Abstract
The paper describes an application of a kind of optical analytical method, digital color analysis (DCA), using colorimetric polymethacrylate sensors (optodes) in order to determine Cr (VI). The optodes are made of optically transparent polymethacrylate matrix (PMM) with 1.5- diphenylcarbazide immobilized. The developed optode can be used in determination of the anlytes using solid-phase spectrophotometry and calculating color coordinates as functions of absorbance spectra. Also color coordinates can be represented as basic color (e.g. RGB) data after the optode image digitizing. Then one can determine the content of an analyte in a sample by an appropriate color difference calculated on these coordinates. Experimental results of Cr (VI) determination show that the DCA characteristics of accuracy and precision are comparable with those of the solid phase spectrophotometry.
| Original language | English |
|---|---|
| Title of host publication | XXI IMEKO World Congress "Measurement in Research and Industry" |
| Publisher | IMEKO-International Measurement Federation Secretariat |
| Publication status | Published - 2015 |
| Event | 21st IMEKO World Congress on Measurement in Research and Industry - Prague, Czech Republic Duration: 30 Aug 2015 → 4 Sep 2015 |
Other
| Other | 21st IMEKO World Congress on Measurement in Research and Industry |
|---|---|
| Country | Czech Republic |
| City | Prague |
| Period | 30.8.15 → 4.9.15 |
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Keywords
- Chromium (VI)
- Colorimetric sensor
- Digital color analysis
- Immobilized reagents
- Optode
- Transparent polymeric matrix
ASJC Scopus subject areas
- Electrical and Electronic Engineering
Cite this
Colorimetric polymer sensor for determination of chromium (VI) : Comparison of estimation methods of the visible color changes. / Saranchina, Nadezhda; Gavrilenko, Nataliya Airatovna; Sukhanov, Alexey; Muravyov, Sergey.
XXI IMEKO World Congress "Measurement in Research and Industry". IMEKO-International Measurement Federation Secretariat, 2015.Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Colorimetric polymer sensor for determination of chromium (VI)
T2 - Comparison of estimation methods of the visible color changes
AU - Saranchina, Nadezhda
AU - Gavrilenko, Nataliya Airatovna
AU - Sukhanov, Alexey
AU - Muravyov, Sergey
PY - 2015
Y1 - 2015
N2 - The paper describes an application of a kind of optical analytical method, digital color analysis (DCA), using colorimetric polymethacrylate sensors (optodes) in order to determine Cr (VI). The optodes are made of optically transparent polymethacrylate matrix (PMM) with 1.5- diphenylcarbazide immobilized. The developed optode can be used in determination of the anlytes using solid-phase spectrophotometry and calculating color coordinates as functions of absorbance spectra. Also color coordinates can be represented as basic color (e.g. RGB) data after the optode image digitizing. Then one can determine the content of an analyte in a sample by an appropriate color difference calculated on these coordinates. Experimental results of Cr (VI) determination show that the DCA characteristics of accuracy and precision are comparable with those of the solid phase spectrophotometry.
AB - The paper describes an application of a kind of optical analytical method, digital color analysis (DCA), using colorimetric polymethacrylate sensors (optodes) in order to determine Cr (VI). The optodes are made of optically transparent polymethacrylate matrix (PMM) with 1.5- diphenylcarbazide immobilized. The developed optode can be used in determination of the anlytes using solid-phase spectrophotometry and calculating color coordinates as functions of absorbance spectra. Also color coordinates can be represented as basic color (e.g. RGB) data after the optode image digitizing. Then one can determine the content of an analyte in a sample by an appropriate color difference calculated on these coordinates. Experimental results of Cr (VI) determination show that the DCA characteristics of accuracy and precision are comparable with those of the solid phase spectrophotometry.
KW - Chromium (VI)
KW - Colorimetric sensor
KW - Digital color analysis
KW - Immobilized reagents
KW - Optode
KW - Transparent polymeric matrix
UR - http://www.scopus.com/inward/record.url?scp=84951145135&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84951145135&partnerID=8YFLogxK
M3 - Conference contribution
AN - SCOPUS:84951145135
BT - XXI IMEKO World Congress "Measurement in Research and Industry"
PB - IMEKO-International Measurement Federation Secretariat
ER -