances, there are no exchange interactions between the paramagnetic centers of the neighboring Cu(tta)2(NITPz1.3Me) molecules whereas in the polymorph with shorter Cu - S distances the interactions are significant and analogous to those in real dimer molecules based on the Cu(AcO)2 matrix with a nitroxide.

KW - Copper(II)

KW - Dimers

KW - Nitroxide

KW - Polymorphous modifications

UR - http://www.scopus.com/inward/record.url?scp=0035972491&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0035972491&partnerID=8YFLogxK

U2 - 10.1016/S0277-5387(01)00596-4

DO - 10.1016/S0277-5387(01)00596-4

M3 - Article

AN - SCOPUS:0035972491

VL - 20

SP - 1215

EP - 1222

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

IS - 11-14

ER -