Change of the activated process of bituminous coal thermal decomposition depending on the method of applying the initiating inorganic salt additive

K. B. Larionov, D. L. Bolgova1

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Thermal conversion of bituminous coal containing 5% by weight of copper nitrate (Cu(NO3)2) initiation additive which was applied by incipient wetness impregnation and mechanical activation has been studied. The experiment was conducted by thermogravimetric analysis at a heating rate of 2.5°C/min up to a maximum temperature of 600°C. Inert gas nitrogen with a flow rate of 60 ml/min was used as a medium. The beginning of the volatile compounds sublimation in modified samples occurs earlier in comparison with the reference samples regardless of the method of Cu(NO3)2 additive application to the coal sample. The essential difference in the thermal decomposition of the researched samples modified by various methods is stages of the process. Decomposition of copper nitrate is accompanied with the beginning of volatile compounds sublimation (in the case of an application by an incipient wetness impregnation) or their sequential release after decomposition of the coarse additive (in the case of mechanical activation). According to the BET analysis, it has been established that the change in the temperature of volatile compounds release δtd is in direct correlation with the pore volume of the modified sample particles.

Original languageEnglish
Title of host publicationInternational Youth Scientific Conference "Heat and Mass Transfer in the Thermal Control System of Technical and Technological Energy Equipment", HMTTSC 2019
EditorsGeniy Kuznetsov, Evgeniya Orlova, Dmitry Feoktistov
PublisherAmerican Institute of Physics Inc.
ISBN (Electronic)9780735418783
DOIs
Publication statusPublished - 9 Aug 2019
EventInternational Youth Scientific Conference on Heat and Mass Transfer in the Thermal Control System of Technical and Technological Energy Equipment 2019, HMTTSC 2019 - Tomsk, Russian Federation
Duration: 23 Apr 201925 Apr 2019

Publication series

NameAIP Conference Proceedings
Volume2135
ISSN (Print)0094-243X
ISSN (Electronic)1551-7616

Conference

ConferenceInternational Youth Scientific Conference on Heat and Mass Transfer in the Thermal Control System of Technical and Technological Energy Equipment 2019, HMTTSC 2019
CountryRussian Federation
CityTomsk
Period23.4.1925.4.19

Fingerprint

inorganic salts
inorganic salt
thermal degradation
bituminous coal
thermal decomposition
sublimation
coal
decomposition
nitrate
copper
salts
reference sample
volatile compounds
temperature
moisture content
nitrates
heating
sampling
activation
nitrogen

ASJC Scopus subject areas

  • Ecology, Evolution, Behavior and Systematics
  • Ecology
  • Plant Science
  • Physics and Astronomy(all)
  • Nature and Landscape Conservation

Cite this

Larionov, K. B., & Bolgova1, D. L. (2019). Change of the activated process of bituminous coal thermal decomposition depending on the method of applying the initiating inorganic salt additive. In G. Kuznetsov, E. Orlova, & D. Feoktistov (Eds.), International Youth Scientific Conference "Heat and Mass Transfer in the Thermal Control System of Technical and Technological Energy Equipment", HMTTSC 2019 [020032] (AIP Conference Proceedings; Vol. 2135). American Institute of Physics Inc.. https://doi.org/10.1063/1.5120669

Change of the activated process of bituminous coal thermal decomposition depending on the method of applying the initiating inorganic salt additive. / Larionov, K. B.; Bolgova1, D. L.

