Complex catalysts for direct synthesis of dimethyl ether from synthesis gas. Part I study of the catalytic properties

Natalia I. Kosova, Pavel G. Musich, Irina A. Kurzina, Alexander V. Vosmerikov

    Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

    Abstract

    The results of the development of combined process for production of dimethyl ether (CuO/ZnO/Al2O3) and methanol dehydration (g-Al2O3, zeolite (ZSM-5 type) with a silicate modulus (M}) 20, 30, 60, 80, 100, and 200) are presented. The experiments on the influence of the catalysts loading and catalytic conditions were carried out (P=3 MPa, H2/CO=2, T=553 K). It was established that the use of ZSM-5 zeolite catalysts with silicate modulus of 30 allows obtaining the yield of dimethyl ether up to 39%. It was stated that catalytic systems were stable during 180 h.

    Original languageEnglish
    Title of host publicationAdvanced Materials Research
    Pages15-22
    Number of pages8
    Volume872
    DOIs
    Publication statusPublished - 2014
    EventRussian-German Forum on Nanotechnology - Tomsk, Russian Federation
    Duration: 21 May 2013 → 24 May 2013

    Publication series

    NameAdvanced Materials Research
    Volume872
    ISSN (Print)10226680

    Other

    OtherRussian-German Forum on Nanotechnology
    CountryRussian Federation
    CityTomsk
    Period21.5.13 → 24.5.13

    Fingerprint

    Synthesis gas
    Silicates
    Ethers
    Catalysts
    Dehydration
    Methanol
    Experiments

    Keywords

    • Dimethyl ether
    • Methanol
    • Mixed catalysts
    • Synthesis gas
    • Zeolite

    ASJC Scopus subject areas

    • Engineering(all)

    Cite this

    Kosova, N. I., Musich, P. G., Kurzina, I. A., & Vosmerikov, A. V. (2014). Complex catalysts for direct synthesis of dimethyl ether from synthesis gas. Part I study of the catalytic properties. In Advanced Materials Research (Vol. 872, pp. 15-22). (Advanced Materials Research; Vol. 872). https://doi.org/10.4028/www.scientific.net/AMR.872.15

    Complex catalysts for direct synthesis of dimethyl ether from synthesis gas. Part I study of the catalytic properties. / Kosova, Natalia I.; Musich, Pavel G.; Kurzina, Irina A.; Vosmerikov, Alexander V.

    Advanced Materials Research. Vol. 872 2014. p. 15-22 (Advanced Materials Research; Vol. 872).

    Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

    Kosova, NI, Musich, PG, Kurzina, IA & Vosmerikov, AV 2014, Complex catalysts for direct synthesis of dimethyl ether from synthesis gas. Part I study of the catalytic properties. in Advanced Materials Research. vol. 872, Advanced Materials Research, vol. 872, pp. 15-22, Russian-German Forum on Nanotechnology, Tomsk, Russian Federation, 21.5.13. https://doi.org/10.4028/www.scientific.net/AMR.872.15
    Kosova NI, Musich PG, Kurzina IA, Vosmerikov AV. Complex catalysts for direct synthesis of dimethyl ether from synthesis gas. Part I study of the catalytic properties. In Advanced Materials Research. Vol. 872. 2014. p. 15-22. (Advanced Materials Research). https://doi.org/10.4028/www.scientific.net/AMR.872.15
    Kosova, Natalia I. ; Musich, Pavel G. ; Kurzina, Irina A. ; Vosmerikov, Alexander V. / Complex catalysts for direct synthesis of dimethyl ether from synthesis gas. Part I study of the catalytic properties. Advanced Materials Research. Vol. 872 2014. pp. 15-22 (Advanced Materials Research).
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    AU - Vosmerikov, Alexander V.

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