Copper(II) complexes with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane: Synthesis, spectroscopic study, and crystal structure

Abstract

New complexes of copper(II) nitrate, chloride, tetrafluoroborate, perchlorate, and perrhenate with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane (L) were obtained. The molecular and crystal structures of [CuL(H ₂O)(NO₃)₂] • (CH₃) ₂CO, [CuL₂(H₂O)][CuL₂Cl][CuCl ₄], [CuL₂](BF₄)₂ • (CH ₃)₂CO, and [CuL₂(H₂O)](ClO ₄)₂ • (CH₃)₂CO were determined by X-ray diffraction analysis. In all the complexes, L was found to serve as a chelating bidentate ligand through the N² and N^2? atoms of its pyrazole rings to form a six-membered chelate ring.

Original language	English
Pages (from-to)	433-444
Number of pages	12
Journal	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume	35
Issue number	6
DOIs	https://doi.org/10.1134/S1070328409060086
Publication status	Published - 1 Jun 2009
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)

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Lider, E. V., Peresypkina, E. V., Lavrenova, L. G., Krivenko, O. L., Boguslavskii, E. G., Smolentsev, A. I., Sheludyakova, L. A., & Vasilevskii, S. F. (2009). Copper(II) complexes with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane: Synthesis, spectroscopic study, and crystal structure. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 35(6), 433-444. https://doi.org/10.1134/S1070328409060086

Copper(II) complexes with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane : Synthesis, spectroscopic study, and crystal structure. / Lider, E. V.; Peresypkina, E. V.; Lavrenova, L. G.; Krivenko, O. L.; Boguslavskii, E. G.; Smolentsev, A. I.; Sheludyakova, L. A.; Vasilevskii, S. F.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 35, No. 6, 01.06.2009, p. 433-444.

Research output: Contribution to journal › Article › peer-review

Lider, EV, Peresypkina, EV, Lavrenova, LG, Krivenko, OL, Boguslavskii, EG, Smolentsev, AI, Sheludyakova, LA & Vasilevskii, SF 2009, 'Copper(II) complexes with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane: Synthesis, spectroscopic study, and crystal structure', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 35, no. 6, pp. 433-444. https://doi.org/10.1134/S1070328409060086

Lider, E. V. ; Peresypkina, E. V. ; Lavrenova, L. G. ; Krivenko, O. L. ; Boguslavskii, E. G. ; Smolentsev, A. I. ; Sheludyakova, L. A. ; Vasilevskii, S. F. / Copper(II) complexes with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane : Synthesis, spectroscopic study, and crystal structure. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2009 ; Vol. 35, No. 6. pp. 433-444.

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abstract = "New complexes of copper(II) nitrate, chloride, tetrafluoroborate, perchlorate, and perrhenate with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane (L) were obtained. The molecular and crystal structures of [CuL(H 2O)(NO3)2] • (CH3) 2CO, [CuL2(H2O)][CuL2Cl][CuCl 4], [CuL2](BF4)2 • (CH 3)2CO, and [CuL2(H2O)](ClO 4)2 • (CH3)2CO were determined by X-ray diffraction analysis. In all the complexes, L was found to serve as a chelating bidentate ligand through the N2 and N2? atoms of its pyrazole rings to form a six-membered chelate ring.",

author = "Lider, {E. V.} and Peresypkina, {E. V.} and Lavrenova, {L. G.} and Krivenko, {O. L.} and Boguslavskii, {E. G.} and Smolentsev, {A. I.} and Sheludyakova, {L. A.} and Vasilevskii, {S. F.}",

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AU - Lider, E. V.

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AU - Lavrenova, L. G.

AU - Krivenko, O. L.

AU - Boguslavskii, E. G.

AU - Smolentsev, A. I.

AU - Sheludyakova, L. A.

AU - Vasilevskii, S. F.

PY - 2009/6/1

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N2 - New complexes of copper(II) nitrate, chloride, tetrafluoroborate, perchlorate, and perrhenate with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane (L) were obtained. The molecular and crystal structures of [CuL(H 2O)(NO3)2] • (CH3) 2CO, [CuL2(H2O)][CuL2Cl][CuCl 4], [CuL2](BF4)2 • (CH 3)2CO, and [CuL2(H2O)](ClO 4)2 • (CH3)2CO were determined by X-ray diffraction analysis. In all the complexes, L was found to serve as a chelating bidentate ligand through the N2 and N2? atoms of its pyrazole rings to form a six-membered chelate ring.

AB - New complexes of copper(II) nitrate, chloride, tetrafluoroborate, perchlorate, and perrhenate with bis(4-iodo-3,5-dimethylpyrazol-1-yl)methane (L) were obtained. The molecular and crystal structures of [CuL(H 2O)(NO3)2] • (CH3) 2CO, [CuL2(H2O)][CuL2Cl][CuCl 4], [CuL2](BF4)2 • (CH 3)2CO, and [CuL2(H2O)](ClO 4)2 • (CH3)2CO were determined by X-ray diffraction analysis. In all the complexes, L was found to serve as a chelating bidentate ligand through the N2 and N2? atoms of its pyrazole rings to form a six-membered chelate ring.

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