Abstract
The behaviour of copper complexes with glycylglycyl-l-histidine (GGH) was investigated using cyclic voltammetry and adsorptive differential pulse cathodic stripping voltammetry. The nature of the observed cathodic and anodic peaks was established and optimum conditions have been found for the determination of nanomolar levels of GGH by means of differential pulse cathodic stripping voltammetry after accumulation in the presence of excess copper at -0.20 V vs. AgAgCl reference electrode and using the stripping peak around -0.40 V which corresponds to the reduction of the copper(I)-GGH complex.
| Original language | English |
|---|---|
| Pages (from-to) | 41-51 |
| Number of pages | 11 |
| Journal | Analytica Chimica Acta |
| Volume | 278 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 6 Jun 1993 |
| Externally published | Yes |
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Keywords
- Copper complexes
- Cyclic voltammetry
- Glycylglycyl-l-histidine
- Stripping voltammetry
ASJC Scopus subject areas
- Analytical Chemistry
- Environmental Chemistry
- Biochemistry
- Spectroscopy
Cite this
Cathodic stripping voltammetric behaviour of copper complexes of glycylgylcyl-l-histidine at a hanging mercury drop electrode. Determination of trace amounts of glycylglycyl-l-histidine. / Fogg, Arnold G.; Nil Ertas, F.; Moreira, Josino C.; Barek, Jiri.
In: Analytica Chimica Acta, Vol. 278, No. 1, 06.06.1993, p. 41-51.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Cathodic stripping voltammetric behaviour of copper complexes of glycylgylcyl-l-histidine at a hanging mercury drop electrode. Determination of trace amounts of glycylglycyl-l-histidine
AU - Fogg, Arnold G.
AU - Nil Ertas, F.
AU - Moreira, Josino C.
AU - Barek, Jiri
PY - 1993/6/6
Y1 - 1993/6/6
N2 - The behaviour of copper complexes with glycylglycyl-l-histidine (GGH) was investigated using cyclic voltammetry and adsorptive differential pulse cathodic stripping voltammetry. The nature of the observed cathodic and anodic peaks was established and optimum conditions have been found for the determination of nanomolar levels of GGH by means of differential pulse cathodic stripping voltammetry after accumulation in the presence of excess copper at -0.20 V vs. AgAgCl reference electrode and using the stripping peak around -0.40 V which corresponds to the reduction of the copper(I)-GGH complex.
AB - The behaviour of copper complexes with glycylglycyl-l-histidine (GGH) was investigated using cyclic voltammetry and adsorptive differential pulse cathodic stripping voltammetry. The nature of the observed cathodic and anodic peaks was established and optimum conditions have been found for the determination of nanomolar levels of GGH by means of differential pulse cathodic stripping voltammetry after accumulation in the presence of excess copper at -0.20 V vs. AgAgCl reference electrode and using the stripping peak around -0.40 V which corresponds to the reduction of the copper(I)-GGH complex.
KW - Copper complexes
KW - Cyclic voltammetry
KW - Glycylglycyl-l-histidine
KW - Stripping voltammetry
UR - http://www.scopus.com/inward/record.url?scp=0027258328&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0027258328&partnerID=8YFLogxK
U2 - 10.1016/0003-2670(93)80083-W
DO - 10.1016/0003-2670(93)80083-W
M3 - Article
AN - SCOPUS:0027258328
VL - 278
SP - 41
EP - 51
JO - Analytica Chimica Acta
JF - Analytica Chimica Acta
SN - 0003-2670
IS - 1
ER -