Copper(II) complexes with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane

Synthesis, spectroscopic study, and crystal structure

E. V. Lider, E. V. Peresypkina, L. G. Lavrenova, O. L. Krivenko, E. G. Boguslavskii, A. I. Smolentsev, L. A. Sheludyakova, S. F. Vasilevskii

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

New complexes of copper(II) nitrate, chloride, tetrafluoroborate, perchlorate, and perrhenate with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane (L) were obtained. The molecular and crystal structures of [CuL(H 2O)(NO3)2] • (CH3) 2CO, [CuL2(H2O)][CuL2Cl][CuCl 4], [CuL2](BF4)2 • (CH 3)2CO, and [CuL2(H2O)](ClO 4)2 • (CH3)2CO were determined by X-ray diffraction analysis. In all the complexes, L was found to serve as a chelating bidentate ligand through the N2 and N2? atoms of its pyrazole rings to form a six-membered chelate ring.

Original languageEnglish
Pages (from-to)433-444
Number of pages12
JournalRussian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume35
Issue number6
DOIs
Publication statusPublished - 1 Jun 2009
Externally publishedYes

Fingerprint

Methane
Chelation
X ray diffraction analysis
Molecular structure
Chlorides
Copper
Nitrates
Crystal structure
Ligands
Atoms
perchlorate
pyrazole
copper(II) nitrate
perrhenate

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Copper(II) complexes with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane : Synthesis, spectroscopic study, and crystal structure. / Lider, E. V.; Peresypkina, E. V.; Lavrenova, L. G.; Krivenko, O. L.; Boguslavskii, E. G.; Smolentsev, A. I.; Sheludyakova, L. A.; Vasilevskii, S. F.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 35, No. 6, 01.06.2009, p. 433-444.

Research output: Contribution to journalArticle

Lider, E. V. ; Peresypkina, E. V. ; Lavrenova, L. G. ; Krivenko, O. L. ; Boguslavskii, E. G. ; Smolentsev, A. I. ; Sheludyakova, L. A. ; Vasilevskii, S. F. / Copper(II) complexes with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane : Synthesis, spectroscopic study, and crystal structure. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2009 ; Vol. 35, No. 6. pp. 433-444.
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abstract = "New complexes of copper(II) nitrate, chloride, tetrafluoroborate, perchlorate, and perrhenate with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane (L) were obtained. The molecular and crystal structures of [CuL(H 2O)(NO3)2] • (CH3) 2CO, [CuL2(H2O)][CuL2Cl][CuCl 4], [CuL2](BF4)2 • (CH 3)2CO, and [CuL2(H2O)](ClO 4)2 • (CH3)2CO were determined by X-ray diffraction analysis. In all the complexes, L was found to serve as a chelating bidentate ligand through the N2 and N2? atoms of its pyrazole rings to form a six-membered chelate ring.",
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T2 - Synthesis, spectroscopic study, and crystal structure

AU - Lider, E. V.

AU - Peresypkina, E. V.

AU - Lavrenova, L. G.

AU - Krivenko, O. L.

AU - Boguslavskii, E. G.

AU - Smolentsev, A. I.

AU - Sheludyakova, L. A.

AU - Vasilevskii, S. F.

PY - 2009/6/1

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N2 - New complexes of copper(II) nitrate, chloride, tetrafluoroborate, perchlorate, and perrhenate with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane (L) were obtained. The molecular and crystal structures of [CuL(H 2O)(NO3)2] • (CH3) 2CO, [CuL2(H2O)][CuL2Cl][CuCl 4], [CuL2](BF4)2 • (CH 3)2CO, and [CuL2(H2O)](ClO 4)2 • (CH3)2CO were determined by X-ray diffraction analysis. In all the complexes, L was found to serve as a chelating bidentate ligand through the N2 and N2? atoms of its pyrazole rings to form a six-membered chelate ring.

AB - New complexes of copper(II) nitrate, chloride, tetrafluoroborate, perchlorate, and perrhenate with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane (L) were obtained. The molecular and crystal structures of [CuL(H 2O)(NO3)2] • (CH3) 2CO, [CuL2(H2O)][CuL2Cl][CuCl 4], [CuL2](BF4)2 • (CH 3)2CO, and [CuL2(H2O)](ClO 4)2 • (CH3)2CO were determined by X-ray diffraction analysis. In all the complexes, L was found to serve as a chelating bidentate ligand through the N2 and N2? atoms of its pyrazole rings to form a six-membered chelate ring.

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