Copper(II) complexes with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane: Synthesis, spectroscopic study, and crystal structure

E. V. Lider, E. V. Peresypkina, L. G. Lavrenova, O. L. Krivenko, E. G. Boguslavskii, A. I. Smolentsev, L. A. Sheludyakova, S. F. Vasilevskii

Research output: Contribution to journal › Article

3 Citations (Scopus)

Abstract

New complexes of copper(II) nitrate, chloride, tetrafluoroborate, perchlorate, and perrhenate with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane (L) were obtained. The molecular and crystal structures of [CuL(H ₂O)(NO₃)₂] • (CH₃) ₂CO, [CuL₂(H₂O)][CuL₂Cl][CuCl ₄], [CuL₂](BF₄)₂ • (CH ₃)₂CO, and [CuL₂(H₂O)](ClO ₄)₂ • (CH₃)₂CO were determined by X-ray diffraction analysis. In all the complexes, L was found to serve as a chelating bidentate ligand through the N² and N^2? atoms of its pyrazole rings to form a six-membered chelate ring.

Original language	English
Pages (from-to)	433-444
Number of pages	12
Journal	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume	35
Issue number	6
DOIs	https://doi.org/10.1134/S1070328409060086
Publication status	Published - 1 Jun 2009
Externally published	Yes

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ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)

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Lider, E. V., Peresypkina, E. V., Lavrenova, L. G., Krivenko, O. L., Boguslavskii, E. G., Smolentsev, A. I., ... Vasilevskii, S. F. (2009). Copper(II) complexes with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane: Synthesis, spectroscopic study, and crystal structure. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 35(6), 433-444. https://doi.org/10.1134/S1070328409060086

Copper(II) complexes with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane : Synthesis, spectroscopic study, and crystal structure. / Lider, E. V.; Peresypkina, E. V.; Lavrenova, L. G.; Krivenko, O. L.; Boguslavskii, E. G.; Smolentsev, A. I.; Sheludyakova, L. A.; Vasilevskii, S. F.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 35, No. 6, 01.06.2009, p. 433-444.

Research output: Contribution to journal › Article

Lider, EV, Peresypkina, EV, Lavrenova, LG, Krivenko, OL, Boguslavskii, EG, Smolentsev, AI, Sheludyakova, LA & Vasilevskii, SF 2009, 'Copper(II) complexes with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane: Synthesis, spectroscopic study, and crystal structure', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 35, no. 6, pp. 433-444. https://doi.org/10.1134/S1070328409060086

Lider, E. V. ; Peresypkina, E. V. ; Lavrenova, L. G. ; Krivenko, O. L. ; Boguslavskii, E. G. ; Smolentsev, A. I. ; Sheludyakova, L. A. ; Vasilevskii, S. F. / Copper(II) complexes with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane : Synthesis, spectroscopic study, and crystal structure. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2009 ; Vol. 35, No. 6. pp. 433-444.

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abstract = "New complexes of copper(II) nitrate, chloride, tetrafluoroborate, perchlorate, and perrhenate with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane (L) were obtained. The molecular and crystal structures of [CuL(H 2O)(NO3)2] • (CH3) 2CO, [CuL2(H2O)][CuL2Cl][CuCl 4], [CuL2](BF4)2 • (CH 3)2CO, and [CuL2(H2O)](ClO 4)2 • (CH3)2CO were determined by X-ray diffraction analysis. In all the complexes, L was found to serve as a chelating bidentate ligand through the N2 and N2? atoms of its pyrazole rings to form a six-membered chelate ring.",

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AU - Lider, E. V.

AU - Peresypkina, E. V.

AU - Lavrenova, L. G.

AU - Krivenko, O. L.

AU - Boguslavskii, E. G.

AU - Smolentsev, A. I.

AU - Sheludyakova, L. A.

AU - Vasilevskii, S. F.

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N2 - New complexes of copper(II) nitrate, chloride, tetrafluoroborate, perchlorate, and perrhenate with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane (L) were obtained. The molecular and crystal structures of [CuL(H 2O)(NO3)2] • (CH3) 2CO, [CuL2(H2O)][CuL2Cl][CuCl 4], [CuL2](BF4)2 • (CH 3)2CO, and [CuL2(H2O)](ClO 4)2 • (CH3)2CO were determined by X-ray diffraction analysis. In all the complexes, L was found to serve as a chelating bidentate ligand through the N2 and N2? atoms of its pyrazole rings to form a six-membered chelate ring.

AB - New complexes of copper(II) nitrate, chloride, tetrafluoroborate, perchlorate, and perrhenate with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane (L) were obtained. The molecular and crystal structures of [CuL(H 2O)(NO3)2] • (CH3) 2CO, [CuL2(H2O)][CuL2Cl][CuCl 4], [CuL2](BF4)2 • (CH 3)2CO, and [CuL2(H2O)](ClO 4)2 • (CH3)2CO were determined by X-ray diffraction analysis. In all the complexes, L was found to serve as a chelating bidentate ligand through the N2 and N2? atoms of its pyrazole rings to form a six-membered chelate ring.

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10.1134/S1070328409060086