Complex of tris(Z-styryl)phosphine with PdCl₂ as a new catalyst for the Sonogashira reaction

Boris A. Trofimov, Sergei F. Vasilevsky, Nina K. Gusarova, Svetlana F. Malysheva, Denis S. Baranov, Victor I. Mamatyuk, Yurii V. Gatilov

Research output: Contribution to journal › Article

6 Citations (Scopus)

Abstract

The complex [(Z-PhCH=CH)₃P]₂PdCl₂ synthesized from tris(Z-styryl)phosphine and PdCl₂ (DMF, 90 °C, 15 min, yield 50%) is an active catalyst in the Sonogashira reaction (coupling between 1-ethynyl-4-nitrobenzene and 1-iodoanthra-9,10-quinone) and its activity is comparable with that of the complex [Ph₃P]₂PdCl₂, the most common catalyst for this type of reactions.

Original language	English
Pages (from-to)	318-319
Number of pages	2
Journal	Mendeleev Communications
Volume	18
Issue number	6
DOIs	https://doi.org/10.1016/j.mencom.2008.11.010
Publication status	Published - 1 Nov 2008
Externally published	Yes

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phosphine

Catalysts

palladium chloride

ASJC Scopus subject areas

Chemistry(all)

Cite this

Trofimov, B. A., Vasilevsky, S. F., Gusarova, N. K., Malysheva, S. F., Baranov, D. S., Mamatyuk, V. I., & Gatilov, Y. V. (2008). Complex of tris(Z-styryl)phosphine with PdCl₂ as a new catalyst for the Sonogashira reaction. Mendeleev Communications, 18(6), 318-319. https://doi.org/10.1016/j.mencom.2008.11.010

Complex of tris(Z-styryl)phosphine with PdCl₂ as a new catalyst for the Sonogashira reaction. / Trofimov, Boris A.; Vasilevsky, Sergei F.; Gusarova, Nina K.; Malysheva, Svetlana F.; Baranov, Denis S.; Mamatyuk, Victor I.; Gatilov, Yurii V.

In: Mendeleev Communications, Vol. 18, No. 6, 01.11.2008, p. 318-319.

Research output: Contribution to journal › Article

Trofimov, BA, Vasilevsky, SF, Gusarova, NK, Malysheva, SF, Baranov, DS, Mamatyuk, VI & Gatilov, YV 2008, 'Complex of tris(Z-styryl)phosphine with PdCl₂ as a new catalyst for the Sonogashira reaction', Mendeleev Communications, vol. 18, no. 6, pp. 318-319. https://doi.org/10.1016/j.mencom.2008.11.010

Trofimov BA, Vasilevsky SF, Gusarova NK, Malysheva SF, Baranov DS, Mamatyuk VI et al. Complex of tris(Z-styryl)phosphine with PdCl₂ as a new catalyst for the Sonogashira reaction. Mendeleev Communications. 2008 Nov 1;18(6):318-319. https://doi.org/10.1016/j.mencom.2008.11.010

Trofimov, Boris A. ; Vasilevsky, Sergei F. ; Gusarova, Nina K. ; Malysheva, Svetlana F. ; Baranov, Denis S. ; Mamatyuk, Victor I. ; Gatilov, Yurii V. / Complex of tris(Z-styryl)phosphine with PdCl₂ as a new catalyst for the Sonogashira reaction. In: Mendeleev Communications. 2008 ; Vol. 18, No. 6. pp. 318-319.

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abstract = "The complex [(Z-PhCH=CH)3P]2PdCl2 synthesized from tris(Z-styryl)phosphine and PdCl2 (DMF, 90 °C, 15 min, yield 50{\%}) is an active catalyst in the Sonogashira reaction (coupling between 1-ethynyl-4-nitrobenzene and 1-iodoanthra-9,10-quinone) and its activity is comparable with that of the complex [Ph3P]2PdCl2, the most common catalyst for this type of reactions.",

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AU - Baranov, Denis S.

AU - Mamatyuk, Victor I.

AU - Gatilov, Yurii V.

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AB - The complex [(Z-PhCH=CH)3P]2PdCl2 synthesized from tris(Z-styryl)phosphine and PdCl2 (DMF, 90 °C, 15 min, yield 50%) is an active catalyst in the Sonogashira reaction (coupling between 1-ethynyl-4-nitrobenzene and 1-iodoanthra-9,10-quinone) and its activity is comparable with that of the complex [Ph3P]2PdCl2, the most common catalyst for this type of reactions.

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10.1016/j.mencom.2008.11.010