Comparative estimates for populations of valence orbitals of chlorine atoms in complexes

O. Kh Poleshchuk, Ya Koput, V. P. Elin, G. N. Dolenko

    Research output: Contribution to journalArticlepeer-review

    Abstract

    The populations of valence orbitals of chlorine atoms in complexes SnCl4L2, SbCl5L, and TiCl4L2 were estimated by nuclear quadrupole resonance and X-ray fluorescence spectroscopy. It is shown that an increase in the negative charge on chlorine atoms upon formation of the main group element complexes can only be explained by taking into account the change in the geometry of an acceptor.

    Original languageEnglish
    Pages (from-to)320-322
    Number of pages3
    JournalRussian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
    Volume23
    Issue number5
    Publication statusPublished - May 1997

    ASJC Scopus subject areas

    • Inorganic Chemistry

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