Catalytically active gold clusters and nanoparticles for CO oxidation

A. N. Pestryakov, N. Bogdanchikova, A. Simakov, I. Tuzovskaya, F. Jentoft, M. Farias, A. Díaz

Research output: Contribution to journalArticle

40 Citations (Scopus)

Abstract

Electronic states of gold nanoparticles in mordenite and their transformations under redox treatments have been studied by the methods of FTIR spectroscopy of adsorbed CO and diffuse reflectance UV-visible spectroscopy. Different states of ionic and metallic gold were detected in the zeolite channels and on the external surface of the zeolite - Au+ and Au3+ ions, charged clusters Aunδ +, and neutral nanoparticles Aum. Catalytic tests of the samples revealed the existence of two types of active sites of gold in CO oxidation - gold clusters <2 nm (low-temperature activity) and gold nanoparticles (high temperature activity).

Original languageEnglish
Pages (from-to)3792-3795
Number of pages4
JournalSurface Science
Volume601
Issue number18
DOIs
Publication statusPublished - 15 Sep 2007

Fingerprint

Carbon Monoxide
Gold
gold
Nanoparticles
Oxidation
nanoparticles
oxidation
Zeolites
Thermodynamic properties
Spectroscopy
Electronic states
spectroscopy
Ions
reflectance
Temperature
electronics
ions

Keywords

  • FTIR
  • Gold catalysts
  • Nanoparticles
  • UV-visible spectroscopy
  • Zeolites

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Condensed Matter Physics
  • Surfaces and Interfaces

Cite this

Pestryakov, A. N., Bogdanchikova, N., Simakov, A., Tuzovskaya, I., Jentoft, F., Farias, M., & Díaz, A. (2007). Catalytically active gold clusters and nanoparticles for CO oxidation. Surface Science, 601(18), 3792-3795. https://doi.org/10.1016/j.susc.2007.04.012

Catalytically active gold clusters and nanoparticles for CO oxidation. / Pestryakov, A. N.; Bogdanchikova, N.; Simakov, A.; Tuzovskaya, I.; Jentoft, F.; Farias, M.; Díaz, A.

In: Surface Science, Vol. 601, No. 18, 15.09.2007, p. 3792-3795.

Research output: Contribution to journalArticle

Pestryakov, AN, Bogdanchikova, N, Simakov, A, Tuzovskaya, I, Jentoft, F, Farias, M & Díaz, A 2007, 'Catalytically active gold clusters and nanoparticles for CO oxidation', Surface Science, vol. 601, no. 18, pp. 3792-3795. https://doi.org/10.1016/j.susc.2007.04.012
Pestryakov AN, Bogdanchikova N, Simakov A, Tuzovskaya I, Jentoft F, Farias M et al. Catalytically active gold clusters and nanoparticles for CO oxidation. Surface Science. 2007 Sep 15;601(18):3792-3795. https://doi.org/10.1016/j.susc.2007.04.012
Pestryakov, A. N. ; Bogdanchikova, N. ; Simakov, A. ; Tuzovskaya, I. ; Jentoft, F. ; Farias, M. ; Díaz, A. / Catalytically active gold clusters and nanoparticles for CO oxidation. In: Surface Science. 2007 ; Vol. 601, No. 18. pp. 3792-3795.
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