TY - JOUR
T1 - Copper(II) complexes with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane
T2 - Synthesis, spectroscopic study, and crystal structure
AU - Lider, E. V.
AU - Peresypkina, E. V.
AU - Lavrenova, L. G.
AU - Krivenko, O. L.
AU - Boguslavskii, E. G.
AU - Smolentsev, A. I.
AU - Sheludyakova, L. A.
AU - Vasilevskii, S. F.
PY - 2009/6/1
Y1 - 2009/6/1
N2 - New complexes of copper(II) nitrate, chloride, tetrafluoroborate, perchlorate, and perrhenate with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane (L) were obtained. The molecular and crystal structures of [CuL(H 2O)(NO3)2] • (CH3) 2CO, [CuL2(H2O)][CuL2Cl][CuCl 4], [CuL2](BF4)2 • (CH 3)2CO, and [CuL2(H2O)](ClO 4)2 • (CH3)2CO were determined by X-ray diffraction analysis. In all the complexes, L was found to serve as a chelating bidentate ligand through the N2 and N2? atoms of its pyrazole rings to form a six-membered chelate ring.
AB - New complexes of copper(II) nitrate, chloride, tetrafluoroborate, perchlorate, and perrhenate with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane (L) were obtained. The molecular and crystal structures of [CuL(H 2O)(NO3)2] • (CH3) 2CO, [CuL2(H2O)][CuL2Cl][CuCl 4], [CuL2](BF4)2 • (CH 3)2CO, and [CuL2(H2O)](ClO 4)2 • (CH3)2CO were determined by X-ray diffraction analysis. In all the complexes, L was found to serve as a chelating bidentate ligand through the N2 and N2? atoms of its pyrazole rings to form a six-membered chelate ring.
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U2 - 10.1134/S1070328409060086
DO - 10.1134/S1070328409060086
M3 - Article
AN - SCOPUS:67650922553
VL - 35
SP - 433
EP - 444
JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
SN - 1070-3284
IS - 6
ER -