International Youth Scientific Conference "Heat and Mass Transfer in the Thermal Control System of Technical and Technological Energy Equipment", HMTTSC 2019. ed. / Geniy Kuznetsov; Evgeniya Orlova; Dmitry Feoktistov. American Institute of Physics Inc., 2019. 020032 (AIP Conference Proceedings; Vol. 2135).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Larionov, KB & Bolgova1, DL 2019, Change of the activated process of bituminous coal thermal decomposition depending on the method of applying the initiating inorganic salt additive. in G Kuznetsov, E Orlova & D Feoktistov (eds), International Youth Scientific Conference "Heat and Mass Transfer in the Thermal Control System of Technical and Technological Energy Equipment", HMTTSC 2019., 020032, AIP Conference Proceedings, vol. 2135, American Institute of Physics Inc., International Youth Scientific Conference on Heat and Mass Transfer in the Thermal Control System of Technical and Technological Energy Equipment 2019, HMTTSC 2019, Tomsk, Russian Federation, 23.4.19. https://doi.org/10.1063/1.5120669
Larionov KB, Bolgova1 DL. Change of the activated process of bituminous coal thermal decomposition depending on the method of applying the initiating inorganic salt additive. In Kuznetsov G, Orlova E, Feoktistov D, editors, International Youth Scientific Conference "Heat and Mass Transfer in the Thermal Control System of Technical and Technological Energy Equipment", HMTTSC 2019. American Institute of Physics Inc. 2019. 020032. (AIP Conference Proceedings). https://doi.org/10.1063/1.5120669
Larionov, K. B. ; Bolgova1, D. L. / Change of the activated process of bituminous coal thermal decomposition depending on the method of applying the initiating inorganic salt additive. International Youth Scientific Conference "Heat and Mass Transfer in the Thermal Control System of Technical and Technological Energy Equipment", HMTTSC 2019. editor / Geniy Kuznetsov ; Evgeniya Orlova ; Dmitry Feoktistov. American Institute of Physics Inc., 2019. (AIP Conference Proceedings).
@inproceedings{fa47571ef5b2488c9e3ec62bc034356e,
title = "Change of the activated process of bituminous coal thermal decomposition depending on the method of applying the initiating inorganic salt additive",
abstract = "Thermal conversion of bituminous coal containing 5{\%} by weight of copper nitrate (Cu(NO3)2) initiation additive which was applied by incipient wetness impregnation and mechanical activation has been studied. The experiment was conducted by thermogravimetric analysis at a heating rate of 2.5°C/min up to a maximum temperature of 600°C. Inert gas nitrogen with a flow rate of 60 ml/min was used as a medium. The beginning of the volatile compounds sublimation in modified samples occurs earlier in comparison with the reference samples regardless of the method of Cu(NO3)2 additive application to the coal sample. The essential difference in the thermal decomposition of the researched samples modified by various methods is stages of the process. Decomposition of copper nitrate is accompanied with the beginning of volatile compounds sublimation (in the case of an application by an incipient wetness impregnation) or their sequential release after decomposition of the coarse additive (in the case of mechanical activation). According to the BET analysis, it has been established that the change in the temperature of volatile compounds release δtd is in direct correlation with the pore volume of the modified sample particles.",
author = "Larionov, {K. B.} and Bolgova1, {D. L.}",
year = "2019",
month = "8",
day = "9",
doi = "10.1063/1.5120669",
language = "English",
series = "AIP Conference Proceedings",
publisher = "American Institute of Physics Inc.",
editor = "Geniy Kuznetsov and Evgeniya Orlova and Dmitry Feoktistov",
booktitle = "International Youth Scientific Conference {"}Heat and Mass Transfer in the Thermal Control System of Technical and Technological Energy Equipment{"}, HMTTSC 2019",

}

TY - GEN

T1 - Change of the activated process of bituminous coal thermal decomposition depending on the method of applying the initiating inorganic salt additive

AU - Larionov, K. B.

AU - Bolgova1, D. L.

PY - 2019/8/9

Y1 - 2019/8/9

N2 - Thermal conversion of bituminous coal containing 5% by weight of copper nitrate (Cu(NO3)2) initiation additive which was applied by incipient wetness impregnation and mechanical activation has been studied. The experiment was conducted by thermogravimetric analysis at a heating rate of 2.5°C/min up to a maximum temperature of 600°C. Inert gas nitrogen with a flow rate of 60 ml/min was used as a medium. The beginning of the volatile compounds sublimation in modified samples occurs earlier in comparison with the reference samples regardless of the method of Cu(NO3)2 additive application to the coal sample. The essential difference in the thermal decomposition of the researched samples modified by various methods is stages of the process. Decomposition of copper nitrate is accompanied with the beginning of volatile compounds sublimation (in the case of an application by an incipient wetness impregnation) or their sequential release after decomposition of the coarse additive (in the case of mechanical activation). According to the BET analysis, it has been established that the change in the temperature of volatile compounds release δtd is in direct correlation with the pore volume of the modified sample particles.

AB - Thermal conversion of bituminous coal containing 5% by weight of copper nitrate (Cu(NO3)2) initiation additive which was applied by incipient wetness impregnation and mechanical activation has been studied. The experiment was conducted by thermogravimetric analysis at a heating rate of 2.5°C/min up to a maximum temperature of 600°C. Inert gas nitrogen with a flow rate of 60 ml/min was used as a medium. The beginning of the volatile compounds sublimation in modified samples occurs earlier in comparison with the reference samples regardless of the method of Cu(NO3)2 additive application to the coal sample. The essential difference in the thermal decomposition of the researched samples modified by various methods is stages of the process. Decomposition of copper nitrate is accompanied with the beginning of volatile compounds sublimation (in the case of an application by an incipient wetness impregnation) or their sequential release after decomposition of the coarse additive (in the case of mechanical activation). According to the BET analysis, it has been established that the change in the temperature of volatile compounds release δtd is in direct correlation with the pore volume of the modified sample particles.

UR - http://www.scopus.com/inward/record.url?scp=85070998052&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85070998052&partnerID=8YFLogxK

U2 - 10.1063/1.5120669

DO - 10.1063/1.5120669

M3 - Conference contribution

T3 - AIP Conference Proceedings

BT - International Youth Scientific Conference "Heat and Mass Transfer in the Thermal Control System of Technical and Technological Energy Equipment", HMTTSC 2019

A2 - Kuznetsov, Geniy

A2 - Orlova, Evgeniya

A2 - Feoktistov, Dmitry

PB - American Institute of Physics Inc.

ER -