Complex of ytterbium ethylenediaminetetraacetate as combined NMR paramagnetic probe for in situ control of temperature and pH in aqueous media

Sergey P. Babailov, Eugeny N. Zapolotsky

    Research output: Contribution to journalArticle

    1 Citation (Scopus)

    Abstract

    The paper reports variations in LIS for [Yb(H2O)n(EDTA)] and [Yb2(EDTA)3]6− complexes as a result of variation in pD and temperature. This is the first detection of kinetically stable complexes of the yttrium subgroup with stoichiometric ratio of 2:3. The experimental paramagnetic lanthanide-induced chemical shift values of these compounds are well fitted by linear dependence on 1/T at different pH values. The [Yb(H2O)n(EDTA)] complex can be considered as one of the most promising combined NMR spectroscopic probe to determine temperature and pH in aqueous media.

    Original languageEnglish
    Pages (from-to)323-326
    Number of pages4
    JournalPolyhedron
    Volume139
    DOIs
    Publication statusPublished - 8 Jan 2018

    Fingerprint

    Ytterbium
    ethylenediaminetetraacetic acids
    Ethylenediaminetetraacetic acid
    ytterbium
    Edetic Acid
    Nuclear magnetic resonance
    nuclear magnetic resonance
    probes
    Yttrium
    Lanthanoid Series Elements
    Chemical shift
    subgroups
    Rare earth elements
    yttrium
    Temperature
    temperature
    chemical equilibrium

    Keywords

    • Aqueous solutions
    • Complexes of lanthanides
    • Lanthanide-induced shifts in NMR spectra
    • Temperature and pH sensitive NMR lanthanide paramagnetic probe
    • Ytterbium

    ASJC Scopus subject areas

    • Physical and Theoretical Chemistry
    • Inorganic Chemistry
    • Materials Chemistry

    Cite this

    Complex of ytterbium ethylenediaminetetraacetate as combined NMR paramagnetic probe for in situ control of temperature and pH in aqueous media. / Babailov, Sergey P.; Zapolotsky, Eugeny N.

    In: Polyhedron, Vol. 139, 08.01.2018, p. 323-326.

    Research output: Contribution to journalArticle

    @article{c392a18e92cb4feebbb7def5aa10b24b,
    title = "Complex of ytterbium ethylenediaminetetraacetate as combined NMR paramagnetic probe for in situ control of temperature and pH in aqueous media",
    abstract = "The paper reports variations in LIS for [Yb(H2O)n(EDTA)]− and [Yb2(EDTA)3]6− complexes as a result of variation in pD and temperature. This is the first detection of kinetically stable complexes of the yttrium subgroup with stoichiometric ratio of 2:3. The experimental paramagnetic lanthanide-induced chemical shift values of these compounds are well fitted by linear dependence on 1/T at different pH values. The [Yb(H2O)n(EDTA)]− complex can be considered as one of the most promising combined NMR spectroscopic probe to determine temperature and pH in aqueous media.",
    keywords = "Aqueous solutions, Complexes of lanthanides, Lanthanide-induced shifts in NMR spectra, Temperature and pH sensitive NMR lanthanide paramagnetic probe, Ytterbium",
    author = "Babailov, {Sergey P.} and Zapolotsky, {Eugeny N.}",
    year = "2018",
    month = "1",
    day = "8",
    doi = "10.1016/j.poly.2017.11.007",
    language = "English",
    volume = "139",
    pages = "323--326",
    journal = "Polyhedron",
    issn = "0277-5387",
    publisher = "Elsevier Limited",

    }

    TY - JOUR

    T1 - Complex of ytterbium ethylenediaminetetraacetate as combined NMR paramagnetic probe for in situ control of temperature and pH in aqueous media

    AU - Babailov, Sergey P.

    AU - Zapolotsky, Eugeny N.

    PY - 2018/1/8

    Y1 - 2018/1/8

    N2 - The paper reports variations in LIS for [Yb(H2O)n(EDTA)]− and [Yb2(EDTA)3]6− complexes as a result of variation in pD and temperature. This is the first detection of kinetically stable complexes of the yttrium subgroup with stoichiometric ratio of 2:3. The experimental paramagnetic lanthanide-induced chemical shift values of these compounds are well fitted by linear dependence on 1/T at different pH values. The [Yb(H2O)n(EDTA)]− complex can be considered as one of the most promising combined NMR spectroscopic probe to determine temperature and pH in aqueous media.

    AB - The paper reports variations in LIS for [Yb(H2O)n(EDTA)]− and [Yb2(EDTA)3]6− complexes as a result of variation in pD and temperature. This is the first detection of kinetically stable complexes of the yttrium subgroup with stoichiometric ratio of 2:3. The experimental paramagnetic lanthanide-induced chemical shift values of these compounds are well fitted by linear dependence on 1/T at different pH values. The [Yb(H2O)n(EDTA)]− complex can be considered as one of the most promising combined NMR spectroscopic probe to determine temperature and pH in aqueous media.

    KW - Aqueous solutions

    KW - Complexes of lanthanides

    KW - Lanthanide-induced shifts in NMR spectra

    KW - Temperature and pH sensitive NMR lanthanide paramagnetic probe

    KW - Ytterbium

    UR - http://www.scopus.com/inward/record.url?scp=85034965626&partnerID=8YFLogxK

    UR - http://www.scopus.com/inward/citedby.url?scp=85034965626&partnerID=8YFLogxK

    U2 - 10.1016/j.poly.2017.11.007

    DO - 10.1016/j.poly.2017.11.007

    M3 - Article

    AN - SCOPUS:85034965626

    VL - 139

    SP - 323

    EP - 326

    JO - Polyhedron

    JF - Polyhedron

    SN - 0277-5387

    ER -