Complex of tris(Z-styryl)phosphine with PdCl₂ as a new catalyst for the Sonogashira reaction

Boris A. Trofimov, Sergei F. Vasilevsky, Nina K. Gusarova, Svetlana F. Malysheva, Denis S. Baranov, Victor I. Mamatyuk, Yurii V. Gatilov

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

The complex [(Z-PhCH=CH)₃P]₂PdCl₂ synthesized from tris(Z-styryl)phosphine and PdCl₂ (DMF, 90 °C, 15 min, yield 50%) is an active catalyst in the Sonogashira reaction (coupling between 1-ethynyl-4-nitrobenzene and 1-iodoanthra-9,10-quinone) and its activity is comparable with that of the complex [Ph₃P]₂PdCl₂, the most common catalyst for this type of reactions.

Original language	English
Pages (from-to)	318-319
Number of pages	2
Journal	Mendeleev Communications
Volume	18
Issue number	6
DOIs	https://doi.org/10.1016/j.mencom.2008.11.010
Publication status	Published - 1 Nov 2008
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1016/j.mencom.2008.11.010

Fingerprint Dive into the research topics of 'Complex of tris(Z-styryl)phosphine with PdCl<sub>2</sub> as a new catalyst for the Sonogashira reaction'. Together they form a unique fingerprint.

Cite this

Complex of tris(Z-styryl)phosphine with PdCl₂ as a new catalyst for the Sonogashira reaction. / Trofimov, Boris A.; Vasilevsky, Sergei F.; Gusarova, Nina K.; Malysheva, Svetlana F.; Baranov, Denis S.; Mamatyuk, Victor I.; Gatilov, Yurii V.

In: Mendeleev Communications, Vol. 18, No. 6, 01.11.2008, p. 318-319.

Research output: Contribution to journal › Article › peer-review

@article{785ced0dd9094df08d84c802bf774c7b,

title = "Complex of tris(Z-styryl)phosphine with PdCl2 as a new catalyst for the Sonogashira reaction",

abstract = "The complex [(Z-PhCH=CH)3P]2PdCl2 synthesized from tris(Z-styryl)phosphine and PdCl2 (DMF, 90 °C, 15 min, yield 50%) is an active catalyst in the Sonogashira reaction (coupling between 1-ethynyl-4-nitrobenzene and 1-iodoanthra-9,10-quinone) and its activity is comparable with that of the complex [Ph3P]2PdCl2, the most common catalyst for this type of reactions.",

author = "Trofimov, {Boris A.} and Vasilevsky, {Sergei F.} and Gusarova, {Nina K.} and Malysheva, {Svetlana F.} and Baranov, {Denis S.} and Mamatyuk, {Victor I.} and Gatilov, {Yurii V.}",

year = "2008",

month = nov,

day = "1",

doi = "10.1016/j.mencom.2008.11.010",

language = "English",

volume = "18",

pages = "318--319",

journal = "Mendeleev Communications",

issn = "0959-9436",

publisher = "Elsevier BV",

number = "6",

}

TY - JOUR

T1 - Complex of tris(Z-styryl)phosphine with PdCl2 as a new catalyst for the Sonogashira reaction

AU - Trofimov, Boris A.

AU - Vasilevsky, Sergei F.

AU - Gusarova, Nina K.

AU - Malysheva, Svetlana F.

AU - Baranov, Denis S.

AU - Mamatyuk, Victor I.

AU - Gatilov, Yurii V.

PY - 2008/11/1

Y1 - 2008/11/1

N2 - The complex [(Z-PhCH=CH)3P]2PdCl2 synthesized from tris(Z-styryl)phosphine and PdCl2 (DMF, 90 °C, 15 min, yield 50%) is an active catalyst in the Sonogashira reaction (coupling between 1-ethynyl-4-nitrobenzene and 1-iodoanthra-9,10-quinone) and its activity is comparable with that of the complex [Ph3P]2PdCl2, the most common catalyst for this type of reactions.

AB - The complex [(Z-PhCH=CH)3P]2PdCl2 synthesized from tris(Z-styryl)phosphine and PdCl2 (DMF, 90 °C, 15 min, yield 50%) is an active catalyst in the Sonogashira reaction (coupling between 1-ethynyl-4-nitrobenzene and 1-iodoanthra-9,10-quinone) and its activity is comparable with that of the complex [Ph3P]2PdCl2, the most common catalyst for this type of reactions.

UR - http://www.scopus.com/inward/record.url?scp=56249087243&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=56249087243&partnerID=8YFLogxK

U2 - 10.1016/j.mencom.2008.11.010

DO - 10.1016/j.mencom.2008.11.010

M3 - Article

AN - SCOPUS:56249087243

VL - 18

SP - 318

EP - 319

JO - Mendeleev Communications

JF - Mendeleev Communications

SN - 0959-9436

IS - 6

ER -