Comparative study of the reactivity of iodinating agents in solution and solid phase

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Abstract

The results of reactions of a series of aromatic substrates with iodine, iodine(I) chloride, and N-iodosuccinimide in solution and solid phase were compared for the first time. In all cases, the general relations holding in the iodination process were similar. Iodine(I) chloride was found to chlorinate anthracene. A high efficiency of solid-phase iodination of β-diketones was demonstrated using dibenzoylmethane as an example.

Original languageEnglish
Pages (from-to)855-859
Number of pages5
JournalRussian Journal of Organic Chemistry
Volume41
Issue number6
DOIs
Publication statusPublished - 1 Jun 2005

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Iodine
Chlorides
Substrates
N-iodosuccinimide
dibenzoylmethane
anthracene

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

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abstract = "The results of reactions of a series of aromatic substrates with iodine, iodine(I) chloride, and N-iodosuccinimide in solution and solid phase were compared for the first time. In all cases, the general relations holding in the iodination process were similar. Iodine(I) chloride was found to chlorinate anthracene. A high efficiency of solid-phase iodination of β-diketones was demonstrated using dibenzoylmethane as an example.",
author = "Krasnokutskaya, {E. A.} and Lesina, {Yu A.} and Gorlushko, {D. A.} and Filimonov, {V. D.}",
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AU - Krasnokutskaya, E. A.

AU - Lesina, Yu A.

AU - Gorlushko, D. A.

AU - Filimonov, V. D.

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AB - The results of reactions of a series of aromatic substrates with iodine, iodine(I) chloride, and N-iodosuccinimide in solution and solid phase were compared for the first time. In all cases, the general relations holding in the iodination process were similar. Iodine(I) chloride was found to chlorinate anthracene. A high efficiency of solid-phase iodination of β-diketones was demonstrated using dibenzoylmethane as an example.

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