Comparative study of interference elimination in heavy metals control by Anodic Stripping Voltammetry (ASV) method

E. A. Sosnin, V. N. Batalova, E. Yu Buyanova, V. F. Tarasenko

Research output: Chapter in Book/Report/Conference proceedingConference contribution

6 Citations (Scopus)

Abstract

The conditions for elimination of interference of surface-active organic substances (for e.g., natrium laurilsulfate) or humic acid on anodic peaks of Zn, Cd, Pb and Cu were investigated. Interference of these substances is related to their adsorption on working electrode and formation of strong ion-metal complexes. Both of them are obstacles to reduction of metal ions on the working electrode. Aiming at interfering substances destruction in solutions, the effect of ozone and UV irradiation from mercury quartz lamp (λ∼254 nm) and KrCl-excilamp (λ∼222 nm) was studied. It is presented that KrCl-excilamp is mostly efficient for surface-active organic substances destruction. Effect of Hg-lamp under TiO2 additions in solution is less efficient. And ozone treatment of the sample is not in the least efficient here, except for Cu. All three ways can bo used for Metal+humic acid complexes destruction.

Original languageEnglish
Title of host publicationPhysics and Control
Subtitle of host publicationGeneral Problems and Applications
PublisherInstitute of Electrical and Electronics Engineers Inc.
Pages349-351
Number of pages3
Volume1
ISBN (Electronic)078037939X, 9780780379398
DOIs
Publication statusPublished - 2003
Externally publishedYes
Event1st International Conference Physics and Control, PhysCon 2003 - Saint Petersburg, Russian Federation
Duration: 20 Aug 200322 Aug 2003

Conference

Conference1st International Conference Physics and Control, PhysCon 2003
CountryRussian Federation
CitySaint Petersburg
Period20.8.0322.8.03

Fingerprint

Heavy Metals
Voltammetry
Electric lamps
Ozone
Heavy metals
Comparative Study
Elimination
Metals
Interference
Electrodes
Electrode
Metal complexes
Metal ions
Quartz
Mercury
TiO2
Irradiation
Adsorption
Ions
Humic Substances

Keywords

  • Chemical analysis
  • Electrodes
  • Interference elimination
  • Lamps
  • Oxidation
  • Signal analysis
  • Silver
  • Surface treatment
  • Thermal degradation
  • Zinc

ASJC Scopus subject areas

  • Civil and Structural Engineering
  • Control and Systems Engineering
  • Control and Optimization

Cite this

Sosnin, E. A., Batalova, V. N., Buyanova, E. Y., & Tarasenko, V. F. (2003). Comparative study of interference elimination in heavy metals control by Anodic Stripping Voltammetry (ASV) method. In Physics and Control: General Problems and Applications (Vol. 1, pp. 349-351). [1236846] Institute of Electrical and Electronics Engineers Inc.. https://doi.org/10.1109/PHYCON.2003.1236846

Comparative study of interference elimination in heavy metals control by Anodic Stripping Voltammetry (ASV) method. / Sosnin, E. A.; Batalova, V. N.; Buyanova, E. Yu; Tarasenko, V. F.

Physics and Control: General Problems and Applications. Vol. 1 Institute of Electrical and Electronics Engineers Inc., 2003. p. 349-351 1236846.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Sosnin, EA, Batalova, VN, Buyanova, EY & Tarasenko, VF 2003, Comparative study of interference elimination in heavy metals control by Anodic Stripping Voltammetry (ASV) method. in Physics and Control: General Problems and Applications. vol. 1, 1236846, Institute of Electrical and Electronics Engineers Inc., pp. 349-351, 1st International Conference Physics and Control, PhysCon 2003, Saint Petersburg, Russian Federation, 20.8.03. https://doi.org/10.1109/PHYCON.2003.1236846
Sosnin EA, Batalova VN, Buyanova EY, Tarasenko VF. Comparative study of interference elimination in heavy metals control by Anodic Stripping Voltammetry (ASV) method. In Physics and Control: General Problems and Applications. Vol. 1. Institute of Electrical and Electronics Engineers Inc. 2003. p. 349-351. 1236846 https://doi.org/10.1109/PHYCON.2003.1236846
Sosnin, E. A. ; Batalova, V. N. ; Buyanova, E. Yu ; Tarasenko, V. F. / Comparative study of interference elimination in heavy metals control by Anodic Stripping Voltammetry (ASV) method. Physics and Control: General Problems and Applications. Vol. 1 Institute of Electrical and Electronics Engineers Inc., 2003. pp. 349-351
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AB - The conditions for elimination of interference of surface-active organic substances (for e.g., natrium laurilsulfate) or humic acid on anodic peaks of Zn, Cd, Pb and Cu were investigated. Interference of these substances is related to their adsorption on working electrode and formation of strong ion-metal complexes. Both of them are obstacles to reduction of metal ions on the working electrode. Aiming at interfering substances destruction in solutions, the effect of ozone and UV irradiation from mercury quartz lamp (λ∼254 nm) and KrCl-excilamp (λ∼222 nm) was studied. It is presented that KrCl-excilamp is mostly efficient for surface-active organic substances destruction. Effect of Hg-lamp under TiO2 additions in solution is less efficient. And ozone treatment of the sample is not in the least efficient here, except for Cu. All three ways can bo used for Metal+humic acid complexes destruction.

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