TY - GEN
T1 - Composition of compounds bounded via sulfide and ether bridges in oils of the organic matter of oil shale of the Dmitrievskoye field
AU - Kovalenko, Elena Yu
AU - Sagachenko, Tatiana A.
AU - Min, Raisa S.
AU - Grin'Ko, Andrei A.
N1 - Funding Information:
This work was performed as part of the state assignment of the Institute of Petroleum Chemistry of the SB RAS (Project V.46.2.2), funded by the Ministry of Science and Higher Education of the Russian Federation.
Publisher Copyright:
© 2020 American Institute of Physics Inc.. All rights reserved.
Copyright:
Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2020/12/14
Y1 - 2020/12/14
N2 - The method of selective chemical destruction reveals that the compounds linked to each other or to other structural fragments via ether and sulfide bridges are present in addition to the components in molecular form in the oil of the organic matter of oil shale from the Dmitrievskoye field. It is shown using chromatography-mass spectrometry that “sulfur-bound” and 'ether-bound' saturated and polycycloaromatic hydrocarbons are represented by n-alkanes, hopanes, naphthalenes, biphenyls, phenanthrenes, phenylnaphthalenes, fluorenes, fluorantenes, pyrenes and benzo[c]phenanthrene, perylenes and benzo[e]pyrenes. Unsubstituted structures, namely naphthalene, fluorene, triphenylene, and indeno[1,2,3cd]fluorantene are only linked through a functional C-S group. The results of the study expand the understanding of the composition of the organic matter of oil shales. They are important for the choice of methods for their processing in order to obtain chemically useful components based on oil shale material, including motor fuels.
AB - The method of selective chemical destruction reveals that the compounds linked to each other or to other structural fragments via ether and sulfide bridges are present in addition to the components in molecular form in the oil of the organic matter of oil shale from the Dmitrievskoye field. It is shown using chromatography-mass spectrometry that “sulfur-bound” and 'ether-bound' saturated and polycycloaromatic hydrocarbons are represented by n-alkanes, hopanes, naphthalenes, biphenyls, phenanthrenes, phenylnaphthalenes, fluorenes, fluorantenes, pyrenes and benzo[c]phenanthrene, perylenes and benzo[e]pyrenes. Unsubstituted structures, namely naphthalene, fluorene, triphenylene, and indeno[1,2,3cd]fluorantene are only linked through a functional C-S group. The results of the study expand the understanding of the composition of the organic matter of oil shales. They are important for the choice of methods for their processing in order to obtain chemically useful components based on oil shale material, including motor fuels.
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U2 - 10.1063/5.0034672
DO - 10.1063/5.0034672
M3 - Conference contribution
AN - SCOPUS:85097987327
T3 - AIP Conference Proceedings
BT - Proceedings of the International Conference on Physical Mesomechanics. Materials with Multilevel Hierarchical Structure and Intelligent Manufacturing Technology
A2 - Panin, Victor E.
A2 - Fomin, Vasily M.
PB - American Institute of Physics Inc.
T2 - International Conference on Physical Mesomechanics. Materials with Multilevel Hierarchical Structure and Intelligent Manufacturing Technology 2020
Y2 - 5 October 2020 through 9 October 2020
ER -