Complex of tris(Z-styryl)phosphine with PdCl2 as a new catalyst for the Sonogashira reaction

Boris A. Trofimov, Sergei F. Vasilevsky, Nina K. Gusarova, Svetlana F. Malysheva, Denis S. Baranov, Victor I. Mamatyuk, Yurii V. Gatilov

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Abstract

The complex [(Z-PhCH=CH)3P]2PdCl2 synthesized from tris(Z-styryl)phosphine and PdCl2 (DMF, 90 °C, 15 min, yield 50%) is an active catalyst in the Sonogashira reaction (coupling between 1-ethynyl-4-nitrobenzene and 1-iodoanthra-9,10-quinone) and its activity is comparable with that of the complex [Ph3P]2PdCl2, the most common catalyst for this type of reactions.

Original languageEnglish
Pages (from-to)318-319
Number of pages2
JournalMendeleev Communications
Volume18
Issue number6
DOIs
Publication statusPublished - 1 Nov 2008
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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    Trofimov, B. A., Vasilevsky, S. F., Gusarova, N. K., Malysheva, S. F., Baranov, D. S., Mamatyuk, V. I., & Gatilov, Y. V. (2008). Complex of tris(Z-styryl)phosphine with PdCl2 as a new catalyst for the Sonogashira reaction. Mendeleev Communications, 18(6), 318-319. https://doi.org/10.1016/j.mencom.2008.11.010