TY - JOUR
T1 - Comparative study of the growth of CNTs on stainless steel with and without the external catalyst
AU - Hashempour, Mazdak
AU - Vicenzo, Antonello
AU - Bestetti, Massimiliano
PY - 2013
Y1 - 2013
N2 - Multi-walled carbon nanotubes were synthesized on 316 stainless steel substrate by chemical vapor deposition through two different methods: 1-without use of any external catalyst and using ethylene as the carbon precursor and 2-using ferrocene as an external source of catalyst particles, dissolved in toluene, as the carbon precursor. Carbon nanotubes grown by the two methods were characterized by scanning and transmission electron microscopy and X-ray diffraction methods and were compared subsequently to determine certain characteristics of each method. Good coverage and homogeneity was observed in both cases. However, the carbon layer was thicker and denser in externally catalyzed samples. Two different mechanisms, namely, base and tip modes, were observed for the nanotubes growth, each with particular characteristics stemming from the synthesis methods. Surface nano-features and external catalyst behavior were found to have the dominant role in determining the morphology of carbon filaments in intrinsically and externally catalyzed samples, respectively.
AB - Multi-walled carbon nanotubes were synthesized on 316 stainless steel substrate by chemical vapor deposition through two different methods: 1-without use of any external catalyst and using ethylene as the carbon precursor and 2-using ferrocene as an external source of catalyst particles, dissolved in toluene, as the carbon precursor. Carbon nanotubes grown by the two methods were characterized by scanning and transmission electron microscopy and X-ray diffraction methods and were compared subsequently to determine certain characteristics of each method. Good coverage and homogeneity was observed in both cases. However, the carbon layer was thicker and denser in externally catalyzed samples. Two different mechanisms, namely, base and tip modes, were observed for the nanotubes growth, each with particular characteristics stemming from the synthesis methods. Surface nano-features and external catalyst behavior were found to have the dominant role in determining the morphology of carbon filaments in intrinsically and externally catalyzed samples, respectively.
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U2 - 10.1149/05824.0021ecst
DO - 10.1149/05824.0021ecst
M3 - Article
AN - SCOPUS:84904996858
VL - 58
SP - 21
EP - 31
JO - ECS Transactions
JF - ECS Transactions
SN - 1938-5862
IS - 24
ER -