Abstract
The copper(I)-catalyzed cycloaddition reaction between azides and alkynes has been employed to make metal-adhesive materials. Copper and brass surfaces supply the necessary catalytic Cu ions, and thus the polymerization process occurs selectively on these metals in the absence of added catalysts. Alternatively, copper compounds can be added to monomer mixtures and then introduced to reducing metal surfaces such as zinc to initiate polymerization. The resulting materials were found to possess comparable or superior adhesive strength to standard commercial glues, and structure-activity correlations have identified several important properties of the monomers.
| Original language | English |
|---|---|
| Pages (from-to) | 4392-4403 |
| Number of pages | 12 |
| Journal | Journal of Polymer Science, Part A: Polymer Chemistry |
| Volume | 42 |
| Issue number | 17 |
| DOIs | |
| Publication status | Published - 1 Sep 2004 |
| Externally published | Yes |
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Keywords
- Adhesives
- Alkynes
- Azides
- Click chemistry
- Copper
- Cycloaddition
- Transition metal chemistry
ASJC Scopus subject areas
- Polymers and Plastics
- Materials Chemistry
Cite this
Click chemistry in materials synthesis. 1. Adhesive polymers from copper-catalyzed azide-alkyne cycloaddition. / Díaz, David D.; Punna, Sreenivas; Holzer, Philipp; Mcpherson, Andrew K.; Sharpless, K. Barry; Fokin, Valery V.; Finn, M. G.
In: Journal of Polymer Science, Part A: Polymer Chemistry, Vol. 42, No. 17, 01.09.2004, p. 4392-4403.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Click chemistry in materials synthesis. 1. Adhesive polymers from copper-catalyzed azide-alkyne cycloaddition
AU - Díaz, David D.
AU - Punna, Sreenivas
AU - Holzer, Philipp
AU - Mcpherson, Andrew K.
AU - Sharpless, K. Barry
AU - Fokin, Valery V.
AU - Finn, M. G.
PY - 2004/9/1
Y1 - 2004/9/1
N2 - The copper(I)-catalyzed cycloaddition reaction between azides and alkynes has been employed to make metal-adhesive materials. Copper and brass surfaces supply the necessary catalytic Cu ions, and thus the polymerization process occurs selectively on these metals in the absence of added catalysts. Alternatively, copper compounds can be added to monomer mixtures and then introduced to reducing metal surfaces such as zinc to initiate polymerization. The resulting materials were found to possess comparable or superior adhesive strength to standard commercial glues, and structure-activity correlations have identified several important properties of the monomers.
AB - The copper(I)-catalyzed cycloaddition reaction between azides and alkynes has been employed to make metal-adhesive materials. Copper and brass surfaces supply the necessary catalytic Cu ions, and thus the polymerization process occurs selectively on these metals in the absence of added catalysts. Alternatively, copper compounds can be added to monomer mixtures and then introduced to reducing metal surfaces such as zinc to initiate polymerization. The resulting materials were found to possess comparable or superior adhesive strength to standard commercial glues, and structure-activity correlations have identified several important properties of the monomers.
KW - Adhesives
KW - Alkynes
KW - Azides
KW - Click chemistry
KW - Copper
KW - Cycloaddition
KW - Transition metal chemistry
UR - http://www.scopus.com/inward/record.url?scp=4444267581&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=4444267581&partnerID=8YFLogxK
U2 - 10.1002/pola.20330
DO - 10.1002/pola.20330
M3 - Article
VL - 42
SP - 4392
EP - 4403
JO - Journal of Polymer Science, Part A: Polymer Chemistry
JF - Journal of Polymer Science, Part A: Polymer Chemistry
SN - 0887-624X
IS - 17
ER -