TY - JOUR
T1 - Complex of tris(Z-styryl)phosphine with PdCl2 as a new catalyst for the Sonogashira reaction
AU - Trofimov, Boris A.
AU - Vasilevsky, Sergei F.
AU - Gusarova, Nina K.
AU - Malysheva, Svetlana F.
AU - Baranov, Denis S.
AU - Mamatyuk, Victor I.
AU - Gatilov, Yurii V.
PY - 2008/11/1
Y1 - 2008/11/1
N2 - The complex [(Z-PhCH=CH)3P]2PdCl2 synthesized from tris(Z-styryl)phosphine and PdCl2 (DMF, 90 °C, 15 min, yield 50%) is an active catalyst in the Sonogashira reaction (coupling between 1-ethynyl-4-nitrobenzene and 1-iodoanthra-9,10-quinone) and its activity is comparable with that of the complex [Ph3P]2PdCl2, the most common catalyst for this type of reactions.
AB - The complex [(Z-PhCH=CH)3P]2PdCl2 synthesized from tris(Z-styryl)phosphine and PdCl2 (DMF, 90 °C, 15 min, yield 50%) is an active catalyst in the Sonogashira reaction (coupling between 1-ethynyl-4-nitrobenzene and 1-iodoanthra-9,10-quinone) and its activity is comparable with that of the complex [Ph3P]2PdCl2, the most common catalyst for this type of reactions.
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U2 - 10.1016/j.mencom.2008.11.010
DO - 10.1016/j.mencom.2008.11.010
M3 - Article
AN - SCOPUS:56249087243
VL - 18
SP - 318
EP - 319
JO - Mendeleev Communications
JF - Mendeleev Communications
SN - 0959-9436
IS - 6
ER -