Complex of tris(Z-styryl)phosphine with PdCl₂ as a new catalyst for the Sonogashira reaction

Boris A. Trofimov, Sergei F. Vasilevsky, Nina K. Gusarova, Svetlana F. Malysheva, Denis S. Baranov, Victor I. Mamatyuk, Yurii V. Gatilov

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7 Citations (Scopus)

Abstract

The complex [(Z-PhCH=CH)₃P]₂PdCl₂ synthesized from tris(Z-styryl)phosphine and PdCl₂ (DMF, 90 °C, 15 min, yield 50%) is an active catalyst in the Sonogashira reaction (coupling between 1-ethynyl-4-nitrobenzene and 1-iodoanthra-9,10-quinone) and its activity is comparable with that of the complex [Ph₃P]₂PdCl₂, the most common catalyst for this type of reactions.

Original language	English
Pages (from-to)	318-319
Number of pages	2
Journal	Mendeleev Communications
Volume	18
Issue number	6
DOIs	https://doi.org/10.1016/j.mencom.2008.11.010
Publication status	Published - 1 Nov 2008
Externally published	Yes

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ASJC Scopus subject areas

Chemistry(all)

Cite this

Trofimov, B. A., Vasilevsky, S. F., Gusarova, N. K., Malysheva, S. F., Baranov, D. S., Mamatyuk, V. I., & Gatilov, Y. V. (2008). Complex of tris(Z-styryl)phosphine with PdCl₂ as a new catalyst for the Sonogashira reaction. Mendeleev Communications, 18(6), 318-319. https://doi.org/10.1016/j.mencom.2008.11.010

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title = "Complex of tris(Z-styryl)phosphine with PdCl2 as a new catalyst for the Sonogashira reaction",

abstract = "The complex [(Z-PhCH=CH)3P]2PdCl2 synthesized from tris(Z-styryl)phosphine and PdCl2 (DMF, 90 °C, 15 min, yield 50%) is an active catalyst in the Sonogashira reaction (coupling between 1-ethynyl-4-nitrobenzene and 1-iodoanthra-9,10-quinone) and its activity is comparable with that of the complex [Ph3P]2PdCl2, the most common catalyst for this type of reactions.",

author = "Trofimov, {Boris A.} and Vasilevsky, {Sergei F.} and Gusarova, {Nina K.} and Malysheva, {Svetlana F.} and Baranov, {Denis S.} and Mamatyuk, {Victor I.} and Gatilov, {Yurii V.}",

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T1 - Complex of tris(Z-styryl)phosphine with PdCl2 as a new catalyst for the Sonogashira reaction

AU - Trofimov, Boris A.

AU - Vasilevsky, Sergei F.

AU - Gusarova, Nina K.

AU - Malysheva, Svetlana F.

AU - Baranov, Denis S.

AU - Mamatyuk, Victor I.

AU - Gatilov, Yurii V.

PY - 2008/11/1

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AB - The complex [(Z-PhCH=CH)3P]2PdCl2 synthesized from tris(Z-styryl)phosphine and PdCl2 (DMF, 90 °C, 15 min, yield 50%) is an active catalyst in the Sonogashira reaction (coupling between 1-ethynyl-4-nitrobenzene and 1-iodoanthra-9,10-quinone) and its activity is comparable with that of the complex [Ph3P]2PdCl2, the most common catalyst for this type of reactions.

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10.1016/j.mencom.2008.11.010