High–resolution infrared spectra of the D2S molecule were experimentally recorded with a Bruker IFS 125HR Fourier transform infrared spectrometer and theoretically analyzed in the region of 700 – 1800 cm−1, where the ν2 and 2ν2 bands are located. For the first time, transitions were assigned to the 2ν2 and 2ν2−ν2 bands of the D2 32S and D2 34S isotopologues. For the ground vibrational state and the ν2 band of D2 34S, the spectral information was considerably extended in comparison with preceding works. For the first time, transitions belonging to the rare D2 33S hydrogen sulfide species were assigned to the ν2 and 2ν2 bands, as well as a rotational structure of the ground vibrational state of D2 33S was determined on the basis of experimental values of the ground state combination differences (maximum values of quantum numbers for used ground state combination differences were Jmax=19, Ka max=8, ΔJmax=2, ΔKa max=2). Sets of spectroscopic parameters of the Watson hamiltonian in A−reduction and Ir−representation was determined for the (010) and (020) vibrational states of all three discussed species and for the ground vibrational states of D2 34S and D2 33S from the weighted fit of parameters of this hamiltonian. The drms of reproduction of the initial experimental data for all nine vibrational states (three vibrational states for any species) is not far from 1×10−4 cm−1 which is close to experimental errors in line positions.
|Journal||Journal of Quantitative Spectroscopy and Radiative Transfer|
|Publication status||Published - Sep 2020|
ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics