Click chemistry in materials synthesis. 1. Adhesive polymers from copper-catalyzed azide-alkyne cycloaddition

Abstract

The copper(I)-catalyzed cycloaddition reaction between azides and alkynes has been employed to make metal-adhesive materials. Copper and brass surfaces supply the necessary catalytic Cu ions, and thus the polymerization process occurs selectively on these metals in the absence of added catalysts. Alternatively, copper compounds can be added to monomer mixtures and then introduced to reducing metal surfaces such as zinc to initiate polymerization. The resulting materials were found to possess comparable or superior adhesive strength to standard commercial glues, and structure-activity correlations have identified several important properties of the monomers.

Original language	English
Pages (from-to)	4392-4403
Number of pages	12
Journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	42
Issue number	17
DOIs	https://doi.org/10.1002/pola.20330
Publication status	Published - 1 Sep 2004
Externally published	Yes

Keywords

Adhesives
Alkynes
Azides
Click chemistry
Copper
Cycloaddition
Transition metal chemistry

ASJC Scopus subject areas

Polymers and Plastics
Materials Chemistry

Access to Document

10.1002/pola.20330

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Díaz, D. D., Punna, S., Holzer, P., Mcpherson, A. K., Sharpless, K. B., Fokin, V. V., & Finn, M. G. (2004). Click chemistry in materials synthesis. 1. Adhesive polymers from copper-catalyzed azide-alkyne cycloaddition. Journal of Polymer Science, Part A: Polymer Chemistry, 42(17), 4392-4403. https://doi.org/10.1002/pola.20330

Click chemistry in materials synthesis. 1. Adhesive polymers from copper-catalyzed azide-alkyne cycloaddition. / Díaz, David D.; Punna, Sreenivas; Holzer, Philipp; Mcpherson, Andrew K.; Sharpless, K. Barry; Fokin, Valery V.; Finn, M. G.

In: Journal of Polymer Science, Part A: Polymer Chemistry, Vol. 42, No. 17, 01.09.2004, p. 4392-4403.

Research output: Contribution to journal › Article

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