Coordination polymers with adjustable dimensionality based on CuII and bis-imidazolyl bridging ligand

M. O. Barsukova, D. G. Samsonenko, T. V. Goncharova, A. S. Potapov, S. A. Sapchenko, D. N. Dybtsev, V. P. Fedin

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

1,4-Bis(imidazol-1-yl)butane was synthesized from imidazole and 1,4-dibromobutane in an alkaline medium. A variation of the molar ratio of reagents in the system copper(II) chloride dihydrate and 1,4-bis(imidazol-1-yl)butane (bImB) upon heating in N,N-dimethylformamide resulted in the synthesis of two new coordination polymers [Cu(bImB)Cl2] (1) and [Cu(bImB)2Cl2] (2), which were structurally characterized. Product 1 was found to possess a chain structure, while structure 2 is built of neutral layers, with the dimensionality of the extended coordination structures being determined by the reaction conditions. The new compounds were characterized by IR spectroscopy, elemental analysis, and powder X-ray diffraction data.

Original languageEnglish
Pages (from-to)2914-2919
Number of pages6
JournalRussian Chemical Bulletin
Volume65
Issue number12
DOIs
Publication statusPublished - 1 Dec 2016

Fingerprint

Polymers
Ligands
Dimethylformamide
X ray powder diffraction
Infrared spectroscopy
Heating
Chemical analysis
butane
imidazole
1,4-dibromobutane
cupric chloride

Keywords

  • bis(imidazolyl)alkanes
  • coordination polymer
  • copper
  • X-ray diffraction

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Barsukova, M. O., Samsonenko, D. G., Goncharova, T. V., Potapov, A. S., Sapchenko, S. A., Dybtsev, D. N., & Fedin, V. P. (2016). Coordination polymers with adjustable dimensionality based on CuII and bis-imidazolyl bridging ligand. Russian Chemical Bulletin, 65(12), 2914-2919. https://doi.org/10.1007/s11172-016-1677-4

Coordination polymers with adjustable dimensionality based on CuII and bis-imidazolyl bridging ligand. / Barsukova, M. O.; Samsonenko, D. G.; Goncharova, T. V.; Potapov, A. S.; Sapchenko, S. A.; Dybtsev, D. N.; Fedin, V. P.

In: Russian Chemical Bulletin, Vol. 65, No. 12, 01.12.2016, p. 2914-2919.

Research output: Contribution to journalArticle

Barsukova, MO, Samsonenko, DG, Goncharova, TV, Potapov, AS, Sapchenko, SA, Dybtsev, DN & Fedin, VP 2016, 'Coordination polymers with adjustable dimensionality based on CuII and bis-imidazolyl bridging ligand', Russian Chemical Bulletin, vol. 65, no. 12, pp. 2914-2919. https://doi.org/10.1007/s11172-016-1677-4
Barsukova, M. O. ; Samsonenko, D. G. ; Goncharova, T. V. ; Potapov, A. S. ; Sapchenko, S. A. ; Dybtsev, D. N. ; Fedin, V. P. / Coordination polymers with adjustable dimensionality based on CuII and bis-imidazolyl bridging ligand. In: Russian Chemical Bulletin. 2016 ; Vol. 65, No. 12. pp. 2914-2919.
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AB - 1,4-Bis(imidazol-1-yl)butane was synthesized from imidazole and 1,4-dibromobutane in an alkaline medium. A variation of the molar ratio of reagents in the system copper(II) chloride dihydrate and 1,4-bis(imidazol-1-yl)butane (bImB) upon heating in N,N-dimethylformamide resulted in the synthesis of two new coordination polymers [Cu(bImB)Cl2] (1) and [Cu(bImB)2Cl2] (2), which were structurally characterized. Product 1 was found to possess a chain structure, while structure 2 is built of neutral layers, with the dimensionality of the extended coordination structures being determined by the reaction conditions. The new compounds were characterized by IR spectroscopy, elemental analysis, and powder X-ray diffraction data.

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